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MECHANOCHEMISTRY

Delving into dynamic effects

Although the application of force to induce chemical transformations is an active area of research, detailed understanding of these mechanochemical pathways is still lacking. Now, the mechanochemical activation of [4]-ladderane has been studied and found to exhibit unique non-equilibrium dynamic effects.

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Fig. 1: Cascade unzipping reaction of [4]-ladderane.

References

  1. James, S. L. & Friščić, T. Chem. Soc. Rev. 42, 7494–7496 (2013).

    Article  CAS  Google Scholar 

  2. Chen, Z. et al. Nat. Chem. https://doi.org/10.1038/s41557-019-0396-5 (2020).

  3. Spring, W. Bull. Soc. Chim. Fr. 39, 641–647 (1883).

    Google Scholar 

  4. Spring, W. Bull. Soc. Chim. Fr. 40, 195–196 (1883).

    Google Scholar 

  5. Lea, M. C. Am. J. Sci. 43, 527–531 (1892).

    Article  Google Scholar 

  6. Gilman, J. J. Science 274, 65 (1996).

    Article  CAS  Google Scholar 

  7. Takacs, L. Chem. Soc. Rev. 42, 7649–7659 (2013).

    Article  CAS  Google Scholar 

  8. Brantley, J. N., Wiggins, K. M. & Bielawski, C. W. Polym. Int. 62, 2–12 (2013).

    Article  CAS  Google Scholar 

  9. Black, A. L., Lenhardt, J. M. & Craig, S. L. J. Mater. Chem. 21, 1655–1663 (2011).

    Article  CAS  Google Scholar 

  10. Chen, D., Sharma, S. K. & Mudhoo, A. Handbook on Applications of Ultrasound: Sonochemistry for Sustainability (CRC Press, 2011).

  11. Cravotto, G., Gaudinoa, E. C. & Cintas, P. Chem. Soc. Rev. 42, 7521–7534 (2013).

    Article  CAS  Google Scholar 

  12. Ong, M. T., Leiding, J., Tao, H., Virshup, A. M. & Mart¡nez, T. J. J. Am. Chem. Soc. 131, 6377–6379 (2009).

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was performed under the auspices of the US Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344.

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Correspondence to Vincenzo Lordi.

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Lordi, V. Delving into dynamic effects. Nat. Chem. 12, 225–226 (2020). https://doi.org/10.1038/s41557-020-0435-2

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