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Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply

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Abstract

The CuO–CeO2/γ-Al2O3 systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(gcat h) and the DME : O2 : N2 molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH4 (≤0.8 mol %) and H2 production rate of ~3.1 L/(gcat h).

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REFERENCES

  1. Li, D., Li, X., and Gong, J., Chem. Rev., 2016, vol. 116, pp. 11529–11653.

    Article  CAS  PubMed  Google Scholar 

  2. Galvita, V.V., Semin, G.L., Belyaev, V.D., et al., Appl. Catal. A: Gen., 2001, vol. 216, pp. 85–90.

    Article  CAS  Google Scholar 

  3. Takeishi, K. and Suzuki, H., Appl. Catal. A: Gen., 2004, vol. 260, pp. 111–117.

    Article  CAS  Google Scholar 

  4. Pechenkin, A.A., Badmaev, S.D., Belyaev, V.D., et al., Appl. Catal. B: Env., 2015, vol. 166-167, pp. 535–543.

    Article  CAS  Google Scholar 

  5. Wang, S., Ishihara, T., and Takita, Y., Appl. Catal. A: Gen., 2002, vol. 228, pp. 167–176.

    Article  CAS  Google Scholar 

  6. Zhang, Q., Li, X., Fujimoto, K., et al., Appl. Catal. A: Gen., 2005, vol. 288, pp. 169–174.

    Article  CAS  Google Scholar 

  7. Chen, Y., Shao, Z., and Xu, N., J. Nat. Gas Chem., 2008, vol. 17, pp. 75–80.

    Article  CAS  Google Scholar 

  8. Zhang, Q., Du, F., He, X., et al., Catal. Today, 2009, vol. 146, pp. 50–56.

    Article  CAS  Google Scholar 

  9. Wachsman, E.D. and Lee, K.T., Science, 2011, vol. 334, pp. 935–939.

    Article  CAS  PubMed  Google Scholar 

  10. Chi, H., Andolina, C.M., Li, J., et al., Appl. Catal. A: Gen., 2018, vol. 556, pp. 64–72.

    Article  CAS  Google Scholar 

  11. Agrell, J., Birgersson, H., Boutonnet, M., et al., J. Catal., 2003, vol. 219, pp. 389–403.

    Article  CAS  Google Scholar 

  12. Badmaev, S.D., Belyaev, V.D., Volkova, G.G., et al., React. Kinet. Catal. Lett., 2007, vol. 90, pp. 197–204.

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by Ministry of Science and Higher Education of the Russian Federation (project no. AAAA-A17-117041710088-0).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    S. D. Badmaev, N. O. Akhmetov, A. A. Pechenkin, V. A. Sobyanin &  V. N. Parmon

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    S. D. Badmaev, N. O. Akhmetov, A. A. Pechenkin, V. A. Sobyanin &  V. N. Parmon

Authors
  1. S. D. Badmaev
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  2. N. O. Akhmetov
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  3. A. A. Pechenkin
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  4. V. A. Sobyanin
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  5. V. N. Parmon
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Correspondence to S. D. Badmaev.

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Translated by Z. Svitanko

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Badmaev, S.D., Akhmetov, N.O., Pechenkin, A.A. et al. Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply. Dokl Phys Chem 487, 95–98 (2019). https://doi.org/10.1134/S0012501619080013

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  • DOI: https://doi.org/10.1134/S0012501619080013

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