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Facile fabrication of durable superamphiphobic PET fabrics

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Abstract

Superamphiphobic coatings/materials are important for a wide variety of applications, but the majority of these coatings/materials still suffer from poor durability. Therefore, multifunctional superamphiphobic coatings/materials with strong mechanical and chemical stability are highly desired. Herein, a simple and flexible approach to produce multifunctional superamphiphobic poly(ethylene terephthalate) (PET) textiles was reported. First, dual micro/nanostructures on the PET fabric surface are constructed by hydrolysis of trimethoxymethylsilane, N-octyltriethoxysilane, and trimethylchlorosilane, and further modified by 1H,1H,2H,2H-perfluorodecyltriethoxysilane and poly(vinylidene fluoride). The as-obtained superamphiphobic PET fabrics show high liquid repellency to water, oil, organic liquids, and strong acid or alkali solutions, exhibiting a water contact angle (WCA) of 161° and an oil contact angle (OCA) of 156°. Meanwhile, the superamphiphobic PET fabrics show strong abrasion resistance; even after 180-cm consistent abrasion, the WCA still maintains 148° and the OCA maintains 140°. Importantly, the fabrics maintain their excellent superamphiphobic property after long-term UV irradiation or ultrasonic treatment, respectively. Because the prepared fabrics have multifunctional features and are easy to fabricate with low cost, they show great potential for self-cleaning, antifouling, anti-icing, drug reduction, corrosion resistance, and protective uniforms.

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References

  1. Chen, F, Yang, H, Liu, X, Chen, D, Xiao, X, Liu, K, Li, J, Cheng, F, Dong, B, Zhou, Y, Guo, Z, Qin, Y, Wang, S, Xu, W, “Facile Fabrication of Multifunctional Hybrid Silk Fabrics with Controllable Surface Wettability and Laundering Durability.” ACS Appl. Mater. Interfaces, 8 5653–5660 (2016)

    Article  CAS  Google Scholar 

  2. Xue, C-H, Bai, X, Jia, S-T, “Robust, Self-Healing Superhydrophobic Fabrics Prepared by One-Step Coating of PDMS and Octadecylamine.” Sci. Rep., 6 27262 (2016)

    Article  Google Scholar 

  3. Wu, L, Zhang, JP, Li, BC, Fan, L, Li, LX, Wang, AQ, “Facile Preparation of Super Durable Superhydrophobic Materials.” J. Colloid Interface Sci., 432 31–42 (2014)

    Article  CAS  Google Scholar 

  4. Deng, Z-Y, Wang, W, Mao, L-H, Wang, C-F, Chen, S, “Versatile Superhydrophobic and Photocatalytic Films Generated from TiO2–SiO2@PDMS and Their Applications on Fabrics.” J. Mater. Chem. A, 2 4178–4184 (2014)

    Article  CAS  Google Scholar 

  5. Guo, X-J, Xue, C-H, Li, M, Li, X, Ma, J-Z, “Fabrication of Robust, Superhydrophobic, Electrically Conductive and UV-Blocking Fabrics via Layer-by-Layer Assembly of Carbon Nanotubes.” RSC Adv., 7 25560–25565 (2017)

    Article  CAS  Google Scholar 

  6. Wu, L, Zhang, J, Li, B, Wang, A, “Mimic Nature, Beyond Nature: Facile Synthesis of Durable Superhydrophobic Textiles Using Organosilanes.” J. Mater. Chem. B, 1 4756–4763 (2013)

    Article  CAS  Google Scholar 

  7. Xue, C-H, Guo, X-J, Ma, J-Z, Jia, S-T, “Fabrication of Robust and Antifouling Superhydrophobic Surfaces via Surface-Initiated Atom Transfer Radical Polymerization.” ACS Appl. Mater. Interfaces, 7 8251–8259 (2015)

    Article  CAS  Google Scholar 

  8. Lu, Y, Sathasivam, S, Song, JL, Crick, CR, Carmalt, CJ, Parkin, IP, “Robust Self-cleaning Surfaces that Function When Exposed to Either Air or Oil.” Science, 347 1132–1135 (2015)

    Article  CAS  Google Scholar 

  9. Wu, G, An, J, Tang, X-Z, Xiang, Y, Yang, J, “A Versatile Approach Towards Multifunctional Robust Microcapsules with Tunable, Restorable, and Solvent-Proof Superhydrophobicity for Self-Healing and Self-Cleaning Coatings.” Adv. Funct. Mater., 24 6751–6761 (2014)

    Article  CAS  Google Scholar 

  10. Zhou, H, Wang, H, Niu, H, Gestos, A, Wang, X, Lin, T, “Fluoroalkyl Silane Modified Silicone Rubber/Nanoparticle Composite: A Super Durable, Robust Superhydrophobic Fabric Coating.” Adv. Mater., 24 2409–2412 (2012)

    Article  CAS  Google Scholar 

  11. Ishizaki, T, Masuda, Y, Sakamoto, M, “Corrosion Resistance and Durability of Superhydrophobic Surface Formed on Magnesium Alloy Coated with Nanostructured Cerium Oxide Film and Fluoroalkylsilane Molecules in Corrosive NaCl Aqueous Solution.” Langmuir ACS J. Surf. Colloids, 27 4780–4788 (2011)

    Article  CAS  Google Scholar 

  12. Wang, G, Liu, S, Wei, S, Liu, Y, Lian, J, Jiang, Q, “Robust Superhydrophobic Surface on Al Substrate With Durability, Corrosion Resistance and Ice-Phobicity.” Sci. Rep., 6 20933 (2016)

    Article  CAS  Google Scholar 

  13. Li, G, Lee, HJ, Michielsen, S, “Design of Abrasion Resistant Super-Antiwetting Nylon Surfaces.” New J. Chem., 41 13593–13599 (2017)

    Article  CAS  Google Scholar 

  14. Li, D, Guo, Z, “Versatile Superamphiphobic Cotton Fabrics Fabricated by Coating with SiO2/FOTS.” Appl. Surf. Sci., 426 271–278 (2017)

    Article  CAS  Google Scholar 

  15. Guo, X-J, Xue, C-H, Jia, S-T, Ma, J-Z, “Mechanically Durable Superamphiphobic Surfaces via Synergistic Hydrophobization and Fluorination.” Chem. Eng. J., 320 330–341 (2017)

    Article  CAS  Google Scholar 

  16. Wang, Z, Li, Q, She, Z, Chen, F, Li, L, “Low-Cost and Large-Scale Fabrication Method for an Environmentally-Friendly Superhydrophobic Coating on Magnesium Alloy.” J. Mater. Chem., 22 4097–4105 (2012)

    Article  CAS  Google Scholar 

  17. Zhuang, A, Liao, R, Dixon, SC, Jiamprasertboon, A, Chen, F, Sathasivam, S, Parkin, IP, Carmalt, CJ, “Transforming a Simple Commercial Glue into Highly Robust Superhydrophobic Surfaces via Aerosol-Assisted Chemical Vapor Deposition.” ACS Appl. Mater. Interfaces, 9 42327–42335 (2017)

    Article  CAS  Google Scholar 

  18. Hwang, GB, Patir, A, Page, K, Lu, Y, Allan, E, Parkin, IP, “Buoyancy Increase and Drag-Reduction Through a Simple Superhydrophobic Coating.” Nanoscale, 9 7588–7594 (2017)

    Article  CAS  Google Scholar 

  19. Wong, WSY, Stachurski, ZH, Nisbet, DR, Tricoli, A, “Ultra-Durable and Transparent Self-Cleaning Surfaces by Large-Scale Self-Assembly of Hierarchical Interpenetrated Polymer Networks.” ACS Appl. Mater. Interfaces, 8 13615–13623 (2016)

    Article  CAS  Google Scholar 

  20. Wang, S, Yu, X, Zhang, Y, “Large-Scale Fabrication of Translucent, Stretchable and Durable Superhydrophobic Composite Films.” J. Mater. Chem. A, 5 23489–23496 (2017)

    Article  CAS  Google Scholar 

  21. Xue, C-H, Yin, W, Zhang, P, Zhang, J, Ji, P-T, Jia, S-T, “UV-Durable Superhydrophobic Textiles with UV-Shielding Properties by Introduction of ZnO/SiO2 Core/Shell Nanorods on PET Fibers and Hydrophobization.” Colloids Surf. A Physicochem. Eng. Asp., 427 7–12 (2013)

    Article  CAS  Google Scholar 

  22. Jiang, L, Zhao, Y, Zhai, J, “A Lotus-Leaf-Like Superhydrophobic Surface: A Porous Microsphere/Nanofiber Composite Film Prepared by Electrohydrodynamics.” Angew. Chem. Int. Ed., 43 4338–4341 (2004)

    Article  CAS  Google Scholar 

  23. Pan, L, Dong, H, Bi, P, “Facile Preparation of Superhydrophobic Copper Surface by HNO3 Etching Technique with the Assistance of CTAB and Ultrasonication.” Appl. Surf. Sci., 257 1707–1711 (2010)

    Article  CAS  Google Scholar 

  24. Sun, MH, Luo, CX, Xu, LP, Ji, H, Qi, OY, Yu, DP, Chen, Y, “Artificial Lotus Leaf by Nanocasting.” Langmuir ACS J. Surf. Colloids, 21 8978–8981 (2005)

    Article  CAS  Google Scholar 

  25. Peng, L, Meng, Y, Li, H, “Facile Fabrication of Superhydrophobic Paper with Improved Physical Strength by a Novel Layer-by-Layer Assembly of Polyelectrolytes and Lignosulfonates-Amine.” Cellulose, 23 2073–2085 (2016)

    Article  CAS  Google Scholar 

  26. Singh, AK, Singh, JK, “Fabrication of Durable Superhydrophobic Coatings on Cotton Fabrics with Photocatalytic Activity by Fluorine-Free Chemical Modification for Dual-Functional Water Purification.” New J. Chem., 41 4618–4628 (2017)

    Article  CAS  Google Scholar 

  27. Mahltig, B, Bottcher, H, “Modified Silica Sol Coatings for Water-Repellent Textiles.” J. Sol Gel Sci. Technol., 27 43–52 (2003)

    Article  CAS  Google Scholar 

  28. Textor, T, Mahltig, B, “Nanosols for Preparation of Antistatic Coatings Simultaneously Yielding Water and Oil Repellent Properties for Textile Treatment.” Mater. Technol., 25 74–80 (2010)

    Article  CAS  Google Scholar 

  29. Textor, T, Mahltig, B, “A Sol–Gel Based Surface Treatment for Preparation of Water Repellent Antistatic Textiles.” Appl. Surf. Sci., 256 1668–1674 (2010)

    Article  CAS  Google Scholar 

  30. Mahltig, B, “Hydrophobic and Oleophobic Finishes for Textiles.” In: Paul, R (ed.) Functional Finishes for Textiles, pp. 387–428. Woodhead Publishing, Cambridge (2015)

    Chapter  Google Scholar 

  31. Wang, L, Urata, C, Sato, T, England, MW, Hozumi, A, “Self-Healing Superhydrophobic Materials Showing Quick Damage Recovery and Long-Term Durability.” Langmuir ACS J. Surf. Colloids, 33 9972–9978 (2017)

    Article  CAS  Google Scholar 

  32. Guo, F, Wen, QY, Peng, YB, Guo, ZG, “Simple One-Pot Approach Toward Robust and Boiling-Water Resistant Superhydrophobic Cotton Fabric and the Application in Oil/Water Separation.” J. Mater. Chem. A, 5 21866–21874 (2017)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), and the Fundamental Research Funds for the Central Universities with Grant No. 2242016K41020.

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Correspondence to Yong Jiang.

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Zhou, X., Sun, S., Zhang, C. et al. Facile fabrication of durable superamphiphobic PET fabrics. J Coat Technol Res 17, 711–718 (2020). https://doi.org/10.1007/s11998-019-00289-0

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