Skip to main content
Log in

Epoxy polymers modified with polyetherimide. Part II: physicomechanical properties of modified epoxy oligomers and carbon fiber reinforced plastics based on them

  • Original Paper
  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Abstract

The influence of the Ultem-1010 polyetherimide (PEI) on the physicomechanical properties of the ED-20 epoxy matrix and carbon-fiber-reinforced plastics (CFRP) based on the epoxy-polyetherimide binders is studied. It is shown that the introduction of PEI allows one to increase the impact strength and fracture toughness of the matrix 70 and 350%, respectively. The fracture toughness of the CFRP increases 40% with the rise in the PEI concentration. The correlation between the fracture toughness of the composites and their matrices has been established.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15

Similar content being viewed by others

References

  1. Richardson MOW (1977) Technology and engineering. Applied Science Publishers, London

    Google Scholar 

  2. Lubin G (1982) Handbook of composites. Van Nostrand Reinhold, New York

    Book  Google Scholar 

  3. Kerber ML (2008) Polymer composite materials: structure, properties, technologies. Profession Publishing, St. Petersburg (in russian)

    Google Scholar 

  4. Katz HS, Mileski JV (1988) Handbook of fillers for plastics. Springer, New York

    Google Scholar 

  5. Fiedler B, Gojny FH, Malte HG et al (2006) Fundamental aspects of nano-reinforced composites. Composit Sci Technol 66:2006

    Google Scholar 

  6. Tjong SC (2006) Structural and mechanical properties of polymer nanocomposites. Mater Sci Eng R Rep 53:73–197

    Article  Google Scholar 

  7. Huang X, Zhi C (eds) (2016) Polymer nanocomposites: electrical and thermal properties

  8. Zheng S, Guo Q, Mi Y (2003) Miscibility and phase behavior in blends of phenolphthalein poly(ether sulfone) and poly(hydroxyether of bisphenol A). Polymer 44:867–876

    Article  CAS  Google Scholar 

  9. Gorbunova IYu, Shustov MV, Kerber ML (2003) Effect of thermoplastic modifiers on the properties and cure process of epoxy polymers. J Eng Phys Thermophys 3:573–576

    Google Scholar 

  10. Bejoy Francis B, Poel GV, Posadaet F et al (2003) Cure kinetics and morphology of blends of epoxy resin with poly (ether ether ketone) containing pendant tertiary butyl groups. Polymer 44(13):3687–3699

    Article  Google Scholar 

  11. Solodilov VI, Korokhin RA, Gorbatkina YuA, Kuperman AM (2012) Organic fiber reinforced plastics based on complex hybrid matrices including polysulfone and carbon nanotubes as modifiers of epoxy resins. Russian J Phys Chem B 6(3):425–432

    Article  CAS  Google Scholar 

  12. Solodilov VI, Gorbatkina YuA (2006) Properties of unidirectional GFRPs based on an epoxy resin modified with polysulphone or an epoxyurethane oligomer. Mech Compos Mater 42(6):513–526

    Article  CAS  Google Scholar 

  13. Kuperman AM, Zelenskii ES, Kerber ML (1996) Glass-reinforced plastics based on matrices combining thermoplastics and thermosetting plastics. Mech Compos Mater 32(6):81–85

    Article  Google Scholar 

  14. Solodilov VI, Bazhenov SL, Gorbatkina YuA, Kuperman AM (2003) Determination of the interlaminar fracture toughness of glass-fiber-reinforced plastics on ring segments. Mech Compos Mater 39(5):407–414

    Article  Google Scholar 

  15. Solodilov VI, Korokhin RA, Gorbatkina YuA, Kuperman AM (2015) Comparison of fracture energies of epoxy-polysulfone matrices and unidirectional composites based on them. Mech Compos Mater 51(2):177–190

    Article  CAS  Google Scholar 

  16. Mikhailin AY (2006) Thermostable polymers and polymer materials. Profession Publishing, St. Petersburg (in Russian)

    Google Scholar 

  17. Mimura K, Ito H, Fujioka H (2000) Improvement of thermal and mechanical properties by control of morphologies in PES-modified epoxy resins. Polymer 41:4451–4459

    Article  CAS  Google Scholar 

  18. Zhong Z, Zheng S et al (1998) Phase behavior and mechanical properties of epoxy resin containing phenolphthalein poly(ether ether ketone). Polymer 39:1075–1080

    Article  CAS  Google Scholar 

  19. Kishi H, Shi Y-B et al (1997) Shear ductility and toughenability study of highly cross-linked epoxy/polyethersulphone. J Mater Sci 32:761–771

    Article  CAS  Google Scholar 

  20. Larracaga M, Mondragon I, Riccardi CC (2007) Miscibility and mechanical properties of an amine-cured epoxy resin blended with poly(ethylene oxide). Polym Int 56:426–433

    Article  Google Scholar 

  21. Liu R, Wang J, Li J, Jian X (2015) An investigation of epoxy/thermoplastic blends based on addition of a novel copoly(aryl ether nitrile) containing phthalazinone and biphenyl moieties. Polym Int 64(12):1786–1793

    Article  CAS  Google Scholar 

  22. Brooker RD, Kinloch AJ, Taylor AC (2010) The morphology and fracture properties of thermoplastic-toughened epoxy polymers. J Adhes 86(7):726–741

    Article  CAS  Google Scholar 

  23. Jang J, Lee W (1994) Polyetherimide-modified high performance epoxy resin. Polym J 26:513–525

    Article  CAS  Google Scholar 

  24. Kinloch AJ, Yuen ML, Jenkins SD (1994) Thermoplastic-toughened epoxy polymers. J Mater Sci 29(14):3781–3790

    Article  CAS  Google Scholar 

  25. Bucknall CB, Gilbert AH (1989) Toughening tetrafunctional epoxy resins using polyetherimide. Polymer 304:213–217

    Article  Google Scholar 

  26. Cho J, Hwang J, Cho K, An J, Park C (1993) Effects of morphology on toughening of tetrafunctional epoxy resins with poly (ether imide). Polymer 34:4832–4836

    Article  CAS  Google Scholar 

  27. Murakami A, Saunders D, Ooishi T et al (1992) Fracture behaviour of thermoplastic modified epoxy resins. J Adhes 39:227–242

    Article  Google Scholar 

  28. Park J-M, Kim D-S, Kong J-W et al (2007) Interfacial evaluation and self-sensing on residual stress and microfailure of toughened carbon fiber/epoxy-amine terminated (AT)-polyetherimide (PEI) composites. Composit B Eng 38(7–8):833–846

    Article  Google Scholar 

  29. Woo EM, Mao KL (1996) Evaluation of interlaminar-toughened poly(etherlmide)-modified epoxy/carbon fiber composites. Polym Compos 17(6):799–805

    Article  CAS  Google Scholar 

  30. Murakami A, Shonaike GO, Ooishi K et al (2000) Fracture toughness of PEI modified epoxy resin CFRP composites. J Reinf Plast Compos 19:137–151

    Article  CAS  Google Scholar 

  31. Shin S, Jang J (2000) The effect of thermoplastic coating on the mechanical properties of woven fabric carbon-epoxy composites. J Mater Sci 35:2047–2054

    Article  CAS  Google Scholar 

  32. Woo EM, Mao KL (1996) Interlaminar morphology effects on fracture resistance of amorphous polymer-modified epoxy/carbon fibre composites. Compos A Appl Sci Manuf 27:625–631

    Article  Google Scholar 

  33. Wu SJ, Lin TK et al (2000) Properties of cyanate ester-cured epoxy/polyphenylene oxide blends as a matrix material for Kevlar fiber composites. J Adhes Sci Technol 14(11):1423–1438

    Article  CAS  Google Scholar 

  34. Babaevsky PG, Kulik SG (1991) Crack resistance of the cured polymer compositions. Khimia, Moscow (in russian)

    Google Scholar 

  35. Babayevsky PG (1980) Workshop on polymeric materials. Khimia, Moscow (in russian)

    Google Scholar 

  36. Tarnopolsky YM, Cincis TY (1975) Methods of static tests of reinforced plastics. Khimia, Moscow (in russian)

    Google Scholar 

  37. Budylin NY, Shapagin AV, Chalykh AE (2012) Comparative study of interdiffusion and phase states in the blends of epoxy oligomers with polysulfones and polyethersulfones. Struct Dyn Mol Syst 2:190–193

    Google Scholar 

Download references

Acknowledgements

This work was done on the Theme No. 45.11 of the State assignment of The Federal Agency for Scientific Organizations (FASO Russia) (the Theme of FASO Russia Number: 0082-2014-0009, State Registration Number: AAAA-A17-117040610309-0).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. A. Korokhin.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Korokhin, R.A., Solodilov, V.I., Zvereva, U.G. et al. Epoxy polymers modified with polyetherimide. Part II: physicomechanical properties of modified epoxy oligomers and carbon fiber reinforced plastics based on them. Polym. Bull. 77, 2039–2057 (2020). https://doi.org/10.1007/s00289-019-02841-9

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-019-02841-9

Keywords

Navigation