Skip to main content
SpringerLink
Log in

Kinetics and mechanism of oxidation of 2-Aminoethanol and 3-Amino-1-propanol by diperiodatoargentate(III) in alkaline medium

  • Published:
Journal of the Iranian Chemical Society Aims and scope Submit manuscript

Abstract

The kinetics of oxidation of 2-aminoethanol and 3-amino-1-propanol by diperiodatoargentate(III) (DPA) were carried out spectrophotometrically in alkaline medium in the temperature range of 293.2-308.2 K. The reaction showed first order with respect to [DPA] and each reductant. The observed rate constant (k obs) decreased with the increase of [IO4 -] and increased with the increase of [OH-]. Increasing ionic strength of the medium decreased the rate. Investigations of the reaction at different temperatures allowed the determination of the activation parameters for the slow step of proposed mechanism. The proposed mechanism and the derived rate laws found consistent with the observed kinetics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. Tegginamath, C.V. Hiremath, S.T. Nandibewoor, J. Phys. Org. Chem. 20 (2007) 55.

    CAS  Google Scholar 

  2. P.J. Rao, B. Sethuram, T.N. Rao, React. Kinet. Catal. 29 (1985) 289.

    CAS  Google Scholar 

  3. K.V. Krishna, P.J.P. Rao, Transition Met. Chem. 20 (1995) 344.

    CAS  Google Scholar 

  4. A. Kumar, Vaishali, P. Ramamurthy, Int. J. Chem. Kinet. 32 (2000) 286.

    CAS  Google Scholar 

  5. G. Sarala, P.J.P. Rao, T.N. Rao, Indian J. Chem. 26A (1987) 475.

    CAS  Google Scholar 

  6. J.H. Shan, S.M. Li, S.Y. Huo, J. Iran. Chem. Soc. 2 (2005)

    Google Scholar 

  7. J.H. Shan, S.M. Li, S.Y. Huo, Transition Met. Chem. 30 (2005) 651.

    Google Scholar 

  8. A. Kumar, P. Kumar, P. Ramamurthy, Polyhedron. 18 (1999) 773.

    CAS  Google Scholar 

  9. F. Feigl, Spot Tests in Organic Analysis, Elsevier Publishing Co., New York, 1956, p. 208.

    Google Scholar 

  10. J.J. Jin, Kinetics Principie of Chemical Reaction in Liquid Phase, Science Technique Press, Shanghai, 1984, pp. 186–218.

    Google Scholar 

  11. J.J. Aveston, Chem. Soc. A (1969) 273.

    Google Scholar 

  12. C.E. Crouthamel, H.V. Meek, D.S. Martin, C.V. Banks, J. Am. Chem. Soc. 71 (1949) 3031

    CAS  Google Scholar 

  13. C.E. Crouthamel, A.M. Hayes, D.S. Martin, J. Am. Chem. Soc. 73 (1951) 82.

    Google Scholar 

  14. H.G. Mukherjee, B. Mandal, S. De, Indian J. Chem. 23 (1984) 426.

    Google Scholar 

  15. J.H. Shan, T.Y. Liu, Acta Chim. Sin. 52 (1994) 1140.

    CAS  Google Scholar 

  16. S.A. Farokhi, S.T. Nandibewoor, Tetrahedron 59 (2003) 7595

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemistry and Environmental Science, Hebei University, Baoding, 071002, China

    H. Shan, H. Y. Wang, C. Y. Song & F. Wang

Authors
  1. H. Shan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Y. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. C. Y. Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. F. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. Shan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shan, H., Wang, H.Y., Song, C.Y. et al. Kinetics and mechanism of oxidation of 2-Aminoethanol and 3-Amino-1-propanol by diperiodatoargentate(III) in alkaline medium. JICS 6, 393–398 (2009). https://doi.org/10.1007/BF03245849

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03245849

Keywords

Search

Navigation