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Utilizing an In Situ Reduction in the Synthesis of BaMoOF5

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Abstract

A new molybdenum containing oxyfluoride, BaMoOF5, space group Cmcm with lattice parameters of a = 7.1445(3), b = 6.7894(3), c = 10.1969(4), was synthesized via a mild hydrothermal crystal growth method. The synthesis resulted in high-quality single crystals of the title material, which were characterized by single-crystal X-ray diffraction. The structure is discussed in detail.

Graphical Abstract

A new Mo(V) oxyfluoride, BaMoOF5, was synthesized via a mild hydrothermal route that included an in-situ reduction step to reduce molybdenum from a starting oxidation state of 6+ to 5+.

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Acknowledgements

We gratefully acknowledge financial support from the United States Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering. Award number DE-SC0018739 funded this work.

Funding

The funding sponsors had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript, and in the decision to publish the results.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, SC, 29208, USA

    Justin B. Felder, Mark D. Smith & Hans-Conrad zur Loye

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  1. Justin B. Felder
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  2. Mark D. Smith
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  3. Hans-Conrad zur Loye
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Correspondence to Hans-Conrad zur Loye.

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10870_2018_767_MOESM1_ESM.pdf

Supplemental Information: The CIF for the reported composition has been deposited in both the ICSD: Number Pending and the CCDC: 1588566. (PDF 82 KB)

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Felder, J.B., Smith, M.D. & zur Loye, HC. Utilizing an In Situ Reduction in the Synthesis of BaMoOF5. J Chem Crystallogr 49, 52–57 (2019). https://doi.org/10.1007/s10870-018-00767-0

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  • DOI: https://doi.org/10.1007/s10870-018-00767-0

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