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Synthesis, Crystal Structure and Thermal Property of Two New Coordination Polymers with Ligands Containing Both N and O Donors

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Abstract

Two new metal–organic coordination polymer frameworks formulated as, {[Co(nta)]·H3O+}n (1), and {[Zn(ina)Cl2]·H3O+·H2O}n (2) (nta = nitriliotriacetic acid, ina = isonicotinate), have been synthesized under mild conditions and characterized by elemental analyses, IR spectrum, PXRD, thermal gravimetric analysis (TG) and single-crystal X-ray diffraction. Complex 1 crystallizes in the orthorhombic space group P2(1)2(1)2(1) with unit cell parameters a = 8.403(4) Å, b = 10.165(5) Å, c = 11.230 Å, β = 90, V = 959.3(9) Å3. Complex 2 crystallizes in the monoclinic space group P2(1)/c with unit cell parameters a = 7.1334(13) Å, b = 22.369(4) Å, c = 7.0089(13) Å, β = 101.099(2), V = 1097.5(3) Å3. In fact, 1 is a new 3D cobalt complex with the nta ligands acted as bridges to form network polymer. Each nta ligand bonds to three cobalt ions, and each cobalt ion coordinates with three nta ligands in different directions. 2 displays a new 1D zigzag chain linked by ina ligand and an interesting 1D hydrogen-bond infinite chain consists of seven-membered rings and four-membered rings. These chains are further linked to generate a new 3D framework.

Graphical Abstract

Two novel metal–organic coordination polymer frameworks have been synthesized under mild conditions and characterized by elemental analyses, IR spectrum, PXRD, thermal gravimetric analysis (TG) and single-crystal X-ray diffraction.

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Acknowledgements

This work was supported by the Research Fund for the Doctoral Program of Daqing Normal University (NO.16ZR04).

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Authors and Affiliations

  1. College of Chemical Engineering, Daqing Normal University; Key Laboratory of Oilfield Applied Chemistry, College of Heilongjiang Province, Daqing, 163712, Heilongjiang, People’s Republic of China

    Han Xue, Hong-Shu Xu, Dan-Feng He, Zhong-Xin Jin & Hong-Sheng Liu

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  1. Han Xue
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  2. Hong-Shu Xu
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  3. Dan-Feng He
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Correspondence to Han Xue or Hong-Sheng Liu.

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Xue, H., Xu, HS., He, DF. et al. Synthesis, Crystal Structure and Thermal Property of Two New Coordination Polymers with Ligands Containing Both N and O Donors. J Chem Crystallogr 50, 133–138 (2020). https://doi.org/10.1007/s10870-019-00785-6

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  • DOI: https://doi.org/10.1007/s10870-019-00785-6

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