Abstract
This work is devoted to kinetic modelling of levulinic acid (LA) hydrogenation to gamma-valerolactone (GVL) in aqueous medium in a batch mode using 5%-Ru/MN100 catalyst, which comprises Ru dioxide nanoparticles confined in polymeric network of hyper-crosslinked polystyrene of MN100 type. Kinetic models of liquid-phase hydrogenation of LA to GVL were proposed based on Langmuir–Hinshelwood and Eley–Rideal mechanisms. Calculations based on experimental data obtained during the study allowed determining the main kinetic parameters of LA hydrogenation reaction and to propose the rate expression adequately describing the catalytic process. Moreover, hypothesis on the reaction mechanism was proposed considering RuO2 as catalytically active phase and 4-hydroxypentanoic acid as main intermediate compound.
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Acknowledgements
The authors thank Dr. Barry Stein (Department of Biology, Indiana University, United States) and Dr. Lyudmila Bronstein (Department of Chemistry, Indiana University, United States) for help with TEM studies, and also Dr. A.S. Morozov and Dr. I.V. Bessonov (JSC «Advanced medical technologies», Russia) for help with SEM/EDX studies.
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Financial support was provided by the Russian Foundation for Basic Research (Project 18–58-80008) and the Russian Science Foundation (Project 19–19-00490).
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The manuscript was written through contributions of all authors (I.I.P., L.Z.N., V.G.M., E.M.S.). All the authors have given approval to the final version of the manuscript.
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Protsenko, I.I., Nikoshvili, L.Z., Matveeva, V.G. et al. Kinetic Modelling of Levulinic Acid Hydrogenation Over Ru-Containing Polymeric Catalyst. Top Catal 63, 243–253 (2020). https://doi.org/10.1007/s11244-020-01223-0
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DOI: https://doi.org/10.1007/s11244-020-01223-0