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New Proton-Conducting Polydiimidazopyridine-Based Membrane for an HT-PEM Fuel Cell

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Abstract

Polydiimidazopyridine was synthesized from 2,3,5,6-tetraaminopyridine and 2,5-dihydroxyterephthalic acid in polyphosphoric acid (PPA) and characterized. Polydiimidazopyridine possessed high viscosity, high thermooxidative stability, and excellent film-forming properties. The polymer was processed from a reaction solution in PPA to proton-conducting membranes featuring high proton conductivity in the temperature range of 20–200°C, being superior in this value to many known membranes.

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ACKNOWLEDGMENTS

The authors are grateful to the Center for molecular composition studies of the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, and to M.I. Buzin for conducting TGA of the polymers and to Z.S. Klemenkova for recording the IR spectra.

Funding

This study was financially supported by Russian Science Foundation grant no. 18–13–00421.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    I. I. Ponomarev, D. Yu. Razorenov, Iv. I. Ponomarev, Yu. A. Volkova & K. M. Skupov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Lysova &  A. B. Yaroslavtsev

Authors
  1. I. I. Ponomarev
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  2. D. Yu. Razorenov
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  3. Iv. I. Ponomarev
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  4. Yu. A. Volkova
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  5. K. M. Skupov
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  6. A. A. Lysova
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  7. A. B. Yaroslavtsev
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Corresponding authors

Correspondence to I. I. Ponomarev or K. M. Skupov.

Additional information

Translated by Z. Svitanko

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Ponomarev, I.I., Razorenov, D.Y., Ponomarev, I.I. et al. New Proton-Conducting Polydiimidazopyridine-Based Membrane for an HT-PEM Fuel Cell. Dokl Chem 486, 156–159 (2019). https://doi.org/10.1134/S0012500819060028

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  • DOI: https://doi.org/10.1134/S0012500819060028

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