Issue 33, 2020

The intercalation of 1,10-phenanthroline into layered NiPS3via iron dopant seeding

Abstract

Using 2% percent of iron dopants as reaction active sites yields a series of single crystals of 1,10-phenanthroline intercalated NiPS3, via a solution reaction with aniline chloride, not possible by a direct reaction. Experimental magnetic susceptibility measurements demonstrate that 1,10-phenanthroline intercalation suppresses the anti-ferromagnetism ordering at around 150 K in Fe0.02Ni0.98PS3, and gives rise to a ferrimagnetic phase transition at a temperature around 75 K. An intercalation mechanism is proposed for the reaction, and this dopant seeding method provides a new approach for intercalation into layered materials.

Graphical abstract: The intercalation of 1,10-phenanthroline into layered NiPS3via iron dopant seeding

Supplementary files

Article information

Article type
Communication
Submitted
23 Jan 2020
Accepted
17 Mar 2020
First published
18 Mar 2020

Chem. Commun., 2020,56, 4603-4606

The intercalation of 1,10-phenanthroline into layered NiPS3via iron dopant seeding

X. Ma, L. Zhang, C. Xu, Q. Dong, R. I. Walton, Z. Li, H. Shi, G. Chen, J. Hu, J. Li and H. Yang, Chem. Commun., 2020, 56, 4603 DOI: 10.1039/D0CC00636J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements