Abstract
The distributions of hydrocarbon gases (HCGs) from C1-C5 in seafloor sediments of the South Tatar sedimentary basin (northern Sea of Japan) were obtained during five research cruises from 2012 to 2017. As a result of this work, areas of gas hydrates, gas flares, and anomalous gas concentrations were discovered. The concentration of HCGs in seafloor sediment, as determined by the “headspace method” varied from 0.38 to 149,000 ppm, with a median of 177 ppm (N = 1420). The median values of HCGs for the Western, Central, and Eastern part of the South Tatar sedimentary basin are 11.7, 99, and 1134 ppm, respectively. Maximum values and gradients in concentrations of HCGs were found in the central and eastern parts of Tatar Strait, where multiple cores contain gas hydrates and gas-saturated sediments. The predominant gas component in all samples was methane, but relatively high concentrations of ethane (up to 789 ppm) and propane (up to 111 ppm) occur. Methane concentrations below 5.25 ppm can be considered as regional background for near seafloor (0–15 cm) sediments from the South Tatar sedimentary basin. The С1/(С2 + С3) ratio across all samples ranges between 2.6 and 345,000, with a median value of 219. The presence of a large-scale degassing zone exists in the northeastern part of Tatar Strait, which coincides with areas of gas hydrates and gas anomalies in the sediments and gas flares in the water column.
Similar content being viewed by others
References
Abrams MA (2005) Significance of hydrocarbon seepage relative to sub-surface petroleum generation and entrapment. Marine and Petroleum Geology 22:457–477. https://doi.org/10.1016/j.marpetgeo.2004.08.003
Abrams M (2017) Evaluation of near-surface gases in marine sediments to assess subsurface petroleum gas generation and entrapment. Geosciences 7(2):35. https://doi.org/10.3390/geosciences7020035
Bernard BB (1978) Light hydrocarbons in marine sediments. PhD Dissertation, Texas
Blumenberg M, Lutz R, Schlömer S, Krüger M, Scheeder G, Berglar K, Weniger P (2016) Hydrocarbons from near-surface sediments of the Barents Sea north of Svalbard – indication of subsurface hydrocarbon generation? Marine and Petroleum Geology 76:432–443. https://doi.org/10.1016/j.marpetgeo.2016.05.031
Brekke T, Lønne Ø, Ohm S (1997) Light hydrocarbon gases in shallow sediments in the northern North Sea. Marine Geology 137(1–2):81–108. https://doi.org/10.1016/s0025-3227(96)00081-3
Burov BA, Luchin VA, Obzhirov AI, Karnaukhov AA (2018) Estimation of methane flux from seafloor sediments to water as a result of methane hydrate degradation caused by water warming in the strait of Tatar. Geoecology. Engineering geology. Hydrogeology. Geocryology 2:3–14. https://doi.org/10.7868/S086978031802-0015
Choi J, Kim J-H, Torres ME, Hong W-L, Lee J-W, Yi BY, Lee KE (2013) Gas origin and migration in the Ulleung Basin, East Sea: results from the second Ulleung Basin gas hydrate drilling expedition (UBGH2). Marine and Petroleum Geology 47:113–124. https://doi.org/10.1016/j.marpetgeo.2013.05.022
Claypool GE, Kaplan IR (1974) The origin and distribution of methane in marine sediments. In: Kaplan IR (ed) Natural gases in marine sediments. Marine science, vol 3. Springer, Boston. https://doi.org/10.1007/978-1-4684-2757-8_8
Claypool GE, Kvenvolden KA (1983) Methane and other hydrocarbon gases in marine sediments. Annu Rev Earth Planet Sci 11:299–327. https://doi.org/10.1146/annurev.ea.11.050183.001503
Dickens GR (2004) Hydrocarbon-driven warming. Nature 429(6991):513–515. https://doi.org/10.1038/429513a
Dymovich VA, Evseev SV, Evseev VF, Nesterova EN, Margulis LS, Atrashenko AF, Belyaev IV, Derkachev AN, Zelepugin VN, Konovalenko AA, Opalikhina EU, Rybak-Franko SE, Utkin IV, Khaybulina GA (2016) State geological map of the Russian Federation. Scale 1: 1 000 000 (third generation). Far eastern series. Sheet M-54 – Aleksandrovsk-Sakhalinskiy. Explanatory note. VSEGEI, St. Petersburg [in Russian]
Fleischer P, Orsi TH, Richardson MD, Anderson AL (2001) Distribution of free gas in marine sediments: a global overview. Geo-Marine Letters 21(2):103–122. https://doi.org/10.1007/s003670100072
Ginsburg GD, Soloviev VA (1994) Submarine gas hydrates. VNIIOkeangeologiya, Leningrad [in Russian]
Gresov AI, Obzhirov AI, Shakirov RB (2009) Methane resources of coal basins in the Far East of Russia and their industrial development perspectives – Vol. 1. Coal methane basins of Primorye, Sakhalin Islands and Khabarovsky kray. Dalnauka, Vladivostok [in Russian]
Gresov AV, Obzhirov AV, Yatsuk AV, Mazurov AK, Ruban AS (2017) Gas content of bottom sediments and geochemical indicators of oil and gas on the shelf of the east Siberian Sea. Russian Journal of Pacific Geology 11:308–314. https://doi.org/10.1134/S1819714017040030
Gresov AI, Yatsuk AV, Obzhirov AI, Razvozzhaeva EP (2018) Gas-geochemical anomalies of surface and ground waters of the Birofeld Graben of the middle Amur Sedimentary Basin (Far East of Russia). Russian Journal of Pacific Geology 12(3):225–238. https://doi.org/10.1134/s181971401803003x
Hachikubo A, Krylov A, Sakagami H, Minami H, Nunokawa Y, Shoji H, Matveeva T, Jin Y, Obzhirov A (2010) Isotopic composition of gas hydrates in subsurface sediments from offshore Sakhalin Island, Sea of Okhotsk. Geo-Marine Letters 30:313–319. https://doi.org/10.1007/s00367-009-0178-y
Hachikubo A, Tomaru H, Lu H, Matsumoto R (2011) Molecular and isotopic compositions characteristics of hydrocarbons in sediments and gas hydrate at Eastern margin of Japan Sea. Proceedings of the 7th International Conference on Gas Hydrates (ICGH 2011), Edinburgh, Scotland, United Kingdom, July 17–21, 2011
Hachikubo A, Yanagawa K, Tomaru H, Lu H, Matsumoto R (2015) Molecular and isotopic composition of volatiles in gas hydrates and in sediment from the Joetsu Basin, eastern margin of the Japan Sea. Energies 8(6):4647–4666. https://doi.org/10.3390/en8064647
Horvitz L (1985) Geochemical exploration for petroleum. Science 229:821–827. https://doi.org/10.1126/science.229.4716.821
Hovland M, Judd AG (1988) Seabed pockmarks and seepages: impact on geology, biology, and marine environment. Graham & Trotman, London
Hunt JM (1979) Petroleum geochemistry and geology. WH Freeman, San Francisco
Jin Y, Shoji H, Obzhirov A, Baranov B (2013) Operation report of Sakhalin slope gas hydrate project 2012. R/V Akademik M.A. Lavrentyev Cruise 59, Korea Polar Research Institute, Inchon
Jin Y, Minami H, Baranov B, Nikolaeva N, Obzhirov A (2015) Operation report of Sakhalin slope gas hydrate project II, 2014. R/V Akademik M.A. Lavrentyev Cruise 67, Korea Polar Research Institute, Inchon
Kharakhinov VV (2010) Oil-and-gas geology of the Sakhalin region. Science World, Moscow [in Russian]
Knies J, Damm E, Gutt J, Mann U, Pinturier L (2004) Near-surface hydrocarbon anomalies in shelf sediments off Spitsbergen: evidences for past seepages. Geochemistry, Geophysics, Geosystems 5(6). https://doi.org/10.1029/2003gc000687
Kolb B, Ettre LS (2006) Static headspace-gas chromatography: theory and practice, Second Edition, New Jersey
Kvenvolden KA (1988) Hydrocarbon gas in sediment of the southern Pacific Ocean. Geo-Marine Letters 8(3):179–187. https://doi.org/10.1007/bf02326095
Liira M, Noormets R, Sepp H, Kekišev O, Maddison M, Olaussen S (2019) Sediment geochemical study of hydrocarbon seeps in Isfjorden and Mohnbukta: a comparison between western and eastern Spitsbergen. Svalbard, Arktos. https://doi.org/10.1007/s41063-019-00067-7
Matsumoto R, Ryu B-J, Lee S-R, Lin S, Wu S, Sain K, Riedel M (2011) Occurrence and exploration of gas hydrate in the marginal seas and continental margin of the Asia and Oceania region. Marine and Petroleum Geology 28(10):1751–1767. https://doi.org/10.1016/j.marpetgeo.2011.09.009
Minami H, Jin Y, Baranov B, Nikolaeva N, Obzhirov A (2016) Operation report of Sakhalin slope gas hydrate project II, 2015. R/V Akademik M. A. Lavrentyev Cruise 70, Kitami Institute of Technology, Kitami
Mishukova GI, Mishukov VF, Obzhirov AI, Pestrikova NL, Vereshchagina OF (2015) Peculiarities of the distribution of methane concentration and methane fluxes at the water-air interface in the Tatar Strait of the sea of Japan. Russian Meteorology and Hydrology 40:427–433. https://doi.org/10.3103/S1068373915060096
Obzhirov A, Shakirov R, Salyuk A, Suess E, Biebow N, Salomatin A (2004) Relations between methane venting, geological structure and seismo-tectonics in the Okhotsk Sea. Geo-Marine Letters 24:135–139. https://doi.org/10.1007/s00367-004-0175-0
Porotov GS (1977) Mathematical methods for the prospecting and exploration of mineral resources. LGI, Leningrad [in Russian]
Ryu B-J, Riedel M, Kim J-H, Hyndman RD, Lee Y-J, Chung B-H, Kim I-S (2009) Gas hydrates in the western deep-water Ulleung Basin, East Sea of Korea. Marine and Petroleum Geology 26(8):1483–1498. https://doi.org/10.1016/j.marpetgeo.2009.02.004
Schoell M (1983) Genetic characterization of natural gases. The American Association of Petroleum Geologists Bulletin 67:2225–2238. https://doi.org/10.1306/ad46094a-16f7-11d7-8645000102c1865d
Shakirov RB (2015) Gas-geochemical fields of the marginal seas of the far eastern region: distribution, genesis, connection with geological structures, gas hydrates and seismo-tectonics. Dissertation, POI FEB RAS. [in Russian]
Shakirov RB, Syrbu NS, Obzhirov AI (2016) Distribution of helium and hydrogen in sediments and water on the Sakhalin slope. Lithology and Mineral Resources 51:61–73. https://doi.org/10.1134/S0024490216010065
Shakirov RB, Obzhirov AI, Salomatin AS, Makarov MM (2017) New data on lineament control of modern centers of methane degassing in east Asian seas. Doklady Earth Sciences 477(1):1287–1290. https://doi.org/10.1134/s1028334x17110241
Shakirov RB, Valitov MG, Obzhirov AI, Mishukov VF, Yatsuk AV, Syrbu NS, Mishukova OV (2019) Methane anomalies, its flux on the sea–atmosphere interface and their relations to the geological structure of the south-Tatar sedimentary basin (Tatar Strait, the sea of Japan). Mar Geophys Res 40:581–600. https://doi.org/10.1007/s11001-019-09389-3
Shoji H, Jin Y, Baranov B, Nikolaeva N, Obzhirov A (2014) Operation report of Sakhalin slope gas hydrate project II, 2013. R/V Akademik M.A. Lavrentyev Cruise 62. Environmental and Energy Resources Research Center, Kitami University, Kitami
Smirnov BV (1983) Probabilistic methods of forecasting in engineering geology. Nedra, Moscow [in Russian]
Starobinets IS (1986) Gas geochemical indicators of oil and gas potential and the prediction of the composition of hydrocarbon accumulations. Nedra, Moscow [in Russian]
Starobinets IS, Petukhov AV, Zubairaev SL et al (1993) Fundamentals of the theory of geochemical fields of hydrocarbon fields. Nedra, Moscow [in Russian]
Vysotsky IV (1979) Geology of natural gas. Nedra, Moscow [in Russian]
Whiticar MJ, Faber E, Schoell M (1986) Biogenic methane formation in marine and freshwater environments: CO2 reduction vs. acetate fermentation - isotope evidence. Geochimica et Cosmochimica Acta 50:693–709. https://doi.org/10.1016/0016-7037(86)90346-7
Zharov AE, Kirillova GL, Margulis LS, Chuiko LS, Kudelkin VV, Varnavsky VG, Gagaev VN (2004) Geology, geodynamics and petroliferous potential of the sedimentary basins of the Tatar Strait. FEB RAS, Vladivostok [in Russian]
Acknowledgments
We are grateful to all our colleagues from the laboratory of gas geochemistry POI FEB RAS, who in various years participated in expeditionary works. Special gratitude to Olga Vereshchagina, Natalya Pestrikova, Elena Maltseva, and Nadezhda Syrbu for performing high-quality chromatographic analysis; Alexander Salomatin (POI) for high-quality hydro-acoustic survey; and Maxim Valitov (POI) for organizing of the expedition OP-54 (2017) and bathymetric survey of the water area. We appreciate to Alexander Derkachev (POI) for proffessional geological sampling. We are very grateful to Glen Snyder for constructive commentary. We appreciate to our colleagues Hitoshi Shoji, Hirotsugu Minami, Akihiro Hachikubo (Kitami Institute of Technology, Japan), Young K. Jin (KOPRI, South Korea), and Boris Baranov (IO RAS, Russia) for many years of joint collaborations in the field of study of gas hydrates in the Far Eastern seas. We also acknowledge the captains and crews of R/V Akademik M.A. Lavrentyev and Akademik Oparin for assistance during expedition works.
Funding
This study was supported by the Russian Foundation for Basic Research (RFBR) grant No. 18–35-00047.
The research is performed within the state basic research programs: № 0271-2019-0006 “Gas-geochemical fields of the seas of Eastern Asia, geodynamic processes and natural gas flux, which influence the formation of geological structures with hydrocarbon deposits and authigenic mineralization in the seafloor sediments”.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Yatsuk, A., Shakirov, R., Gresov, A. et al. Hydrocarbon gases in seafloor sediments of the TATAR strait, the northern sea of Japan. Geo-Mar Lett 40, 481–490 (2020). https://doi.org/10.1007/s00367-019-00628-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00367-019-00628-5