Abstract
The possibility of sorption and cocrystallization binding of lead(n) with nanohydroxyapatite (HAP) acting as a potential carrier of short-lived lead radionuclides 211,212Pb was studied. The peculiarities of the kinetics were revealed, and the isotherms of sorption of lead ions on hydroxyapatite with different textures were constructed. A multistage sorption mechanism accompanied by a change in the structure and morphology of the sorbent was studied. The possibility of the formation of a new phase (hydroxypyromorphite) of lead during the sorption and cocrystallization interaction was shown. The introduction of lead into the synthesis of HAP at the early stages of crystallization exerts the highest effect on its morphology and structure. The optimization of the formation of the HAP-Pb composite over the course of the process will make it possible to use the short-lived 211Pb radionuclide in subsequent experiments.
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This work was financially supported by the Russian Foundation for Basic Research (Projects Nos 18-03-00432 and 19-08-00055) using the equipment of the Research and Educational Center for Collective Use at the Chemical Department of the M. V. Lomonosov Moscow State University “Nanochemistry and Nanomaterials. Chemistry of Atmosphere.”
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2197–2204, December, 2019.
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Severin, A.V., Orlova, M.A., Shalamova, E.S. et al. Nanohydroxyapatite and its textures as potential carriers of promising short-lived lead isotopes. Russ Chem Bull 68, 2197–2204 (2019). https://doi.org/10.1007/s11172-019-2688-8
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DOI: https://doi.org/10.1007/s11172-019-2688-8