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Hybrid organic-inorganic materials on the basis of acrylic monomers and TEOS prepared by simultaneous UV-curing and sol-gel process

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Abstract

In this work cross-linked hybrid organic-inorganic membranes consisting of polymeric matrix functionalized with sulfonic groups and uniformly distributed silica domains have been successfully synthesized through in situ polymerization strategy via photo-initiated copolymerization of acrylic monomers (acrylonitrile AN, acrylamide AAm, 3-sulfopropyl acrylate potassium salt SPAK) and simultaneous formation of silica counterpart using TEOS-based sol-gel system. N,N′-methylenebis(acrylamide) (MBA) was used as a cross-linker. The ratio between monomers was maintained stable, whereas the amount of added sol-gel system was varied. The influence of inorganic component content on properties of hybrid polymer-inorganic membranes was investigated. Chemical composition, thermal properties, structure and morphology of the obtained hybrid membranes were investigated by ATR-FTIR, TGA, DSC, SEM and EFTEM. Proton conductivity of the synthesized membranes was high (7.6 to 13.5 mS/cm) and increases with an increase of silica content. The prepared membranes were thermally stable up to 90 °C, and exhibited proton conductivity and swelling coefficients sufficient for possible use as proton-conducting membranes.

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Acknowledgements

Khrystyna Demydova acknowledges German Academic Exchange Service (DAAD) for financial support (ResearchGrants for Doctoral Candidates and Young Academicsand Scientists 2015/16, program ID 57130104). Authors also thank Dr. Petr Formanek and Uta Reuter for their help with TEM experiments, and Dr. Klaus-Jochen Eichhorn for the helpful discussion.

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Authors and Affiliations

  1. Department of Physical Chemistry of Fossil Fuels L.M. Lytvynenko Institute of Physico-organic Chemistry and Coal Chemistry NAS of Ukraine, 3a, Naukova str., Lviv, 79060, Ukraine

    Khrystyna Demydova, Iryna Yevchuk & Oksana Demchyna

  2. Leibniz-Institut für Polymerforschung Dresden e.V, Hohe Strasse 6, 01069, Dresden, Germany

    Andriy Horechyy, Jochen Meier-Haaсk, Mikhail Malanin, Liane Häußler & Manfred Stamm

  3. TechnischeUniversität Dresden, Physical Chemistry of Polymer Materials, 01062, Dresden, Germany

    Manfred Stamm

Authors
  1. Khrystyna Demydova
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  2. Andriy Horechyy
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  3. Jochen Meier-Haaсk
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  4. Mikhail Malanin
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  5. Liane Häußler
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  6. Manfred Stamm
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  7. Iryna Yevchuk
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  8. Oksana Demchyna
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Correspondence to Oksana Demchyna.

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Demydova, K., Horechyy, A., Meier-Haaсk, J. et al. Hybrid organic-inorganic materials on the basis of acrylic monomers and TEOS prepared by simultaneous UV-curing and sol-gel process. J Polym Res 27, 88 (2020). https://doi.org/10.1007/s10965-020-02057-w

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  • DOI: https://doi.org/10.1007/s10965-020-02057-w

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