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Polarity of para-disubstituted benzene derivatives: a correlation analysis of the substituent effect

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The article is concerned with the influence of resonance donor substituents RD on the dipole moments μ of molecules 1,4-RDC6H4RA containing resonance acceptor groups RA (CF3, CN, COCH3, NO2 or COH) and grouped in five reaction (indicator) series. Generally, the μ values depend on the inductive, resonance, and polarizability effects of the substituents RD. Strengthening of the resonance acceptor properties of the RA groups leads to weaker conjugation between the substituents RD and the π-system.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    O. V. Kuznetsova, A. N. Egorochkin & N. M. Khamaletdinova

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  1. O. V. Kuznetsova
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  2. A. N. Egorochkin
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  3. N. M. Khamaletdinova
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Correspondence to O. V. Kuznetsova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1860–1865, October, 2019.

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Kuznetsova, O.V., Egorochkin, A.N. & Khamaletdinova, N.M. Polarity of para-disubstituted benzene derivatives: a correlation analysis of the substituent effect. Russ Chem Bull 68, 1860–1865 (2019). https://doi.org/10.1007/s11172-019-2636-7

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  • DOI: https://doi.org/10.1007/s11172-019-2636-7

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