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Direct Amination of Benzene with NH3 and H2O2 Over Hierarchical Fe,Cu/ZSM-5 Prepared by Post-synthesis Treatment of Nanocrystallite B–ZSM-5

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Abstract

Hierarchical Fe,Cu/ZSM-5 was prepared by post-synthesis treatment of nanocrystallite B–ZSM-5. The hierarchical MFI zeolites containing Fe and/or Cu were characterized with XRD, FT-IR, SEM, UV–Vis and N2-sorption techniques. UV–Vis and FT-IR spectroscopy demonstrated that some of the Fe and Cu cations were incorporated into the zeolite framework. Direct amination of benzene to aniline with H2O2 and NH3 was studied using a series of Fe and/or Cu doped ZSM-5 catalysts. The effect of Fe and/or Cu incorporation into ZSM-5 catalyst and crystallite size of the catalyst on the benzene conversion, product distribution and aniline selectivity in the direct amination reaction was investigated. Nanocrystallite hierarchical Fe,Cu/ZSM-5 exhibited the best catalytic oxido-amination performance (conversion of benzene was 23.7% and selectivity for aniline was 74.1%).

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Acknowledgements

Financial support from the NSFC of China, and technical support from the Analytical and Testing Centre of Yunnan University are cordially acknowledged.

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Authors and Affiliations

  1. School of Chemistry, Yunnan University, Kunming, 650091, China

    Honglin Wang, Zhigang Ma & Juanjuan Yang

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  1. Honglin Wang
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  2. Zhigang Ma
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  3. Juanjuan Yang
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Correspondence to Honglin Wang.

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Wang, H., Ma, Z. & Yang, J. Direct Amination of Benzene with NH3 and H2O2 Over Hierarchical Fe,Cu/ZSM-5 Prepared by Post-synthesis Treatment of Nanocrystallite B–ZSM-5. Catal Lett 150, 1454–1461 (2020). https://doi.org/10.1007/s10562-019-03026-9

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