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Comparative study of different polar adsorbents for adsorption of water soluble vitamins

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Abstract

The comparative study of adsorption properties of several adsorbents with focus on selective isolation of water-soluble B vitamins (B2, B, B6 and B12) from food products and some pharmaceutical formulations by solid-phase extraction is performed. The adsorption of vitamins was investigated for eleven adsorbents including bare silica, silica modified with polyvinylpyrrolidone, octadecyl-, aminopropyl-, cyanobutyl-functional groups, poly(styrene–divinylbenzene) modified with lactam groups, hypercrosslinked polystyrene, activated carbon and porous microdispersed sintered detonation nanodiamond. Dynamic adsorption capacities of adsorbents for each of the tested vitamins were determined from the dynamic output curves. The highest adsorption capacity was found for HCPS-based sorbents, but complete desorption from these sorbents required harsh conditions. On this reason MSDN was suited better for the preconcentration of water soluble vitamins.

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Authors and Affiliations

  1. Physical Chemistry Division, Chemistry Department, Lomonosov Moscow State University, 1–3 Leninskie Gory, Moscow, Russian Federation, 119991

    Sergey N. Lanin, Artem E. Vinogradov, Kseniya S. Lanina & Pavel N. Nesterenko

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation, 119071

    Sergey N. Lanin

  3. Samara National Research University, 34 Moskovskoye shosse, Samara, Russian Federation, 443086

    Svetlana A. Platonova

  4. Irish Separation Science Cluster, Dublin City University, Collins Ave., Glasnevin, Dublin, Ireland

    Ekaterina P. Nesterenko

  5. Australian Centre for Research on Separation Science, University of Tasmania, Hobart, TAS, 7001, Australia

    Pavel N. Nesterenko

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  1. Sergey N. Lanin
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  2. Svetlana A. Platonova
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  3. Artem E. Vinogradov
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  4. Kseniya S. Lanina
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  5. Ekaterina P. Nesterenko
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  6. Pavel N. Nesterenko
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Correspondence to Sergey N. Lanin.

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Lanin, S.N., Platonova, S.A., Vinogradov, A.E. et al. Comparative study of different polar adsorbents for adsorption of water soluble vitamins. Adsorption 26, 339–348 (2020). https://doi.org/10.1007/s10450-019-00186-3

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