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Synthesis of Highly Durable Sulfonated Polyketone Fibers by Direct Sulfonation Reaction and Their Adsorption Properties for Heavy Metals

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Abstract

In this study, sulfonated polyketone (SPK) cation exchange fibers were prepared by direct sulfonation with various concentration of sulfonating agent and sulfonation time. Fourier-transform infrared (FTIR) spectrum analysis was performed to confirm the structure of the sulfonated polyketone cation exchange fibers. The degree of sulfonation (DOS) and water uptake (W.U) of SPK cation exchange fibers were measured by gravimetric method and ion exchange capacity (IEC) was measured by titration method, respectively. The DOS of the SPK cation exchange fibers increased with sulfonation time and concentration of sulfonating agent. The SPK cation exchange fibers sulfonated for 15 min at a mole ratio of 1:2 of polyketone to chlorosulfonic acid had the DOS of 47%, ion exchange capacity 3.36 meq/g, and water content 35.1%, showing the best performance.

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References

  1. J. F. Wei, Z. P. Wang, J. Zhang, Y. Y. Wu, Z. P. Zhang, and C. H. Xiong, React. Funct. Polym., 65, 127 (2005).

    Article  CAS  Google Scholar 

  2. P. Kampalanonwat and P. Supaphol, ACS Appl. Mater. Inter., 2, 3619 (2010).

    Article  CAS  Google Scholar 

  3. F. C. Rix, M. Brookhart, and P. S. White, J. Am. Chem. Soc., 118, 4746 (1996).

    Article  CAS  Google Scholar 

  4. C. Bianchini and A. Meli, Coord. Chem. Rev., 225, 35 (2002).

    Article  CAS  Google Scholar 

  5. G. P. Belov and E. V. Novikova, Russian Chem. Rev., 73, 267 (2004).

    Article  CAS  Google Scholar 

  6. A. Sommazzi and Garbassi, F., Prog. Polym. Sci., 22, 1547 (1997).

    Article  CAS  Google Scholar 

  7. N. Ataollahi, K. Vezzù, G. Nawn, G. Pace, G. Cavinato, F. Girardi, P. Scardi, V. Di Noto, and R. Di Maggio, Electrochim. Acta, 226, 148 (2017).

    Article  CAS  Google Scholar 

  8. I. S. Kim, C. W. Hwang, Y. J. Kim, A. Canlier, K. S. Jeong, and T. S. Hwang, Macromol. Res., 25, 1063 (2017).

    Article  CAS  Google Scholar 

  9. M. Paronen, F. Sundholm, D. Ostrovskii, P. Jacobsson, G. Jeschke, E. Rauhala, and P. Tikkanen, Chem. Mater., 15, 4447 (2003).

    Article  CAS  Google Scholar 

  10. K. W. Kang and T. S. Hwang, Membr. J., 25, 406 (2015).

    Article  Google Scholar 

  11. F. Wang, M. Hickner, Y. S. Kim, T. A. Zawodzinski, and J. E. McGrath, J. Membr. Sci., 197, 231 (2002).

    Article  CAS  Google Scholar 

  12. H. Ghassemi, J. E. McGrath, and T. A. Zawodzinski Jr., Polymer, 47, 4132 (2006).

    Article  CAS  Google Scholar 

  13. B. C. Johnson, I. Yilgör, C. Tran, M. Iqbal, J. P. Wightman, D. R. Lloyd, and J. E. McGrath, J. Polym. Sci., Polym. Chem. Ed., 22, 721 (1984).

    Article  CAS  Google Scholar 

  14. Y. F. Lin, C. Y. Yen, C. H. Hung, Y. H. Hsiao, and C. C. M. Ma, J. Power Sources, 168, 162 (2007).

    Article  CAS  Google Scholar 

  15. M. V. Reddy, G. C. S. Reddy, R. M. N. Kalla, and Y. T. Jeong, RSC Adv., 5, 35267 (2015).

    Article  CAS  Google Scholar 

  16. P. Staiti, F. Lufrano, A. S. Arico, E. Passalacqua, and V. Antonucci, J. Membr. Sci., 188, 71 (2001).

    Article  CAS  Google Scholar 

  17. X. Li, C. Zhao, H. Lu, Z. Wang, and H. Na, Polymer, 46, 5820 (2005).

    Article  CAS  Google Scholar 

  18. K. W. Kang, C. W. Hwang, and T. S. Hwang, Macromol. Res., 23, 1126 (2015).

    Article  CAS  Google Scholar 

  19. L. Xu and H. K. Lee, J. Chromatogr. A, 1216, 6549 (2009).

    Article  CAS  Google Scholar 

  20. J. P. Shin, I. J. Park, S. B. Lee, D. H. Seo, and J. H. Kim, Membr. J., 14, 173 (2004).

    CAS  Google Scholar 

  21. N. S. Kwak, S. M. Kim, Y. K. Yang, K. S. Kang, and T. S. Hwang, Polym. Korea, 28, 397 (2004).

    CAS  Google Scholar 

  22. J. S. Park and Y. C. Nho, Polym. Korea, 22, 47 (1998).

    CAS  Google Scholar 

  23. F. Lufrano, I. Gatto, P. Staiti, V. Antonucci, and E. Passalacqua, Solid State Ionics, 145, 47 (2001).

    Article  CAS  Google Scholar 

  24. G. Yan and T. Viraraghavan, Water Res., 37, 4486 (2003).

    Article  CAS  Google Scholar 

  25. W. Y. Kim, Y. S. Kim, G. C. Yug, and D. Y. Shin, Synthesis and Adsorption Properties for Heavy Metal Ions of Amidoxime Type Chelate Resin, 16, 277 (1992).

    CAS  Google Scholar 

  26. T. Yoshioka, Bull. Chem. Soc. Japan, 58, 2618 (1985).

    Article  CAS  Google Scholar 

  27. J.-W. Lee, S.-H. Kim, and G.-S. Hwang, J. Korea Academia-Industrial, 18, 584 (2017).

    Google Scholar 

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Author notes

  1. S. Y. Hwang and Y. S. Cho contributed equally.

Authors and Affiliations

  1. Department of Applied Chemical Engineering, College of Engineering, Chungnam National University, 99 Daehak-ro, Yuseoung-gu, Daejeon, 34134, Korea

    Seong Yeon Hwang, Yong Seok Cho, Yoon Seo Jung & Taek Sung Hwang

  2. Department of Chemical Engineering Education, College of Education, Chungnam National University, 99 Daehak-ro, Yuseoung-gu, Daejeon, 34134, Korea

    Taekeun Kim

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  1. Seong Yeon Hwang
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  2. Yong Seok Cho
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  3. Taekeun Kim
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  4. Yoon Seo Jung
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  5. Taek Sung Hwang
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Correspondence to Taek Sung Hwang.

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Acknowledgments: This work was supported by the Ministry of Trade, Industry and Energy (MOTIE) and the Korea Institute for the Advancement of Technology (KIAT) (N0002383, 2018).

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Hwang, S.Y., Cho, Y.S., Kim, T. et al. Synthesis of Highly Durable Sulfonated Polyketone Fibers by Direct Sulfonation Reaction and Their Adsorption Properties for Heavy Metals. Macromol. Res. 28, 336–342 (2020). https://doi.org/10.1007/s13233-020-8046-8

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  • DOI: https://doi.org/10.1007/s13233-020-8046-8

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