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Effect of the Sintering Process on the Structure, Colorimetric, Optical and Photoluminescence Properties of SrWO4 Phosphor Powders

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Abstract

Scheelite-type strontium tungstate (SrWO4) phosphor powders were successfully synthesized using strontium nitrate and tungstic acid as starting materials by a gamma-ray irradiation-assisted polyacrylamide gel route. The phase purity, structure, functional groups, surface morphology, chemical composition, colorimetric, optical and photoluminescence properties of SrWO4 phosphor powders were systematically studied by various testing instruments. The crystallite size of SrWO4 phosphor powders increases with the increasing of sintering temperature. The color, optical and photoluminescence properties of SrWO4 phosphor powders are strongly dependent on the sintering temperature, carbon chain and the distortion of tetrahedral [WO4] clusters. The fluorescence emission at (310 nm, 338 nm, 360 nm and 400 nm) and 465 nm can be ascribed to the new energy level formed by a carbon chain, amorphous SrWO4 or oxygen vacancy, and the distortion of tetrahedral [WO4] clusters, respectively.

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Acknowledgments

This work was supported by the Talent Introduction Project (09924601), Major Cultivation Projects (18ZDPY01) and Research Project of Higher Education Teaching Reform (JGZC1903) of Chongqing Three Gorges University, the Chongqing Basic Research and Frontier Exploration (general project) (cstc2019jcyj-msxmX0310, cstc2018jcyjAX0599) and the Science and Technology Research Program of Chongqing Education Commission of China (KJQN201901, KJZD-M201901201).

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Authors and Affiliations

  1. School of Electronic and Information Engineering, Chongqing Three Gorges University, Chongqing, Wanzhou, 404000, China

    Shifa Wang, Huajing Gao, Yong Wang, Guangzhuang Sun, Xinxin Zhao, Hufeng Liu & Chaoli Chen

  2. Chongqing Key Laboratory of Geological Environment Monitoring and Disaster Early-Warning in Three Gorges Reservoir Area, Chongqing Three Gorges University, Chongqing, Wanzhou, 404000, China

    Shifa Wang

  3. School of Science, Lanzhou University of Technology, Lanzhou, 730050, China

    Huajing Gao

  4. Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing, 400714, China

    Liang Yang

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  1. Shifa Wang
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Wang, S., Gao, H., Wang, Y. et al. Effect of the Sintering Process on the Structure, Colorimetric, Optical and Photoluminescence Properties of SrWO4 Phosphor Powders. J. Electron. Mater. 49, 2450–2462 (2020). https://doi.org/10.1007/s11664-020-07941-1

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