Abstract
A new azo-dye reagent was prepared by the reaction between sulfacetamide and rutin compounds. The new synthesized reagent of (E)-N-((4-((5-(5,7-dihydroxy-3-3-[3-α-l-rhamnopyranosyl-(1 → 6)-β-d-glucopyrano-syloxy]-4-oxo-4H-chromen-2-yl)-2,3-dihydroxyphenyl)diazenyl)phenyl)sulfonyl)acetamide [NDRGA] was characterized by FT-IR, 1HNMR, mass spectra and elemental analysis measurements and then used for the spectrophotometric determination of Sm(III). The proposed method was based on the formation of a lemon-colored complex between Sm(III) and NDGRA reagent in an alkaline medium using borate buffer at pH = 8 with absorption maximum at 475 nm. The method was enhanced by the use of cationic surfactant of cetylpyridinium bromide (CPB). Different factors affecting the formation and stability of the complex such as reagent concentration, time, temperature, solvents and order of addition were also studied. The composition of the complex was found to be 1:1 (metal: ligand) by using Job’s and molar ratio methods. The stability constant of the complex was calculated to be 1.1805 × 106. The method showed a good linearity in the concentration range of 2.0–90 µg ml−1 of Sm(III) with molar absorptivity and Sandell’s sensitivity 1.3014 × 104 L mol−1 cm−1 and 1.155 × 10−2 µg cm−2, respectively. The limit of quantification (LOQ) and detection (LOD) were calculated. The interference effect of some foreign ions was also studied. The validity of the calibration curve was found useful for the determination of micro-amounts of Sm(III) in some industrial and blood samples.
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References
Bower VE, Bates RG (1955) pH values of the Clark and Lubs buffer solutions at 25° C. J Res Natl Bur Stand 55:197–200
Britton HTS (1952) Hydrogen ions, vol 28, 4th edn. Chapman and Hall, London, pp 359–364
Gadzhieva SR, Guseinov FE, Chyragov FM (2005) Spectrophotometric study of the complexation of samarium(III) with disodium 2-(2-hydroxy-3-sulfo-5-nitrophenylazo)naphthalene-1,8-dihydroxy-3,6-disulfonate in the presence of cetyltrimethylammonium bromide. J Anal Chem 60:819–821. https://doi.org/10.1007/s10809-005-0188-5
Job P (1928) Formation and stability of inorganic complexes in solution. Ann Chim 9:113–203
Li B, Sun Y, Yin J (1999) Determination of cerium, neodymium and samarium in biological materials at low levels by isotope dilution inductively coupled plasma mass spectrometry. J Anal At Spectrom 14:1843–1848. https://doi.org/10.1039/A905346H
Li Y, Yu H, Zheng S, Miao Y, Yin S, Li P, Bian Y (2016) Direct quantification of rare earth elements concentrations in urine of workers manufacturing cerium, lanthanum oxide ultrafine and nanoparticles by a developed and validated ICP-MS. Int J Environ Res Public Health 13:1–10. https://doi.org/10.3390/ijerph13030350
Lurie JU (1978) Handbook of analytical chemistry, 2nd edn. Mir Publishers, Moscow
Makombe M, Horst CV, Silwana B, Iwuoha E, Somerset V (2018) Voltammetric and spectroscopic determination of rare earth elements in fresh and surface water samples. Environments 5:1–10. https://doi.org/10.3390/environments5100112
Mehmood M (2018) Rare earth elements-a review. J Ecol Nat Resour 2:1–6. https://doi.org/10.23880/jenr-16000128
Motojima K, Lzawa K (1964) Potentiometric titration of free acid and uranium in uranium (VI) solutions with alkali. Anal Chem 36:733–735. https://doi.org/10.1021/ac60210a011
Paama L, Pamoja E, Must M, Peramaki P (2001) Optimal conditions for europium and samarium determination in cathodoluminophors by inductively coupled plasma atomic emission spectrometry. J Anal At Spectrom 16:1333–1336. https://doi.org/10.1039/B105520H
Ratre P, Kumar D (2013) Spectrophotometric determination of trace amounts of samarium in environmental samples. Am Int J Res Formal Appl Nat Sci 3:110–118
Sangal SP, Agarwala BV, Dey AK (1969) Compleximetric determination of rare earths in aqueous solution. Mikrochim Acta 3:660–663. https://doi.org/10.1007/BF01216471
Soylak M, Turkoglu O (2000) Spectrophotometric determination of samarium(III) with chrome azurol S in the presence of cetylpyridinium chloride. Talanta 53:125–129. https://doi.org/10.1016/S0039-9140(00)00386-6
Tirmizi SA, Wattoo FH, Wattoo MHS, Sarwar S, Memon AN, Ghangro AB (2012) Spectrophotometric study of stability constants of cimetidine–Ni(II) complex at different temperatures. Arab J Chem 5:309–314. https://doi.org/10.1016/j.arabjc.2010.09.009
Uhrovcik J, Lesny J (2014) Extractive spectrophotometric determination of samarium with chlorophosphonazo III. Acta Tech Jaurinensis 7:62–70. https://doi.org/10.1413/actatechjaur.v7.n1.218
Yoe JH, Jones AL (1944) Colorimetric determination of iron with disodium-1,2-dihydroxybenzene-3,5-disulfonate. Ind Eng Chem Anal Ed 16:111–115. https://doi.org/10.1021/i560126a015
Zolfonoun E, Yousefi SR (2016) Simultaneous determination of rare earth elements by ICP OES after on-Line enrichment using multi-walled carbon nanotubes coated cellulose acetate membrane. J Braz Chem Soc 27:2348–2353. https://doi.org/10.5935/0103-5053.20160131
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Abd El-wahaab, B., Elgendy, K. & El-didamony, A. Synthesis and characterization of new azo-dye reagent and using to spectrophotometric determination of samarium(III) in some industrial and blood samples. Chem. Pap. 74, 1439–1448 (2020). https://doi.org/10.1007/s11696-019-01000-8
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DOI: https://doi.org/10.1007/s11696-019-01000-8