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Electrostatic Long-Range Interactions in Macromolecules of Flexible-Chain Linear Polyelectrolytes with Low Charge Density in Aqueous Solutions of Different Ionic Strength

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Abstract

Molecular hydrodynamics methods (translational diffusion, velocity sedimentation, viscometry) have been used to study copolymers of N-methyl-N-vinylacetamide and N-methyl-N-vinylamine hydrochloride with an average content of charged groups (4.4 ± 0.2) mol % in aqueous 0.2 M NaCl solution. Kuhn–Mark–Houwink–Sakurada scaling relationships have been obtained. Viscous flow has been studied in the widest possible range of ionic strengths of aqueous solutions, from salt-free to 6 M NaCl. The data have been compared with those previously obtained for neutral poly-N-methyl-N-vinylacetamide. It has been shown experimentally for the first time that the character of the dependence of the intrinsic viscosity on the molecular mass of a copolymer of such a composition in solutions of minimal ionic strength is typical of the chains exhibiting intrachain volume effects, i.e. electrostatic long-range interactions.

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REFERENCES

  1. Muthukumar, M., Macromolecules, 2017, vol. 50, pp. 9528–9560. https://doi.org/10.1021/acs.macromol.7b01929

    Article  CAS  Google Scholar 

  2. Dautzenberg, H., Jaeger, W., Koetz, J., Philipp, B., Seidel, C., and Stscherbina, D., Polyelectrolytes: Formation, Characterization, and Application, Munich: Hanser-Gardner Publ., 1994.

    Google Scholar 

  3. Odijk, T., J. Polym. Sci.: Polym. Phys. Ed., 1977, vol. 15, no. 3, pp. 477–483. https://doi.org/10.1002/pol.1977.180150307

    CAS  Google Scholar 

  4. Skolnick, J. and Fixman, M., Macromolecules, 1977, vol. 10, no. 5, pp. 944–948. https://doi.org/10.1021/ma60059a011

    Article  CAS  Google Scholar 

  5. Gubarev, A.S., Carrillo, J.M.Y., and Dobrynin, A.V., Macromolecules, 2009, vol. 42, no. 15, pp. 5851–5860. https://doi.org/10.1021/ma9008143

    Article  CAS  Google Scholar 

  6. Staudinger, H., Nobel Lecture (1953): Macromolecular Chemistry, in: Nobel Lectures, Chemistry 1942–1962, Amsterdam: Elsevier, 1964, pp. 397–419.

    Google Scholar 

  7. Kraemer, E.O., Ind. Eng. Chem., 1938, vol. 30, no. 10, pp. 1200–1203. https://doi.org/10.1021/ie50346a023

    Article  CAS  Google Scholar 

  8. Pavlov, G.M., Okatova, O.V., Mikhailova, A.V., et al., Macromol. Biosci., 2010, vol. 10, p. 790. https://doi.org/10.1002/mabi.200900475

    Article  CAS  Google Scholar 

  9. Pavlov, G.M., Okatova, O.V., Gubarev, A.S., et al., Macromolecules, 2014, vol. 47, no. 8, p. 2748. https://doi.org/10.1021/ma500274k

    Article  CAS  Google Scholar 

  10. Flory, P.J., Principles of Polymer Chemistry, New York: Cornell Univ. Press, 1953.

    Google Scholar 

  11. Gray, G., Bloomfield, V., and Hearst, J., J. Chem. Phys., 1967, vol. 46, no. 4, pp. 1493–1498. https://doi.org/10.1063/1.1840879

    Article  CAS  Google Scholar 

  12. Pavlov, G.M., Eur. Phys. J. E: Soft Matter Biol. Phys., 2007, vol. 22, pp. 171–180. https://doi.org/10.1140/epje/e2007-00025-x

    Article  CAS  Google Scholar 

  13. Pavlov, G.M., Panarin, E.F., Korneeva, E.V., et al., Makromol. Chem., 1990, vol. 191, no. 12, pp. 2889–2899. https://doi.org/10.1002/macp.1990.021911205

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    G. M. Pavlov, O. A. Dommes, O. V. Okatova, I. I. Gavrilova &  E. F. Panarin

  2. Peter the Great St. Petersburg Polytechnic University, 195251, St. Petersburg, Russia

    E. F. Panarin

Authors
  1. G. M. Pavlov
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  2. O. A. Dommes
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  3. O. V. Okatova
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  4. I. I. Gavrilova
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  5. E. F. Panarin
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Correspondence to O. A. Dommes.

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Translated by G. Kirakosyan

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Pavlov, G.M., Dommes, O.A., Okatova, O.V. et al. Electrostatic Long-Range Interactions in Macromolecules of Flexible-Chain Linear Polyelectrolytes with Low Charge Density in Aqueous Solutions of Different Ionic Strength. Dokl Phys Chem 489, 164–167 (2019). https://doi.org/10.1134/S0012501619110022

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  • DOI: https://doi.org/10.1134/S0012501619110022

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