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Recent advances in experimental thermodynamics of metal–organic frameworks

Published online by Cambridge University Press:  20 September 2019

Hui Sun  and
Di Wu Open the ORCID record for Di Wu [Opens in a new window]
Hui Sun
Affiliation:
Petroleum Processing Research Center, East China University of Science and Technology, Shanghai 200237, China International Joint Research Center of Green Energy Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
Di Wu*
Affiliation:
Alexandra Navrotsky Institute for Experimental Thermodynamics, Washington State University, Pullman, Washington 99163, USA The Gene and Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, Washington 99163, USA Department of Chemistry, Washington State University, Pullman, Washington 99163, USA Materials Science and Engineering, Washington State University, Pullman, Washington 99163, USA
*
a)Author to whom correspondence should be addressed. Electronic mail: Email: d.wu@wsu.edu
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Abstract

This mini review summarizes recent advances in experimental thermodynamics of metal–organic frameworks (MOFs). Taking advantage of the development in mechanochemistry, near-room temperature solution calorimetry, and low-temperature heat capacity measurements, the energetic landscape, entropy trends, and Gibbs free energy evolutions of MOFs with true polymorphism [Zn(MeIm)2, Zn(EtIm)2, and Zn(CF3Im)2] as framework topology varies were thoroughly explored by integrated calorimetric and computational methodologies. In addition, the formation enthalpies of MOFs with ultrahigh porosity (MOF-177 and UMCM-1) and the simplest structure (metal formates) have been determined. The studies summarized below highlight the complex interplays among interrelated compositional, chemical, and topological (structural) factors in the determination of the thermodynamic parameters of MOFs.

Keywords

thermodynamicsmetal–organic frameworkscalorimetryheat capacitystructure
Type
Review Article
Information
Powder Diffraction , Volume 34 , Issue 4 , December 2019 , pp. 297 - 301
Copyright
Copyright © International Centre for Diffraction Data 2019 

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