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Clinically Pertinent Manganese Oxide/Polyoxytyramine/Reduced Graphene Oxide Nanocomposite for Voltammetric Detection of Salivary and Urinary Arsenic

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Abstract

Arsenic (AsIII), a notorious environmental hazard poses threat to the lives of several hundred million people. Notwithstanding radical developments of AsIII detection in water, a fast, simple and sensitive electrochemical process with lower detection limit for the quantification of AsIII in saliva and urine samples has scarcely ever been tried. Here, we have detected the poisoning due to AsIII in the saliva and urine samples of tobacco-chewers/smokers using a novel one-pot synthesized MnO2/polyoxytyramine/rGO nanocomposite. The composite was characterized by various analytical techniques such as UV–Vis. and FT-IR spectroscopic analyses, XRD, SEM, TEM, EDAX and elemental mapping analyses. The proposed AsIII quantification system has a wide linearity range (0.01–0.900 ppb) and the lowest detection limit (42 parts per trillion).

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Acknowledgements

The “Catalyzed and Financial support” by Tamilnadu State Council for Science and Technology, Department of Higher Education, Government of Tamilnadu, India for the award of research funding for research scholars (RFRS) scheme (TNSCST/RFRS/VR/07/2018-19) is very much acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Thiagarajar College, Madurai, Tamil Nadu, 625 009, India

    Sathish Kumar Ponnaiah, Prakash Periakaruppan & Mohannivas Selvam

  2. Department of Microbiology and Immunology, Institute of Biomedical Sciences, College of Health Science, Mekelle University, 1871, Mekelle, Ethiopia

    Saravanan Muthupandian

  3. Department of Civil Engineering, Sethu Institute of Technology, Virudhunagar, Tamil Nadu, 626 115, India

    B. Jeyaprabha

  4. Department of Chemistry, Arul Anandar College, Karumathur, Tamil Nadu, 625 514, India

    Rayappan Selvanathan

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  1. Sathish Kumar Ponnaiah
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  2. Prakash Periakaruppan
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  4. Saravanan Muthupandian
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Correspondence to Prakash Periakaruppan.

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Ponnaiah, S.K., Periakaruppan, P., Selvam, M. et al. Clinically Pertinent Manganese Oxide/Polyoxytyramine/Reduced Graphene Oxide Nanocomposite for Voltammetric Detection of Salivary and Urinary Arsenic. J Clust Sci 31, 877–885 (2020). https://doi.org/10.1007/s10876-019-01696-4

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  • DOI: https://doi.org/10.1007/s10876-019-01696-4

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