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Thermochromic polydiacetylene supramolecules with oligo(ethylene oxide) headgroups for tunable colorimetric response

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In this effort, we have prepared PDA suspensions derived from oligoethylene oxide-containing DA monomers and investigated their colorimetric responses to thermal stimulation. Depending on the DA monomers employed, the PDA supramolecules displayed different initial color changing temperatures. In general, DA monomers having larger headgroups result in the generation of colorimetrically less stable PDA supramolecules. The results described in the current investigation should provide useful information about the design of colorimetrically tunable PDA supramolecules.

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Correspondence to Jong-Man Kim.

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Kim, J.W., Lee, C.H., Yoo, H.O. et al. Thermochromic polydiacetylene supramolecules with oligo(ethylene oxide) headgroups for tunable colorimetric response. Macromol. Res. 17, 441–444 (2009). https://doi.org/10.1007/BF03218887

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