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Catalytic Performance and Kinetics of the Precursor of [Fe]-Hydrogenase in the Reaction of Phenol Hydroxylation in Aqueous Phase at Ambient Temperature

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Abstract

FeI2(CO)3PPh3, which usually used as the precursor of [Fe]-hydrogenase, was firstly used as catalyst in one-step hydroxylation of phenol to dihydroxybenzenes. It was found that the reaction can be conducted smoothly in aqueous phase at ambient temperature (25 °C). In the optimum conditions, the conversion of phenol is 26.7% and selectivity of DHB is 80.0%. The possible mechanism was investigated and proposed. The apparent kinetics study shows that it is a pseudo second order reaction and activation energy Ea is 66.36 kJ/mol.

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Acknowledgements

This work was supported by the National Key R&D Program of China [2017YFB0404701] and National Natural Science Foundation of China [21908161, 21276187, 21103121].

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Authors and Affiliations

  1. Tianjin Key Laboratory of Applied Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300354, China

    Li Hai, Tianyong Zhang, Shuang Jiang, Xiaoyuan Ma, Di Wang & Bin Li

  2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China

    Tianyong Zhang

  3. Tianjin Engineering Research Center of Functional Fine Chemicals, Tianjin, 300354, China

    Tianyong Zhang & Bin Li

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  1. Li Hai
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  2. Tianyong Zhang
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  3. Shuang Jiang
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  4. Xiaoyuan Ma
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  5. Di Wang
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  6. Bin Li
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Correspondence to Tianyong Zhang, Shuang Jiang or Bin Li.

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Hai, L., Zhang, T., Jiang, S. et al. Catalytic Performance and Kinetics of the Precursor of [Fe]-Hydrogenase in the Reaction of Phenol Hydroxylation in Aqueous Phase at Ambient Temperature. Catal Lett 150, 1238–1243 (2020). https://doi.org/10.1007/s10562-019-03060-7

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  • DOI: https://doi.org/10.1007/s10562-019-03060-7

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