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Determination of kinetically or thermodynamically stable product between the two lead coordination polymers

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Abstract

To study the effects of ultrasonic irradiation, heating, the molar ratio of initial reactants and reaction time on formation of [Pb2(4,4′-Bipy)I4]n(1) and [Pb(4,4′-Bipy)I2]n (2) coordination polymers, [4,4′-Bipy = 4,4′-Bipyridine], some experiments were designed and eight samples were synthesized under different conditions. The results showed that the [Pb(4,4′-Bipy)I2]n (2) was the only stable product under the designed conditions, and it is the thermodynamically stable product. [Pb2(4,4′-Bipy)I4]n (1) which can be formed only with crystallization technique is kinetically stable product. These samples were characterized by IR spectroscopy, X-ray powder diffraction (XRD), and scanning electron microscopy (SEM).

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Funding

The authors would like to acknowledge the financial support of University of Tehran for this research under grant number 01/1/389845.

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Authors and Affiliations

  1. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Alireza Davoodi & Kamran Akhbari

  2. Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Songkhla, Thailand

    Anukorn Phuruangrat

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  1. Alireza Davoodi
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  2. Kamran Akhbari
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  3. Anukorn Phuruangrat
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Correspondence to Kamran Akhbari.

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Davoodi, A., Akhbari, K. & Phuruangrat, A. Determination of kinetically or thermodynamically stable product between the two lead coordination polymers. Colloid Polym Sci 298, 449–457 (2020). https://doi.org/10.1007/s00396-020-04625-4

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  • DOI: https://doi.org/10.1007/s00396-020-04625-4

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