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Magnetic properties of (1 − x)Bi0.5Na0.5TiO3 + xSrCoO3 − δ solid-solution materials

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Abstract

(1 − x)Bi0.5Na0.5TiO3 + xSrCoO3 − δ solid-solution system was synthesised through the simple sol–gel technique. X-ray diffraction and Raman scattering analyses were used to study the structure of (1 − x)Bi0.5Na0.5TiO3 + xSrCoO3 − δ system. Results showed that the SrCoO3 − δ materials dissolved well into the host Bi0.5Na0.5TiO3 crystal. The random incorporation of Sr and Co cations into the host Bi0.5Na0.5TiO3 crystal to form a solid solution resulted in reduced optical band-gap energy and induced the complex magnetic properties of host Bi0.5Na0.5TiO3 materials. The optical band-gap energy of pure Bi0.5Na0.5TiO3 materials was estimated to be approximately 3.09 eV, which decreased to 2.18 eV for 9 mol% SrCoO3 − δ solute incorporated into Bi0.5Na0.5TiO3 materials. The magnetic properties of Bi0.5Na0.5TiO3 materials were tuned as a function of SrCoO3 − δ concentration added into the host Bi0.5Na0.5TiO3 materials. The enhanced magnetic performance in SrCoO3 − δ-modified Bi0.5Na0.5TiO3 materials can be possibly applied in multifunction materials for electronic devices.

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Authors and Affiliations

  1. Department of General Physics, School of Engineering Physics, Ha Noi University of Science and Technology, 1 Dai Co Viet Road, Ha Noi, Viet Nam

    Dang Duc Dung

  2. Department of Physics, Faculty of Basic and Fundamental Sciences, Viet Nam Maritime University, 484, Lach Tray street, Hai Phong City, Viet Nam

    Nguyen The Hung

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  2. Nguyen The Hung
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Dung, D.D., Hung, N.T. Magnetic properties of (1 − x)Bi0.5Na0.5TiO3 + xSrCoO3 − δ solid-solution materials. Appl. Phys. A 126, 240 (2020). https://doi.org/10.1007/s00339-020-3409-8

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