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Synthesis of nitrogen-superdoped and graphene fiber-supported three-dimensional graphene foam for supercapacitors

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Abstract

Nitrogen-doped three-dimensional (3D) graphene foam (GF) has aroused tremendous interest for the supercapacitors (SCs) applications because of its unique properties. However, it is still confronting the challenges of facile preparation and the high N-doping level. Here, by rolling a part of graphene planes into the fiber-like scaffold to support other graphene sheets, we obtain high-quality 3D GF. Followed by fluorination and N-doping, N-superdoped GF (NGF) with N content as high as 15.7 at.% was successfully prepared. The combination of fiber-supported 3D structure and high N-level facilitate forming GF with large surface area, low internal resistance, good wettability, and sufficient active sites, which results in high-performance SCs: The prepared NGF electrode has a high specific capacitance (320.0 F g−1 and 303.5 F g−1 in three- and two-electrode system, respectively), and a long cycle life (92.8% retention after 1000 cycles), as well, the NGF SC device has a high energy density (42.1 Wh kg−1 at 250 W kg−1).

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References

  1. Bellani S, Martín-García B, Oropesa-Nuñez R et al (2019) “Ion sliding” on graphene: a novel concept to boost supercapacitor performance. Nanoscale Horizons 4:1077–1091

    CAS  Google Scholar 

  2. Wang Q, Wang S, Guo X et al (2019) MXene-reduced graphene oxide aerogel for aqueous zinc-ion hybrid supercapacitor with ultralong cycle life. Adv Electron Mater 5:1900537

    CAS  Google Scholar 

  3. Avireddy H, Byles BW, Pinto D et al (2019) Stable high-voltage aqueous pseudocapacitive energy storage device with slow self-discharge. Nano Energy 64:103961

    CAS  Google Scholar 

  4. Liu J, Wang J, Xu C et al (2018) Advanced energy storage devices: basic principles, analytical methods, and rational materials design. Adv Sci 5:1700322

    Google Scholar 

  5. El-Kady MF, Ihns M, Li M et al (2015) Engineering three-dimensional hybrid supercapacitors and microsupercapacitors for high-performance integrated energy storage. Proc Natl Acad Sci USA 112:4233–4238

    CAS  Google Scholar 

  6. Down MP, Rowley-Neale SJ, Smith GC, Banks CE (2018) Fabrication of graphene oxide supercapacitor devices. ACS Appl Energy Mater 1:707–714

    CAS  Google Scholar 

  7. Ke Q, Wang J (2016) Graphene-based materials for supercapacitor electrodes—a review. J Mater 2:37–54

    Google Scholar 

  8. El-Kady MF, Shao Y, Kaner RB (2016) Graphene for batteries, supercapacitors and beyond. Nat Rev Mater 1:16033

    CAS  Google Scholar 

  9. Lu S-Y, Jin M, Zhang Y et al (2018) Chemically exfoliating biomass into a graphene-like porous active carbon with rational pore structure, good conductivity, and large surface area for high-performance supercapacitors. Adv Energy Mater 8:1702545

    Google Scholar 

  10. Xu Y, Lin Z, Zhong X et al (2014) Holey graphene frameworks for highly efficient capacitive energy storage. Nat Commun 5:4554

    CAS  Google Scholar 

  11. Raccichini R, Varzi A, Passerini S, Scrosati B (2014) The role of graphene for electrochemical energy storage. Nat Mater 14:271–279

    Google Scholar 

  12. Strauss V, Marsh K, Kowal MD et al (2018) A simple route to porous graphene from carbon nanodots for supercapacitor applications. Adv Mater 30:1704449

    Google Scholar 

  13. Lin Z, Taberna P-L, Patrice Simon (2016) Graphene-based supercapacitors using eutectic ionic liquid mixture electrolyte. Electrochim Acta 206:446–451

    CAS  Google Scholar 

  14. Hashemi M, Rahmanifar MS, El-Kady MF et al (2018) The use of an electrocatalytic redox electrolyte for pushing the energy density boundary of a flexible polyaniline electrode to a new limit. Nano Energy 44:489–498

    CAS  Google Scholar 

  15. Lukatskaya MR, Dunn B, Gogotsi Y (2016) Multidimensional materials and device architectures for future hybrid energy storage. Nat Commun 7:12647

    Google Scholar 

  16. Zhao X, Zheng B, Huang T, Gao C (2015) Graphene-based single fiber supercapacitor with a coaxial structure. Nanoscale 7:9399–9404

    CAS  Google Scholar 

  17. Wang C, Ding Y, Yuan Y et al (2016) Multifunctional, highly flexible, free-standing 3D polypyrrole foam. Small 12:4070–4076

    CAS  Google Scholar 

  18. Zhang W, Xu C, Ma C et al (2017) Nitrogen-superdoped 3D graphene networks for high-performance supercapacitors. Adv Mater 29:1701677

    Google Scholar 

  19. Yu M, Zhang J, Li S et al (2016) Three-dimensional nitrogen doped holey reduced graphene oxide framework as metal-free counter electrodes for high performance dye-sensitized solar cells. J Power Sources 308:44–51

    CAS  Google Scholar 

  20. Kumar NA, Baek J-B (2015) Doped graphene supercapacitors. Nanotechnology 26:492001

    Google Scholar 

  21. Lv K, Fan Y, Zhu Y et al (2018) Elastic Ag-anchored N-doped graphene/carbon foam for the selective electrochemical reduction of carbon dioxide to ethanol. J Mater Chem A 6:5025–5031. https://doi.org/10.1039/c7ta10802h

    Article  CAS  Google Scholar 

  22. Li S-M, Yang S-Y, Wang Y-S et al (2015) N-doped structures and surface functional groups of reduced graphene oxide and their effect on the electrochemical performance of supercapacitor with organic electrolyte. J Power Sources 278:218–229

    CAS  Google Scholar 

  23. Wu Y, Yan D, Zhang Z et al (2019) Electron highways into nanochannels of covalent organic frameworks for high electrical conductivity and energy storage. ACS Appl Mater Interfaces 11:7661–7665

    CAS  Google Scholar 

  24. Qu J, He N, Patil SV et al (2019) Screen printing of graphene oxide patterns onto viscose nonwovens with tunable penetration depth and electrical conductivity. ACS Appl Mater Interfaces 11:14944–14951

    CAS  Google Scholar 

  25. Suresh Balaji S, Karnan M, Sathish M (2018) Supercritical fluid processing of N-doped graphene and its application in high energy symmetric supercapacitor. Int J Hydrogen Energy 43:4044–4057

    CAS  Google Scholar 

  26. Dai S, Liu Z, Zhao B et al (2018) A high-performance supercapacitor electrode based on N-doped porous graphene. J Power Sources 387:43–48

    CAS  Google Scholar 

  27. Gao H, Duan H (2015) 2D and 3D graphene materials: preparation and bioelectrochemical applications. Biosens Bioelectron 65:404–419

    CAS  Google Scholar 

  28. Wu Y, Yi N, Huang L et al (2015) Three-dimensionally bonded spongy graphene material with super compressive elasticity and near-zero poisson’s ratio. Nat Commun 6:6141

    CAS  Google Scholar 

  29. Yousefi N, Lu X, Elimelech M, Tufenkji N (2019) Environmental performance of graphene-based 3D macrostructures. Nat Nanotechnol 14:107–119

    CAS  Google Scholar 

  30. Zhang Q, Xu Z, Lu B (2016) Strongly coupled MoS2 –3D graphene materials for ultrafastcharge slow discharge LIBs and water splitting applications. Energy Storage Mater 4:84–91

    Google Scholar 

  31. Zhu J, Childress AS, Karakaya M et al (2016) Defect-engineered graphene for high-energy- and high-power-density supercapacitor devices. Adv Mater 28:7185–7192

    CAS  Google Scholar 

  32. Lota G, Lota K, Frackowiak E (2007) Nanotubes based composites rich in nitrogen for supercapacitor application. Electrochem Commun 9:1828–1832

    CAS  Google Scholar 

  33. Lota G, Grzyb B, Machnikowska H et al (2005) Effect of nitrogen in carbon electrode on the supercapacitor performance. Chem Phys Lett 404:53–58

    CAS  Google Scholar 

  34. Zeng J, Cao Q, Wang X et al (2015) Nitrogen-doped hierarchical porous carbon for supercapacitor with well electrochemical performances. J Solid State Electrochem 19:1591–1597

    CAS  Google Scholar 

  35. Dong X, Hu N, Wei L et al (2016) A new strategy to prepare N-doped holey graphene for high-volumetric supercapacitors. J Mater Chem A 4:9739–9743. https://doi.org/10.1039/c6ta01406b

    Article  CAS  Google Scholar 

  36. Yu H, Zhang B, Bulin C et al (2016) High-efficient synthesis of graphene oxide based on improved hummers method. Sci Rep 6:36143

    CAS  Google Scholar 

  37. Xin L, Li R, Lu Z et al (2018) Hierarchical metal-organic framework derived nitrogen-doped porous carbon by controllable synthesis for high performance supercapacitors. J Electroanal Chem 813:200–207

    CAS  Google Scholar 

  38. Gao S, Li X, Li L, Wei X (2017) A versatile biomass derived carbon material for oxygen reduction reaction, supercapacitors and oil/water separation. Nano Energy 33:334–342

    CAS  Google Scholar 

  39. Xu Y, Sheng K, Li C, Shi G (2010) Self-assembled graphene hydrogel via a one-step hydrothermal process. ACS Nano 4:4324–4330

    CAS  Google Scholar 

  40. Zhao Y, Hu C, Hu Y et al (2012) A versatile, ultralight, nitrogen-doped graphene framework. Angew Chem Int Ed 51:11371–11375. https://doi.org/10.1002/anie.201206554

    Article  CAS  Google Scholar 

  41. Wu Z-S, Ren W, Gao L et al (2009) Synthesis of graphene sheets with high electrical conductivity and good thermal stability by hydrogen arc discharge exfoliation. ACS Nano 3:411–417

    CAS  Google Scholar 

  42. Liu Y, Shen Y, Sun L et al (2016) Elemental superdoping of graphene and carbon nanotubes. Nat Commun 7:10921

    CAS  Google Scholar 

  43. Khan ZU, Yan T, Shi L, Zhang D (2018) Improved capacitive deionization by using 3D intercalated graphene sheet–sphere nanocomposite architectures. Environ Sci Nano 5:980–991

    Google Scholar 

  44. Chi Y-W, Hu C-C, Huang K-P et al (2016) Manipulation of defect density and nitrogen doping on few-layer graphene sheets using the plasma methodology for electrochemical applications. Electrochim Acta 221:144–153

    CAS  Google Scholar 

  45. Rybin M, Pereyaslavtsev A, Vasilieva T et al (2016) Efficient nitrogen doping of graphene by plasma treatment. Carbon N Y 96:196–202

    CAS  Google Scholar 

  46. Lin T, Chen IW, Liu F et al (2015) Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage. Science 350:1508–1513. https://doi.org/10.1126/science.aab3798

    Article  CAS  Google Scholar 

  47. Xing L, Chen X, Tan Z et al (2019) Synthesis of porous carbon material with suitable graphitization strength for high electrochemical capacitors. ACS Sustain Chem Eng 7:6601–6610

    CAS  Google Scholar 

  48. Fan Y-M, Song W-L, Li X, Fan L-Z (2017) Assembly of graphene aerogels into the 3D biomass-derived carbon frameworks on conductive substrates for flexible supercapacitors. Carbon N Y 111:658–666

    CAS  Google Scholar 

  49. Deng S, Rhee D, Lee WK et al (2019) Graphene wrinkles enable spatially defined chemistry. Nano Lett 19:5640–5646

    CAS  Google Scholar 

  50. Wang J, Chen B, Xing B (2016) Wrinkles and folds of activated graphene nanosheets as fast and efficient adsorptive sites for hydrophobic organic contaminants. Environ Sci Technol 50:3798–3808

    CAS  Google Scholar 

  51. Cui L, Du X, Wei G, Feng Y (2016) Thermal conductivity of graphene wrinkles: a molecular dynamics simulation. J Phys Chem C 120:23807–23812

    CAS  Google Scholar 

  52. Sha J, Salvatierra RV, Dong P et al (2017) Three-dimensional rebar graphene. ACS Appl Mater Interfaces 9:7376–7384

    CAS  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (61604062, 51702130, 11604061), Natural Science Foundation of Jiangsu Province (BK20170550), Natural Science Foundation of Guangxi Zhuang Autonomous Region of China (2018GXNSFAA050014), Senior Talent Fund of Jiangsu University.

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Authors and Affiliations

  1. Department of Physics, Faculty of Science, Jiangsu University, Zhenjiang, 212013, China

    Weigeng Ke, Sennian He, Wentao Le, Yuan Liu, Faling Zhang, Mingming Chen & Dawei Cao

  2. School of Science, Guilin University of Technology, Guilin, 541004, China

    Tao Tang

  3. Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, College of Physics and Energy, Fujian Normal University, Fuzhou, 350117, China

    Yongping Zheng

  4. Sinosteel Anhui Tianyuan Technology Co., Ltd, Hefei, 243000, China

    Jie Chen

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  1. Weigeng Ke
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  2. Sennian He
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  4. Yuan Liu
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Correspondence to Yuan Liu or Tao Tang.

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Ke, W., He, S., Le, W. et al. Synthesis of nitrogen-superdoped and graphene fiber-supported three-dimensional graphene foam for supercapacitors. J Mater Sci 55, 6952–6962 (2020). https://doi.org/10.1007/s10853-020-04496-8

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