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Dimensions and conformations of macromolecules of N-methyl-N-vinylacetamide and N-methyl-N-vinylamine hydrochloride in solutions in a wide interval of ionic strength

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Abstract

Fractions of the copolymer of N-methyl-N-vinylacetamide and N-methyl-N-vinylamine hydrochloride containing 15.7 ± 0.5% of charged units are obtained by radical polymerization, fractionation, and hydrolysis. Viscous flow, velocity sedimentation, and translational diffusion of their dilute solutions are studied in 0.2 M NaCl. Viscosimetric studies are also carried out in a wide range of ionic forces: from the minimum (~10–6 mol/L) to the maximum (6 mol/L). The hydrodynamic volumes and equilibrium rigidity of the copolymer under study are compared with the data obtained earlier for an uncharged homopolymer and a copolymer with a higher linear charge density (~44% of charged units) in solutions with different ionic strength. The correspondence of the values obtained to the theories of Odijk, Skolnik, and Fixman (OSF) as well as Dobrynin is discussed.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bolshoi pr. 31, St. Petersburg, 199004, Russia

    O. A. Dommes, O. V. Okatova, A. A. Kostina, I. I. Gavrilova, E. F. Panarin & G. M. Pavlov

  2. Peter the Great St. Petersburg Polytechnic University, Politekhnicheskaya ul. 29, St. Petersburg, 195251, Russia

    E. F. Panarin

  3. St. Petersburg State University, Universitetskaya nab. 7/8, St. Petersburg, 199034, Russia

    G. M. Pavlov

Authors
  1. O. A. Dommes
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  2. O. V. Okatova
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  3. A. A. Kostina
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  4. I. I. Gavrilova
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  5. E. F. Panarin
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  6. G. M. Pavlov
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Corresponding author

Correspondence to G. M. Pavlov.

Additional information

Original Russian Text © O.A. Dommes, O.V. Okatova, A.A. Kostina, I.I. Gavrilova, E.F. Panarin, G.M. Pavlov, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya C, 2017, Vol. 59, No. 1, pp. 131–139.

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Dommes, O.A., Okatova, O.V., Kostina, A.A. et al. Dimensions and conformations of macromolecules of N-methyl-N-vinylacetamide and N-methyl-N-vinylamine hydrochloride in solutions in a wide interval of ionic strength. Polym. Sci. Ser. C 59, 125–132 (2017). https://doi.org/10.1134/S1811238217010039

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  • DOI: https://doi.org/10.1134/S1811238217010039

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