Abstract
A Ti–Zr alloy was prepared by magnesiothermic reduction from TiO2–ZrO2–Mg mixtures followed by acid leaching and the influence of leaching conditions on the quality of final product was explored. For nitric and hydrochloric acids as leaching agents, conditions for complete removal of MgO from crude TiZr–MgO combustion product had been optimized. The resistance of combustion-synthesized Ti–Zr alloy to elution with nitric acid was higher than that with hydrochloric acid.
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REFERENCES
Yang, B.C., Uchida, M., Kim, H.M., Zhang, X.D., and Kokubo, T., Preparation of bioactive titanium metal via anodic oxidation treatment, Biomaterials, 2004, vol. 25, no. 6, pp. 1003–1010. https://doi.org/10.1016/S0142-9612(03)00626-4
Kim, W.G., Choe, H.C., and Ko, Y.M., Electrochemical behavior of TiN-coated/nanotube-formed Ti–Zr alloy, J. Korean Phys. Soc., 2009, vol. 54, no. 3, pp. 1036−1041. https://doi.org/10.3938/jkps.54.1036
Kuroda, D., Niinomi, M., Morinaga, M., Kato, Y., and Yashiro, T., Design and mechanical properties of new β-type titanium alloys for implant materials, J. Mater. Sci. Eng. A, 1998, vol. 243, nos. 1–2, pp. 244−249. https://doi.org/10.1016/S0921-5093(97)00808-3
Northwood, D.O., The development and applications of zirconium alloys, Mater. Des., 1985, vol. 6, no. 2, pp. 58–70. https://doi.org/10.1016/0261-3069(85)90165-7
Kobayashi, E., Matsumoto, S., Doi, H., Yoneyama, T., and Hamanaka, H., Mechanical properties of the binary titanium–zirconium alloys and their potential for biomedical materials, J. Biomed. Mater. Res., 1995, vol. 29, no. 8, pp. 943–950. https://doi.org/10.1002/jbm.820290805
Luz, T., Henriques, V., de Oliveira, J., and Diniz, E., Production of Ti–Zr alloy by powder metallurgy, SAE Technical Paper 2013-36-0388, 2013. https://doi.org/10.4271/2013-36-0388
Lee, D.-W., Baek, Y-K., Lee, W.-J., and Wang, J.-P., Study on synthesis of Zr–Ti alloy powder using molten magnesium, J. Mater. Res. Innovations, 2013, vol. 17, no. 2, pp. 113–117. https://doi.org/10.1179/1432891713Z.000000000304
Vershinnikov, V.I., Kovalev, D.Yu., Ignat’eva, T.I., Aleshin, V.V., and Mikhailov, Yu.M., Feasibility of producing a Ti–Zr alloy via combustion in the TiO2–ZrO2–Mg system, Inorg. Mater., 2019, vol. 55, no. 2, pp. 83–88. https://doi.org/10.1134/S0020168519020146
Sangwal, K., Dissolution kinetics of MgO crystals in aqueous acidic salt solutions, J. Mater. Sci., 1982, vol. 17, no. 12, pp. 3598–3610. https://doi.org/10.1007/BF00752203
Sangwal, K., Mechanism of dissolution of MgO crystals in acids, J. Mater. Sci., 1980, vol. 15, no. 1, pp. 237–246. https://doi.org/10.1007/BF00552450
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This work was financially supported by the Russian Foundation for Basic Research (project no. 16-29-01035ofi_m).
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Translated by Yu. Scheck
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Ignat’eva, T.I., Vershinnikov, V.I., Semenova, V.N. et al. Ti–Zr Alloy by Magnesiothermic Reduction and Acid Leaching: Influence of Process Conditions. Int. J Self-Propag. High-Temp. Synth. 28, 187–190 (2019). https://doi.org/10.3103/S1061386219030075
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DOI: https://doi.org/10.3103/S1061386219030075