Abstract
Pd nanoparticles (NPs)/reduced graphene oxide (RGO) nanocomposite was prepared in a one-pot process by using Euphorbia stenoclada extract as antioxidant media in the absence of any surfactant, dangerous reactants or using external energy input. Catalytic potential of the fabricated Pd-RGO nanocomposite was examined for the degradation of environmental contaminants including Cr(VI), 4-nitrophenol (4-NP), Congo red (CR), methylene blue (MB) and methyl orange (MO). The Pd-RGO nanocomposite has been thoroughly characterized by employing X-ray diffraction, UV–Vis and TEM studies. Furthermore, recyclability and reusability aspects of the nanocomposite were monitored for multiple uses without much change in catalytic activity.
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Aslantürk ÖS, Aşkin Çelik T (2013) Antioxidant, cytotoxic and apoptotic activities of extracts from medicinal plant Euphorbia platyphyllos. J Med Plants Res 7(19):1293–1304
Bhowmik K, Mukherjee A, Mishra MK, De G (2014) Stable Ni nanoparticle-reduced graphene oxide composites for the reduction of highly toxic aqueous Cr(VI) at room temperature. Langmuir 30:3209–3216
Borah BJ, Barali P (2014) Surfactant-free synthesis of CuNi nanocrystals and their application for catalytic reduction of 4-nitrophenol. J Mol Catal A Chem 390:29–36
Chaabi M, Freund-Michel V, Frossard N, Randriantsoa A, Andriantsitohaina R, Lobstein A (2007) Anti-proliferative effect of Euphorbia stenoclada in human airway smooth muscle cells in culture. J Ethnopharmacol 109:134–139
Chen X, Cai Z, Chen X, Oyamac M (2014) AuPd bimetallic nanoparticles decorated on graphene nanosheets: their green synthesis, growth mechanism and high catalytic ability in 4-nitrophenol reduction. J Mater Chem A 2:5668–5674
Cheng F, Betts JW, Kelly SM, Schaller J, Heinze T (2013) Synthesis and antibacterial effects of aqueous colloidal solutions of silver nanoparticles using aminocellulose as a combined reducing and capping reagent. Green Chem 15:989–998
Chi Y, Yuan Q, Li YJ, Tu JC, Zhao L, Li N, Li XT (2012) Synthesis of Fe3O4@SiO2-Ag magnetic nanocomposite based on small-sized and highly dispersed silver nanoparticles for catalytic reduction of 4-nitrophenol. J Colloid Interface Sci 383:96–102
Dauthal P, Mukhopadhyay M (2012) Prunus domestica fruit extract-mediated synthesis of gold nanoparticles and its catalytic activity for 4-nitrophenol reduction. Ind Eng Chem Res 51:13014–13020
Fu G-T, Jiang X, Wu R, Wei S-H, Sun D-M, Tang Y-W, Lu T-H, Chen Y (2014) Arginine-assisted synthesis and catalytic properties of single-crystalline palladium tetrapods. ACS Appl Mater Interfaces 6:22790–22795
Geng X-L, Su Z-T (2005) Research on preparation of nano-copper powder by liquid-phase method. Appl Chem Ind 34(10):615–617
Ghosh BK, Hazra S, Naik B, Ghosh NN (2015) Preparation of Cu nanoparticle loaded SBA-15 and their excellent catalytic activity in reduction of variety of dyes. Powder Technol 269:371–378
Goyal A, Bansal S, Singhal S (2014) Facile reduction of nitrophenols: comparative catalytic efficiency of MFe2O4 (M = Ni, Cu, Zn) nano ferrites. Int J Hydrogen Energ 39:4895–4908
Guang C, Yongjian T, Wei L, Jiangshan L, Jun L, Tianzu Y (2005) The preparation technology and application of nanocrystalline copper powder. Met Funct Mater 12(3):18–21
Hebbalalu D, Lalley J, Nadagouda MN, Varma RS (2013) Greener techniques for the synthesis of silver nanoparticles using plant extracts, enzymes, bacteria, biodegradable polymers and microwaves. ACS Sustain Chem Eng 1:703–712
Jiang Z, Xie J, Jiang D, Wei X, Chen M (2013) Modifiers-assisted formation of nickel nanoparticles and their catalytic application to p-nitrophenol reduction. CrystEngComm 15:560–569
Khodadadi B, Bordbar M, Nasrollahzadeh M (2017) Green synthesis of Pd nanoparticles at apricot kernel shell substrate using Salvia hydrangea extract: catalytic activity for reduction of organic dyes. J Colloid Interface Sci 490:1–10
Li S, Guo S, Yang H, Gou G, Ren R, Li J, Dong Z, Jin J, Ma J (2014) Enhancing catalytic performance of Au catalysts by noncovalent functionalized graphene using functional ionic liquids. J Hazard Mat 270:11–17
Momeni SS, Nasrollahzadeh M, Rustaiyan A (2016) Green synthesis of the Cu/ZnO nanoparticles mediated by Euphorbia prolifera leaf extract and investigation of their catalytic activity. J Colloid Interface Sci 472:173–179
Mozafarian V (1996) A dictionary of Iranian plant names: Latin, English, Persian, Farhang e Mo’aser, Tehran, Iran, p 219
Nadagouda MN, Varma RS (2008) Green synthesis of silver and palladium nanoparticles at room temperature using coffee and tea extract. Green Chem 10:859–862
Nasrollahzadeh M, Sajadi SM, Maham M, Salaryan P, Enayati A, Sajjadi SA, Naderi K (2011) Optimal extraction method of phenolics from the root of Euphorbia condylocarpa. Chem Nat Compd 47:434–435
Nasrollahzadeh M, Sajadi SM, Rostami-Vartooni A, Khalaj M (2014) Journey on greener pathways: use of Euphorbia condylocarpa M. bieb as reductant and stabilizer for green synthesis of Au/Pd bimetallic nanoparticles as reusable catalysts in the Suzuki and Heck coupling reactions in water. RSC Adv 4:43477–43484
Qing-Chun C (2005) Hydrothermal conditions for fabrication of Cu nanorods and nanowires through reduction. Fine Chem 22(6):417–419
Seo E, Kim J, Hong Y, Kim YS, Lee D, Kim BS (2013) Double hydrophilic block copolymer templated Au nanoparticles with enhanced catalytic activity nitroarene reduction. J Phys Chem C 117:11686–11693
Su BY, Jia YZ, Zhang SQ, Chen XM, Oyama M (2014) Synthesis of palladium nanoparticles on citrate-functionalized graphene oxide with high catalytic activity for 4-nitrophenol reduction. Chem Lett 43:919–921
Varma RS (2012) Greener approach to nanomaterials and their sustainable applications. Curr Opin Chem Eng 1(2):123–128
Wang Z, Xu C, Gao G, Li X (2014) Facile synthesis of well-dispersed Pd-graphene nanohybrids and their catalytic properties in 4-nitrophenol reduction. RSC Adv 4:13644–13651
Wu K-L, Wei X-W, Zhou X-M, Wu D-H, Liu X-W, Ye Y, Wang Q (2011) NiCo2 alloys: controllable synthesis, magnetic properties, and catalytic applications in reduction of 4-nitrophenol. J Phys Chem C 115:16268–16274
Wu K-L, Yu R, Wei X-W (2012) Monodispersed FeNi2 alloy nanostructures: solvothermal synthesis, magnetic properties and size-dependent catalytic activity. CrystEngComm 14:7626–7632
Wu Y-G, Wen M, Wu Q-S, Fang H (2014) Ni/graphene nanostructure and its electron-enhanced catalytic action for hydrogenation reaction of nitrophenol. J Phys Chem C 118:6307–6313
Xu R, Bi H, He G, Zhu J, Chen H (2014) Synthesis of Cu-Fe3O4@graphene composite: a magnetically separable and efficient catalyst for the reduction of 4-nitrophenol. Mater Res Bull 57:190–196
Zhang P, Sui Y, Wang C, Wang Y, Cui G, Wang C, Liu B, Zou B (2014) A one-step green route to synthesize copper nanocrystals and their applications in catalysis and surface enhanced Raman scattering. Nanoscale 6:5343–5350
Acknowledgements
The supports provided by the University of Qom are appreciated. RSV gratefully acknowledges the support by the Operational Programme Research, Development and Education—European Regional Development Fund, Project No. CZ.02.1.01/0.0/0.0/16_019/0000754 of the Ministry of Education, Youth and Sports of the Czech Republic.
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Nasrollahzadeh, M., Jaleh, B., Baran, T. et al. Efficient degradation of environmental contaminants using Pd-RGO nanocomposite as a retrievable catalyst. Clean Techn Environ Policy 22, 325–335 (2020). https://doi.org/10.1007/s10098-019-01784-z
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DOI: https://doi.org/10.1007/s10098-019-01784-z