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Compressibility and structure behaviour of maruyamaite (K-tourmaline) from the Kokchetav massif at high pressure up to 20 GPa

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Abstract

The structural behaviour of maruyamaite (K-dominant tourmaline) X(K0.54Na0.28Ca0.19)Y(Mg1.3Al1.17Fe0.39Ti0.14)Z(Al5Mg)[Si5.95Al0.05O18](BO3)3V,W[O1.69(OH)2.31] from the ultrahigh-pressure metamorphic rocks of Kokchetav massif was studied using synchrotron based single-crystal diffraction up to 20 GPa. Within the whole pressure range the compression is regular and anisotropic, with the c direction being more compressible than the a direction. Fitting the V/P data with the 2nd and 3rd order Birch-Murnaghan equations of state gives: V0 = 1587.2(7) Å3, K0 = 115.6(9) GPa at fixed K′ = 4, and V0 = 1588(1) Å3, K0 = 112(3) GPa, K′ = 4.5(4). The bulk modulus values are slightly higher as compared to those found for dravite and cation-deficient synthetic K-dravite. The pressure evolution of the main structural parameters of K-tourmaline is similar to those of dravite. However, a minor change in the rigidity of local contacts of the X site with 6-membered ring, due to the presence of K, is apparently critical for stabilization of tourmaline structure within 15–20 GPa, which is evinced by the absence of the phase transition observed in dravite near 15.4 GPa. The stabilizing function of K becomes apparent at P > 15 GPa. The comparison of the HP structural behaviour of maruyamaite and dravite supports the recent suggestion that the large X site plays a secondary role in the elastic behaviour of tourmaline, compared to the octahedral framework. In addition, the present study reveals several new features of polyhedra distortions, which demonstrate their complex interaction on compression.

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Acknowledgements

The authors are grateful to J. Cempírek and an anonymous reviewer for their helpful remarks, as well as to Yu.V. Seryotkin for valuable discussion of the results. This study is supported by the Russian Scientific Foundation (project 18-17-00186). Diffraction experiments were carried at the European Synchrotron Radiation Facility and supported by approval of ESRF Proposal ES-810.

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Authors and Affiliations

  1. V.S. Sobolev Institute of Geology and Mineralogy SibD RAS, pr. ak. Koptyuga 3, 630090, Novosibirsk, Russia

    Anna Yu. Likhacheva, S. V. Rashchenko, Kira A. Musiyachenko & Andrey V. Korsakov

  2. Novosibirsk State University, Pirogova str. 1, 630090, Novosibirsk, Russia

    S. V. Rashchenko

  3. European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000, Grenoble, France

    Ines E. Collings & Michael Hanfland

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  1. Anna Yu. Likhacheva
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Correspondence to Anna Yu. Likhacheva.

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Fig. S1

F-f plots based on the Birch-Murnaghan 2nd order (a) and 3rd order (b) EoS fit of the pressure volume data for maruyamaite. (PNG 135 kb)

High Resolution Image (EPS 6239 kb)

Fig. S2

Pressure dependence of the T6O18 ring ditrigonality in maruyamaite (solid symbols) and dravite (empty symbols, data compiled from O’Bannon et al. 2018) structure. (PNG 32 kb)

High Resolution Image (EPS 63 kb)

Fig. S3

Pressure dependence of the T6O18 ring puckering in maruyamaite (solid symbols) and dravite (empty symbols, data compiled from O’Bannon et al. 2018) structure. (PNG 41 kb)

High Resolution Image (EPS 64 kb)

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Likhacheva, A.Y., Rashchenko, S.V., Musiyachenko, K.A. et al. Compressibility and structure behaviour of maruyamaite (K-tourmaline) from the Kokchetav massif at high pressure up to 20 GPa. Miner Petrol 113, 613–623 (2019). https://doi.org/10.1007/s00710-019-00672-0

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