Abstract
The gas chromatographic properties of the porous methacrylate polymers, copolymers of 2,3-epoxypropyl methacrylate (2,3-EPMA) and ethylenedimethacrylate (EDMA), modified by silver nanoparticles were studied. The modification of the initial methacrylate copolymer by silver nanoparticles almost does not change the ability of the copolymer to dispersion interaction but results in an increase in polarity and enhances the possibility of specific interactions to occur. The aminated copolymer (copolymer of 2,3-EPMA and EDMA modified by diethylenetriamine using the reaction at the epoxy group) modified by silver nanoparticles demonstrates a higher ability to dispersion interactions and a lower polarity. Possibly, the sorption of silver particles on amino groups of the polymer is a reason for decreasing polarity of the polymer.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. A. Davankov, M. P. Tsyurupa, Comprehensive Anal. Chem., 2011, 56, 670.
N. P. Platonova, A. K. Buryak, A. V. Ul’yanov, Z. K. Blinnikova, V. A. Davankov, M. P. Tsyurupa, Sorbtsionnye i khromatograficheskie protsessy [Sorption and Chromatographic Processes], 2012, 12, 575 (in Russian).
T. N. Zhabkina, A. N. Krechetnikova, A. A. Revina, Khranenie i pererabotka sel’khozsyr’ya [Storage and Processing of Agricultural Raw Materials], 2005, No. 5, 9 (in Russian).
F. Svec, J. Hradil, J. Coupek, J. Kalal, Angew. Makromol., 1975, 48, 135.
A. G. Dokuchaev, T. G. Myasoedova, A. A. Revina, Khim. Vys. Energii, 1997, 31, 353 [High Energy Chem. (Engl. Transl.), 1997, 31].
A. A. Revina, RF Pat. No. 2322327; Byul. Izobr. [Invention Bulletin], 2008, 11 (in Russian).
O. G. Larionov, V. V. Petrenko, N. P. Platonova, J. Chromatogr., 1991, 552, 31.
N. P. Platonova, S. A. Borovikova, V. M. Sharapov, A. K. Buryak, Sorbtsionnye i khromatograficheskie protsessy [Sorption and Chromatographic Processes], 2018, 18, 860 (in Russian).
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1893–1896, October, 2019.
Rights and permissions
About this article
Cite this article
Platonova, N.P., Revina, A.A., Kul’kova, T.A. et al. Gas chromatographic properties of methacrylate polymers modified by silver nanoparticles. Russ Chem Bull 68, 1893–1896 (2019). https://doi.org/10.1007/s11172-019-2643-8
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-019-2643-8