Skip to main content

Advertisement

Log in

Investigation of Wear and Corrosion Behaviors of Ti15Mo Alloy Produced by Mechanical Alloying Method in SBF Environment

  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

This study aims to examine the wear performance and electrochemical corrosion properties of Ti15Mo alloy produced by mechanical alloying (MA) in simulated body fluid (SBF) environment. Ti15Mo alloy was produced by milling in a mechanical alloying device for 120 min. The alloys produced are examined using SEM, X-ray diffraction, hardness and density measurements. Three different loads, four different sliding distances and 1 m · sec–1 sliding speed were used in the tests performed in SBF environment. Corrosion tests were carried out using potentiodynamic polarization technique, cyclic polarization measurement at 37°C body temperature, in SBF, with a scan interval of ±750 mV and scan rate of 1 mV/sec. Density and hardness measurement results of MA’ed Ti15Mo alloy are 4.93 g/cm3 and 299.5 HV, respectively. As a result of increasing the load applied during the wear tests, the resistance of the samples against wear has decreased and the amount of wear has increased. Corrosion tests showed that the potentiodynamic polarization parameters were 36.969 mA/cm2 for Icorr value and 0.54448 mmpy for corrosion rate. Corrosion tests made in the environment of SBF and at body temperature revealed that there was very little pitting corrosion observed in MA’ed Ti15Mo alloy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

References

  1. D. Mareci, R. Chelariu, D.M. Gordin, M. Romas, D. Sutiman, and T. Gloriant, “Effect of Mo content on electrochemical behaviour of TiMo alloys for dental applications,” Mater. Corros., Vol. 61, No. 10, 829–837 (2010.).

    Article  CAS  Google Scholar 

  2. D.R.C. McLachlan, “Aluminium and the risk for Alzheimer’s disease,” Environmetrics, 6, No. 3, 233–275 (1995).

    Article  Google Scholar 

  3. M. Niinomi, “Mechanical biocompatibilities of titanium alloys for biomedical applications,” J. Mech. Behav. Biomed. Mater., 1, No. 1, 30–42 (2008).

    Article  Google Scholar 

  4. M. Geetha, A.K. Singh, R. Asokamani, and A.K. Gogia, “Ti based biomaterials, the ultimate choice for orthopaedic implants – A review,” Prog. Mater. Sci., 54, No. 3, 397–425 (2009).

    Article  CAS  Google Scholar 

  5. J.R.S.M. Júnior, R.A. Nogueira, R.O. de Araújo, T.A.G. Donato, V.E. Arana-Chavez, A.P.R.A. Claro, J.C.S. Moraes, M.A.R. Buzalaf, and C.R. Grandini, “Preparation and characterization of Ti–15Mo alloy used as biomaterial,” Mater. Res., 14, No. 1, 107–112 (2011).

    Article  Google Scholar 

  6. W.F. Ho, C.P. Ju, and J.C. Lin, “Structure and properties of cast binary Ti–Mo alloys,” Biomaterials, 20, No. 22, 2115–2122 (1999).

    Article  CAS  Google Scholar 

  7. N.T.C. Oliveira and A.C. Guastaldi, “Electrochemical stability and corrosion resistance of Ti–Mo alloys for biomedical applications,” Acta Biomater., 5, No. 1, 399–405 (2009).

    Article  CAS  Google Scholar 

  8. L. Bolzoni, E.M. Ruiz-Navas, and E. Gordo, “Feasibility study of the production of biomedical Ti–6Al–4V alloy by powder metallurgy,” Mater. Sci. Eng. C., 49, 400–407 (2015).

    Article  CAS  Google Scholar 

  9. V.K. Balla, S. Bodhak, S. Bose, and A. Bandyopadhyay, “Porous tantalum structures for bone implants: fabrication, mechanical and in vitro biological properties,” Acta Biomater., 6, No. 8, 3349–3359 (2010).

    Article  CAS  Google Scholar 

  10. P. Mohan, A. Amigo, and V. Amigo, “Effects of Fe and Mo content on the microstructure and mechanical properties of Ti–Mo based alloys prepared by elemental blend and mechanical alloying technique,” in: PM 16 Int. Conf. Powder Metall. Part. Mater., Pune, India (2016), pp. 25–31.

  11. M. Wagner, “Medium-term results of a modern metal-on-metal system in total hip replacement,” Arthroplasty 2000, 49–62 (2001).

  12. A. Choubey, B. Basu, and R. Balasubramaniam, “Tribological behaviour of Ti-based alloys in simulated body fluid solution at fretting contacts,” Mater. Sci. Eng. A., 379, Nos. 1–2, 234–239 (2004).

    Article  Google Scholar 

  13. T. Kokubo, H. Kushitani, S. Sakka, T. Kitsugi, and T. Yamamuro, “Solutions able to reproduce in vivo surface-structure changes in bioactive glass-ceramic A-W,” J. Biomed. Mater. Res., 24, No. 6, 721–734 (1990).

    Article  CAS  Google Scholar 

  14. S. Kumar and T.S. Narayanan, “Electrochemical characterization of β-Ti alloy in Ringer’s solution for implant application,” J. Alloys Compd.. 479, Nos. 1–2, 699–703 (2009).

    Article  CAS  Google Scholar 

  15. L.J. Xu, S.L. Xiao, J. Tian, and Y.Y. Chen, “Microstructure, mechanical properties and dry wear resistance of β-type Ti–15Mo–xNb alloys for biomedical applications,” Trans. Nonferrous Met. Soc. China, 23, No. 3, 692–698 (2013).

    Article  CAS  Google Scholar 

  16. E.B. Lee, M.K. Han, B.J. Kim, H.J. Song, and Y.J. Park, “Effect of molybdenum on the microstructure, mechanical properties and corrosion behavior of Ti alloys,” Int. J. Mater. Res., 105, No. 9, 847–853 (2014).

    Article  CAS  Google Scholar 

  17. D. Özyürek and S. Tekeli, “Wear properties of titanium and Ti6Al4V alloy by mechanical milling,” High Temp. Mat. Process, 30, Nos. 1–2, 175–180 (2011).

    Google Scholar 

  18. B.K.C. Ganesh, N. Ramanaih, N. Bhuvaneswari, and S.V.N. Pammi, “Effect of Hank’s solution and shot blasting on the tribological behavior of titanium implant alloys,” Int. J. Mater. Biomater. App., 2, No. 1, 5–11 (2012).

    Google Scholar 

  19. J.H.H. Bongaerts, D. Rossetti, and J.R. Stokes, “The lubricating properties of human whole saliva,” Tribology Lett., 27, No. 3, 277–287 (2007).

    Article  CAS  Google Scholar 

  20. D. Özyürek, T. Tunçay, H. Evlen, and I. Çiftçi, “Synthesis, characterization and dry sliding wear behavior of in–situ formed TiAl3 precipitate reinforced A356 alloy produced by mechanical alloying method,” Mat. Res. 18, No. 4, 813–820 (2015).

    Article  Google Scholar 

  21. I. Simsek and D. Ozyürek, “An investigation of the effect of high-energy milling time of Ti6Al4V biomaterial on the wear performance in the simulated body fluid environment,” Powder Metall., 60, No. 5, 384–392 (2017).

    Article  CAS  Google Scholar 

  22. C. Suryanarayana, “Mechanical alloying and milling,” Prog. Mater. Sci., 46, Nos. 1–2, 1–184 (2001).

    Article  CAS  Google Scholar 

  23. G. Ren, Z. Zhang, X. Zhu, X. Men, W. Jiang, and W. Liu, “Sliding wear behaviors of Nomex fabric/phenolic composite under dry and water-bathed sliding conditions,” Friction, 2, No. 3, 264–271 (2014).

    Article  CAS  Google Scholar 

  24. D. Mareci, G. Ungureanu, D.M. Aelenei, and J.C. Mirza Rosca, “Electrochemical characteristics of titanium based biomaterials in artificial saliva,” Mater. Corros., 58, No. 11, 848–856 (2007).

    Article  CAS  Google Scholar 

  25. M. Szklarska, G. Dercz, J. Rak, W. Simka, and B. Losiewicz, “The influence of passivation type on corrosion resistance of Ti15Mo alloy in simulated body fluids,” Arch. Metall Mater., 60, No. 4, 2687–2694 (2015).

    Article  CAS  Google Scholar 

  26. D.J. Blackwood, A.W.C. Chua, K.H.W. Seah, R. Thampuran, and S.H. Teoh, “Corrosion behaviour of porous titaniumgraphite composites designed for surgical implants,” Corros. Sci., 42, No. 3, 481–503 (2000).

    Article  CAS  Google Scholar 

  27. R. Bhola, C. Chandra, F.M. Alabbas, S. Kundu, B. Mishra, and D.L. Olson, “Corrosion response of Ti6Al4V and Ti15Mo dental implant alloys in the presence of listerine oral rinse,” Int. J. Corros., 2013, 1–7 (2013).

    Article  Google Scholar 

  28. D. Mareci, R. Chelariu, I. Dan, D.M. Gordin, and T. Gloriant, “Corrosion behaviour of β-Ti20Mo alloy in artificial saliva,” J. Mater. Sci. Mater. Med., 21, No. 11, 2907–2913 (2010).

    Article  CAS  Google Scholar 

  29. E. Bardal, Corrosion and Protection, London, Springer-Verlag Ltd. (2004), 315 pp.

  30. D. Mareci, R. Chelariu, S. Ivanescu, D.M. Gordin, I. Cretescu, and T. Gloriant, “Electrochemical behavior of a new titanium alloy for dental applications,” Rev. Chim., 60, No. 8, 787–793 (2009).

    CAS  Google Scholar 

  31. E. Vasilescu, P. Drob, D. Raducanu, I. Cinca, D. Mareci, J.M.C. Moreno, M. Popa, C. Vasilescu, and J.C.M. Roscad, “Effect of thermo-mechanical processing on the corrosion resistance of Ti6Al4V alloys in biofluids,” Corros. Sci., 51, No. 12, 2885–2896 (2009).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Dursun Özyürek.

Additional information

Published in Poroshkova Metallurgiya, Vol. 58, Nos. 7–8 (528), pp. 98–108, 2019.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Şimşek, I., Özyürek, D. Investigation of Wear and Corrosion Behaviors of Ti15Mo Alloy Produced by Mechanical Alloying Method in SBF Environment. Powder Metall Met Ceram 58, 446–454 (2019). https://doi.org/10.1007/s11106-019-00094-9

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11106-019-00094-9

Keywords

Navigation