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Spectral Characteristics of Mechanochemically Prepared Perovskite CH3NH3PbBr3 Nanoparticles Passivated by Amines with Different Alkyl Chain Length

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Theoretical and Experimental Chemistry Aims and scope

We are the first to establish that the introduction of a small amount of passivating amine (Am) during the preparation of CH3NH3PbBr3 (MAPbBr3) (MA/Am = 0.7) leads to the formation of pseudo-2D nanoparticles of this hybrid perovskite, the number of layers in which decreases going from oleylamine to hexylamine. The use of a solution of polystyrene in toluene yields more homogeneous in size stabilized MAPbBr3 nanoparticles and alters the number of layers in them. The resultant MAPbBr3 dispersions and films have strong photoluminescence (PL), whose maximum is shifted toward higher energies in comparison with a powder of this hybrid perovskite due to a quantum size effect. Dispersions and films of MAPbBr3 prepared using oleylamine have the highest PL quantum yield (about 90%) due to the formation of 2D nanoparticles with ≥ 4 layers. An advantage of the MAPbBr3 samples prepared using hexylamine is increased color purity of the PL.

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References

  1. H. Wei, Y. Fang, P. Mulligan, et al., Nat. Photonics, 10, 333-339 (2016).

    Article  CAS  Google Scholar 

  2. S. A. Veldhuis, P. P. Boix, N. Yantara, et al., Adv. Mater., 28, No. 32, 6804-6834 (2016).

    Article  CAS  Google Scholar 

  3. Y. Zhao and K. Zhu, Chem. Soc. Rev., 45, No. 3, 655-689 (2016).

    Article  CAS  Google Scholar 

  4. H. Sun, Z. Yang, M. Wei, et al., Adv. Mater., 28, No. 34, 1701153 (1-9) (2017).

  5. Y. Hassan, Y. Song, R. D. Pensack, et al., Adv. Mater., 28, No. 3, 566-573 (2016).

    Article  CAS  Google Scholar 

  6. E. Mosconi, J. M. Azpiroz, and F. De Angelis, Chem. Mater., 27, No. 13, 4885-4892 (2015).

    Article  CAS  Google Scholar 

  7. F. Zhang, H. Zhong, C. Chen, et al., ACS Nano, 9, No. 4, 4533-4542 (2015).

    Article  CAS  Google Scholar 

  8. B. Luo, Y.-C. Pu, S. A. Lindley, et al., Angew. Chem. Int. Ed., 55, No. 31, 8864-8868 (2016).

    Article  CAS  Google Scholar 

  9. L. C. Schmidt, A. Pertegas, S. Gonzalez-Carrero, et al., J. Am. Chem. Soc., 136, No. 3, 850-853 (2014).

    Article  CAS  Google Scholar 

  10. B. Luo, Y.-C. Pu, Y. Yang, et al., J. Phys. Chem. C, 119, No. 47, 26672-26682 (2015).

    Article  CAS  Google Scholar 

  11. H. Huang, A. S. Susha, S. V. Kershaw, et al., Adv. Sci., 2, No. 9, 1500194 (2015).

    Article  Google Scholar 

  12. L. Protesescu, S. Yakunin, M. I. Bondarchuk, et al., Nano Lett., 15, No. 6, 3692-3696 (2015).

    Article  CAS  Google Scholar 

  13. X. Ji, X. Peng, Q. Wang, et al., Org. Electron., 52, 350-355 (2018).

    Article  CAS  Google Scholar 

  14. V. M. Sorokin, N. V. Konoshchuk, D. M. Khmil, et al., Teor. Éksp. Khim., 55, No. 4, 201-209 (2019). [Theor. Exp. Chem., 55, No. 4, 223-231 (2019) (English translation).]

    Google Scholar 

  15. A. J. Gordon and R. A. Ford, The Chemist’s Companion, Wiley, New York (1972).

    Google Scholar 

  16. Y. Wei, X. Deng, Z. Xie, et al., Adv. Funct. Mater., 27, No. 39, 1703535 (2017).

    Article  Google Scholar 

  17. O. Yu. Posudievsky, N. V. Konoshchuk, A. G. Shkavro, et al., ACS Appl. Nano Mater., 1, No. 8, 4145-4155 (2018).

    Article  CAS  Google Scholar 

  18. A. M. Brouwer, Pure Appl. Chem., 83, No. 12, 2213-2228 (2011).

    Article  CAS  Google Scholar 

  19. R. E. Kellogg and R. G. Bennett, J. Chem. Phys., 41, No. 10, 3042-3045 (1964).

    Article  CAS  Google Scholar 

  20. A. Jana, M. Mittal, A. Singla, and S. Sapra, Chem. Commun., 53, 3046-3049 (2017).

    Article  CAS  Google Scholar 

  21. K.-H. Wang, L.-C. Li, M. Shellaiah, and K. W. Sun, Sci. Rep., 7, 13643 (2017).

    Article  Google Scholar 

  22. P. Tyagi, S. M. Arveson, W. A. Tisdale, et al., J. Phys. Chem. Lett., 6, No. 10, 1911-1916 (2015).

    Article  CAS  Google Scholar 

  23. X. Kong, K. Zong, and S. S. Lee, Chem. Mater., 31, No. 14, 4953-4970 (2019).

    Article  CAS  Google Scholar 

  24. Y. Rakita, N. Kedem, S. Gupta, et al., Cryst. Growth Des., 16, No. 10, 5717-5725 (2016).

    Article  CAS  Google Scholar 

  25. G. C. Papavassiliou, G. A. Mousdis, and G. C. Anyfantis, Z. Naturforsch., 65, No. 4, 516-520 (2010).

    Article  CAS  Google Scholar 

  26. J. A. Sichert, Y. Tong, N. Mutz, et al., Nano Lett., 15, No. 10, 6521-6527 (2015).

    Article  CAS  Google Scholar 

  27. J. Cho, Y.-H. Choi, T. E. O’Loughlin, et al., Chem. Mater., 28, No. 19, 6909-6916 (2016).

    Article  CAS  Google Scholar 

  28. V. A. Hintermayr, A. F. Richter, F. Ehrat, et al., Adv. Mater., 28, No. 43, 9478-9485 (2016).

    Article  CAS  Google Scholar 

  29. I. Levchuk, P. Herre, M. Brandl, et al., Chem. Commun., 53, 244-247 (2007).

    Article  Google Scholar 

  30. D. Sapori, M. Kepenekian, L. Pedesseau, et al., Nanoscale, 8, No. 12, 6369-6378 (2016).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. L. V. Pysarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Nauky Ave., 31, Kyiv, 03028, Ukraine

    N. V. Konoshchuk, O. Yu. Posudievsky, V. G. Koshechko & V. D. Pokhodenko

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  1. N. V. Konoshchuk
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  2. O. Yu. Posudievsky
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  3. V. G. Koshechko
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  4. V. D. Pokhodenko
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Correspondence to N. V. Konoshchuk.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 55, No. 5, pp. 288-295, September-October, 2019.

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Konoshchuk, N.V., Posudievsky, O.Y., Koshechko, V.G. et al. Spectral Characteristics of Mechanochemically Prepared Perovskite CH3NH3PbBr3 Nanoparticles Passivated by Amines with Different Alkyl Chain Length. Theor Exp Chem 55, 316–323 (2019). https://doi.org/10.1007/s11237-019-09623-4

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  • DOI: https://doi.org/10.1007/s11237-019-09623-4

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