Skip to main content

Advertisement

Log in

Magma generation and sulfide saturation of Permian mafic-ultramafic intrusions from the western part of the Northern Tianshan in NW China: implications for Ni-Cu mineralization

  • Article
  • Published:
Mineralium Deposita Aims and scope Submit manuscript

Abstract

Compared to Permian magmatic Ni-Cu sulfide deposits in the eastern part of the Northern Tianshan, such as Huangshan and Huangshandong, those in the western part (e.g., Baixintan and Lubei) are poorly documented. Zircon ID-TIMS U-Pb age data (279.7 ± 0.2 Ma) of lherzolite and LA-ICPMS U-Pb age data (277.8 ± 3.4 Ma) of a hornblende gabbro suggest the Lubei intrusion was emplaced in the Early Permian. The Baixintan and Lubei mafic-ultramafic intrusive rocks are characterized by enrichments of large ion lithophile elements and Th and U relative to the high field strength elements, as well as depletion of Nb and Ta relative to mid-ocean ridge basalt. The (87Sr/86Sr)t (0.70354–0.70713), εNd(t) (2.80 to + 7.05), and εHf(t) (2.50–18.4) values for the intrusions indicate that they have assimilated Tianshan basement rocks, whereas the Se/S ratios (181 × 10−6–418 × 10−6) and δ34SCDT values (− 0.13‰ to 0.90‰) of the sulfides suggest that crustal sulfur has not been incorporated into the magma. The decrease in Pd/Zr with increasing (Th/Nb)PM indicates that sulfide saturation accompanied crustal contamination. The olivine compositions and whole-rock chalcophile elements of the Baixintan and Lubei intrusions imply that the parental magma of the intrusive rocks in the west contains higher chalcophile elements than those in the east, which suggests that the mafic-ultramafic intrusions in the western part of the Northern Tianshan should be regarded as favorable Ni-Cu sulfide exploration targets.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  • Aldanmaz E, Pearce JA, Thirlwall MF, Mitchell JG (2000) Petrogenetic evolution of Late Cenozoic, post-collision volcanism in western Anatolia, Turkey. J Volcanol Geotherm Res 102:67–95

    Google Scholar 

  • Barnes SJ (1986) The effect of trapped liquid crystallization on cumulus mineral compositions in layered intrusions. Contrib Mineral Petrol 93:524–531

    Google Scholar 

  • Barnes SJ, Lightfoot PC (2005) Formation of magmatic nickel sulfide group ore deposits and processes affecting their copper and platinum-group element contents. Economic Geology 100th Anniversary Volume: 179–213

  • Barnes SJ, Maier WD (1999) The fractionation of Ni, Cu, and the noble metals in silicate and sulfide liquids. In Dynamic processes in magmatic ore deposits and their application to mineral exploration. In: Keays RR, Lesher CM, Lightfoot PC, Farrow CEG (eds) Geological Association of Canada, Short course notes 13, pp 69–106

    Google Scholar 

  • Barnes SJ, Couture JF, Sawyer EW, Bouchaib C (1993) Nickel-copper occurrences in the Belleterre-Angliers belt of the Pontiac Subprovince and the use of Cu-Pd ratios in interpreting platinum-group element distributions. Econ Geol 88:1402–1419

    Google Scholar 

  • Barnes SJ, Makovicky E, Makovicky M, Hansen JR, Moller SK (1997) Partition coefficients for Ni, Cu, Pd, Pt, Rh and Ir between monosulfide solid solution and sulfide liquid and the implication for the formation of compositionally zoned Ni–Cu sulfide bodies by fractional crystallization of sulfide liquid. Can J Earth Sci 34:366–374

    Google Scholar 

  • Barnes SJ, Osborne GA, Cook D, Barnes L, Maier WD, Godel B (2011) The Santa Rita nickel sulfide deposit in the Fazenda Mirabela intrusion, Bahia, Brazil: geology, sulfide geochemistry, and genesis. Econ Geol 106:1083–1110

    Google Scholar 

  • Barnes SJ, Godel B, Gürer D, Brenan JM, Robertson J, Paterson D (2013) Sulfide-olivine Fe-Ni exchange and the origin of anomalously Ni rich magmatic sulfides. Economic Geology 108:1971–1982

    Google Scholar 

  • BGMX (Bureau of Geology and Mineral Resources of Xinjiang Uygur Autonomous Region) (1993) Regional geology of Xinjiang Uygur autonomous region. Geological Publishing House, Beijing, pp 1–841 (in Chinese with English abstract)

    Google Scholar 

  • Black LP, Gulson BL (1978) The age of the mud tank carbonatite, Strangways Range, Northern Territory. BMRJ J Aust Geol Geophys 3:227–232

    Google Scholar 

  • Boudreau AE, Meurer WP (1999) Chromatographic separation of the platinum-group elements, gold, base metals and sulfur during degassing of a compacting and solidifying igneous crystal pile. Contrib Mineral Petrol 134:174–185

    Google Scholar 

  • Campbell IH, Naldrett AJ (1979) The influence of silicate: sulfide ratios on the geochemistry of magmatic sulfides. Econ Geol 74:1503–1506

    Google Scholar 

  • Chen XJ, Shu LS, Santosh M (2011) Late Paleozoic post-collisional magmatism in the Eastern Tianshan Belt, Northwest China: new insights from geochemistry, geochronology and petrology of bimodal volcanic rocks. Lithos 127:581–598

    Google Scholar 

  • Chen BY, Yu JJ, Liu SJ (2018) Source characteristics and tectonic setting of mafic-ultramafic intrusions in Northern Xinjiang, NW China: insights from the petrology and geochemistry of the Lubei mafic-ultramafic intrusion. Lithos 308-309:329–345

    Google Scholar 

  • Deng YF, Song XY, Jie W, Chen SL, Li J (2011a) Petrogenesis of the Huangshandong Ni-Cu sulfide-bearing mafic-ultramafic intrusion, Northern Tianshan, Xinjiang: evidence from major and trace elements and Sr-Nd isotope. Acta Geol Sin 85:1436–1451 (in Chinese with English abstract)

    Google Scholar 

  • Deng YF, Song XY, Chen LM, Cheng SL, Zhang XL, Li J (2011b) Features of the mantle source of the Huangshanxi Ni-Cu sulfide-bearing mafic-ultramafic intrusion, eastern Tianshan. Acta Petrol Sin 27:3640–3652 (in Chinese with English abstract)

    Google Scholar 

  • Deng YF, Song XY, Chen LM, Zhou TF, Pirajno F, Yuan F, Xie W, Zhang DY (2014) Geochemistry of the Huangshandong Ni-Cu deposit in northwestern China: implications for the formation of magmatic sulfide mineralization in orogenic belts. Ore Geol Rev 56:181–198

    Google Scholar 

  • Deng YF, Song XY, Hollings P, Zhou T, Yuan F, Chen LM, Zhang D (2015) Role of asthenosphere and lithosphere in the genesis of the Early Permian Huangshan mafic-ultramafic intrusion in the Northern Tianshan, NW China. Lithos 227:241–254

    Google Scholar 

  • Deng XH, Wang JB, Pirajno F, Wang YW, Li YC, Li C, Zhou LM, Chen YJ (2016) Re–Os dating of chalcopyrite from selected mineral deposits in the Kalatag district in the eastern Tianshan Orogen, China. Ore Geol Rev 77:72–81

    Google Scholar 

  • Deng YF, Song XY, Hollings P, Chen LM, Zhou T, Yuan F, Xie W, Zhang D, Zhao BB (2017) Lithological and geochemical constraints on the magma conduit systems of the Huangshan Ni-Cu sulfide deposit, NW China. Mineral Deposita 52:845–862

    Google Scholar 

  • Eckstrand O, Grinenko L, Krouse H, Paktunc A, Schwann P, Scoates R (1989) Preliminary data on sulphur isotopes and Se/S ratios, and the source of sulphur in magmatic sulphides from the Fox River Sill, Molson Dykes and Thompson nickel deposits, northern Manitoba 1. Current Research Part: C, Geological Survey of Canada, Paper 89-1C: 235–242

  • Eggins SM, Grün R, McCulloch MT, Pike AWG, Chappell J, Kinsley L, Mortimer G, Shelley M, Murray-Wallace CV, Spötl C, Taylor L (2005) In situ U-series dating by laser-ablation multi-collector ICP-MS: new prospects for Quaternary geochronology. Quat Sci Rev 24:2523–2538

    Google Scholar 

  • Feng YQ, Qian ZZ, Duan J, Sun T, Xu G, Jiang C, Ren M, Chen HJ (2017) Genesis and re-forming potential of mafic-ultramafic intrusions in the western part of east Tianshan Cu-Ni metallogenic belt, Xinjiang. Acta Geol Sin 91:792–811 (in Chinese with English abstract)

    Google Scholar 

  • Feng YQ, Qian ZZ, Duan J, Xu G, Ren M, Jiang C (2018) Geochronological and geochemical study of the Baixintan magmatic Ni-Cu sulphide deposit: new implications for the exploration potential in the western part of the East Tianshan nickel belt (NW China). Ore Geol Rev 95:366–381

    Google Scholar 

  • Fleet ME, Chryssoulis SL, Stone WE, Weisener CG (1993) Partitioning of platinum-group elements and Au in the Fe–Ni–Cu–S system: experiments on the fractional crystallization of sulfide melt. Contrib Mineral Petrol 115:36–44

    Google Scholar 

  • Gao JF, Zhou MF (2012) Generation and evolution of siliceous high magnesium basaltic magmas in the formation of the Permian Huangshandong intrusion (Xinjiang, NW China). Lithos 162-163:128–139

    Google Scholar 

  • Gao JF, Zhou MF, Lightfoot PC, Wang CY, Qi L, Sun M (2013) Sulfide saturation and magma emplacement in the formation of the Permian Huangshandong Ni-Cu Sulfide Deposit, Xinjiang, Northwestern China. Econ Geol 108:1833–1848

    Google Scholar 

  • Govindaraju K (1994) Compilation of working values and sample description for 383 geostandards. Geostand Newslett 18:1–158

    Google Scholar 

  • Han CM, Xiao WJ, Zhao GC, Ao SJ, Zhang JE, Qu WJ, Du AD (2010) In-situ U-Pb, Hf and Re-Os isotopic analyses of the Xiangshan Ni-Cu-Co deposit in Eastern Tianshan (Xinjiang), Central Asia Orogenic Belt: constraints on the timing and genesis of the mineralization. Lithos 120:547–562

    Google Scholar 

  • Hawkesworth C, Turner S, Peate D, McDermott F, Calsteren P (1997) Elemental U and Th variations in island arc rocks: implications for U-series isotopes. Chem Geol 139:207–221

    Google Scholar 

  • Hiess J, Bennett VC, Nutman AP, Williams IS (2009) In situ U-Pb, O and Hf isotopic compositions of zircon and olivine from Eoarchaean rocks, West Greenland: new insights to making old crust. Geochim Cosmochim Acta 73:4489–4516

    Google Scholar 

  • Hofmann AW (1988) Chemical differentiation of the Earth: the relationship between mantle, continental crust, and oceanic crust. Earth Planet Sci Lett 90:297–314

    Google Scholar 

  • Hu AQ, Jahn B, Zhang GX, Chen YB, Zhang QF (2000) Crustal evolution and Phanerozoic crustal growth in northern Xinjiang: Nd isotopic evidence. Part I. Isotopic characterization of basement rocks. Tectonophysics 328:15–51

    Google Scholar 

  • Jahn BM, Wu FY, Chen B (2000) Massive granitoid generation in Central Asia: Nd isotope evidence and implication for continental growth in the Phanerozoic. Episodes 23:82–92

    Google Scholar 

  • Johnson MC, Plank T (1999) Dehydration and melting experiments constrain the fate of subducted sediments. Geochem Geophys Geosyst 1. https://doi.org/10.1029/1999GC000014

    Google Scholar 

  • Keays RR (1995) The role of komatiitic and picritic magmatism and S-saturation in the formation of ore deposits. Lithos 34:1–18

    Google Scholar 

  • Keays RR, Lightfoot PC (2010) Crustal sulfur is required to form magmatic Ni-Cu sulfide deposits: evidence from chalcophile element signatures of Siberian and Deccan Trap basalts. Mineral Deposita 45:241–257

    Google Scholar 

  • Kelemen PB, Hanghøj K, Greene AR (2004) One view of the geochemistry of subduction-related magmatic arcs, with an emphasis on primitive andesite and lower crust. In: Rudnick RL (ed) Treatise on geochemistry, the crust. Elsevier, Amsterdam, pp 593–659

    Google Scholar 

  • Li CS, Naldrett AJ (1999) Geology and petrology of the Voisey's Bay intrusion: reaction of olivine with sulfide and silicate liquids. Lithos 47:1–31

    Google Scholar 

  • Li CS, Naldrett AJ (2000) Melting reactions of gneissic inclusions with enclosing magma at Voisey’s Bay, Labrador, Canada: implications with respect to ore genesis. Econ Geol 95:801–814

    Google Scholar 

  • Li CS, Ripley EM (2003) Compositional variations of olivine and sulfur isotopes in the Noril'sk and Talnakh intrusions, Siberia: implications for ore-forming processes in dynamic magma conduits. Econ Geol 98:69–86

    Google Scholar 

  • Li CS, Ripley EM (2005) Empirical equations to predict the sulfur content of mafic magmas at sulfide saturation and applications to magmatic sulfide deposits. Mineral Deposita 40:218–230

    Google Scholar 

  • Li CS, Ripley EM (2011) The giant Jinchuan Ni-Cu (PGE) deposit: tectonic setting, magma evolution, ore genesis and exploration implications. Rev Econ Geol 17:163–180

    Google Scholar 

  • Li C, Naldrett AJ, Ripley EM (2001) Critical factors for the formation of a nickel-copper deposit in an evolved magma system: lessons from a composition of the Pants Lake and Voisey’s Bay sulfide occurences in Labrador, Canada. Mineral Deposita 36:85–92

    Google Scholar 

  • Li CS, Lightfoot PC, Amelin Y, Naldrett AJ (2000) Contrasting petrological and geochemical relationships in the Voisey’s Bay and Mushuau intrusions, Labrador, Canada: implications for ore genesis. Econ Geol 95:771–799

    Google Scholar 

  • Li CS, Xu Z, deWaal SA, Ripley EM, Maier WD (2004) Compositional variations of olivine from the Jinchuan Ni-Cu sulfide deposit, western China: implications for ore genesis. Mineral Deposita 39:159–172

    Google Scholar 

  • Li JY, Wang KZ, Sun GH, Mo SG, Li WQ, Yang TN, Gao LM (2006a) Paleozoic active margin slices in the southern Turfan Hami basin: geological records of subduction of the Paleo Asian Ocean plate in central Asian regions. Acta Petrol Sin 22:1087–1102 (in Chinese with English abstract)

    Google Scholar 

  • Li JY, Song B, Wang KZ, Li YP, Sun GH, Qi DY (2006b) Permian mafic-ultramafic complexes on the southern margin of the Tu-Ha basin, east Tianshan mountains: geological records of vertical crustal growth in Central Asia. Acta Geosci Sin 27:424–446 (in Chinese with English abstract)

    Google Scholar 

  • Li CS, Naldrett AJ, Ripley EM (2007) Controls on the Fo and Ni contents of olivine in sulfide-bearing mafic/ultramafic intrusions: principles, modeling, and examples from Voisey’s Bay. Earth Sci Front 14:177–185

    Google Scholar 

  • Li X, Wang DK, Zhao SM (2014) The discovery of Baixintan magmatic Ni-Cu sulfide deposits in Hami area, Xinjiang. Xinjiang Geol 32:466–469 (in Chinese with English abstract)

    Google Scholar 

  • Li CS, Zhang ZW, Li WY, Wang YL, Sun T, Ripley EM (2015) Geochronology, petrology and Hf–S isotope geochemistry of the newly-discovered Xiarihamu magmatic Ni–Cu sulfide deposit in the Qinghai–Tibet plateau, western China. Lithos 216-217:224–240

    Google Scholar 

  • Lightfoot PC, Hawkesworth CJ (1988) Origin of Deccan Trap lavas: evidence from combined trace element and Sr-, Nd- and Pb-isotope studies. Earth Planet Sci Lett 91:89–104

    Google Scholar 

  • Lightfoot PC, Hawkesworth CJ (1997) Flood basalts and magmatic Ni, Cu and PGE sulphide mineralization: comparative geochemistry of the Noril’sk (Siberian Trap) and West Greenland sequences: American Geophysical Union Monograph 100: 357–380

  • Liu DQ, Tang YL, Zhou RH (2005) Copper deposits and nickel deposits in Xinjiang. China. Beijing: Geological Publishing House, 360 p. (in Chinese with English abstract)

  • Long LL, Wang JB, Wang YW, Fang TH, Mao QG, Gao YH, Zhao LT, Gao LM (2017) Zircon U-Pb geochronological, geochemistry characteristics and potential mineralization significance of the rhyolite in Kalatage copper polymetallic ore cluster area, eastern Tianshan. Acta Prtrologica Sinica 33:367–384 (in Chinese with English abstract)

    Google Scholar 

  • Ludwig KR (2001) Isoplot/EX, version 2.49. A geochronological toolkit for Microsoft Excel. Berkeley Geochronological Center Special Publication, Berkeley, California, pp 1–55

    Google Scholar 

  • Ludwig KR (2012) Isoplot 3.75–4.15: a geochronological toolkit for Microsoft Excel. Berkeley Geochronology Center Special Publication, Berkeley, California, pp 1–75

    Google Scholar 

  • Ma RS, Wang CY, Ye SF, Liu GB (1993) Tectonic framework and crustal evolution of the Eastern Tianshan. Nanjing University Press, Nanjing (in Chinese)

    Google Scholar 

  • Maier WD, Barnes SJ (2010) The Kabanga Ni sulfide deposits, Tanzania: II. Chalcophile and siderophile element geochemistry. Mineral Deposita 45:443–460

    Google Scholar 

  • Maier WD, Li C, De Waal SA (2001) Why are there no major Ni-Cu sulfide deposits in large layered mafic-ultramafic intrusions. Can Mineral 39:547–556

    Google Scholar 

  • Maier WD, Barnes SJ, Chinyepi G, Barton JJ, Eglington B, Setshedi T (2008) The composition of magmatic Ni-Cu-(PGE) sulfide deposits in the Tati and Selebi-Phikwe belts of eastern Botswana. Mineral Deposita 43:37–60

    Google Scholar 

  • Mao JW, Yang JM, Qu WJ, Du AD, Wang ZL, Han CM (2002) Re-Os dating of Cu-Ni sulfide ores from Huangshandong deposit in Xinjiang and its geodynamic significance. Mineral Deposits 21:323–330 (in Chinese with English abstract)

    Google Scholar 

  • Mao JW, Pirajno F, Zhang ZH, Chai FM, Wu H, Chen SP, Chen LS, Yang JM, Zhang CQ (2008) A review of the Cu-Ni sulphide deposits in the Chinese Tianshan and Altay orogens (Xinjiang Autonomous Region, NW China): principal characteristics and ore-forming processes. J Asian Earth Sci 32:184–203

    Google Scholar 

  • Mao QG, Fang TH, Wang JB, Wang SL, Wang N (2010) Geochronology studies of the Early Paleozoic Honghai massive sulfide deposits and its geological significance in Kalatage area, eastern Tianshan Mountain. Acta Petrol Sin 26:2017–2026 (in Chinese with English abstract)

    Google Scholar 

  • Mao YJ, Qin KZ, Li CS, Xue SC, Ripley EM (2014) Petrogenesis and ore genesis of the Permian Huangshanxi sulfide ore-bearing mafic-ultramafic intrusion in the Central Asian Orogenic Belt, western China. Lithos 200-201:111–125

    Google Scholar 

  • Mao YJ, Qin KZ, Li CS, Tang DM (2015) A modified genetic model for the Huangshandong magmatic sulfide deposit in the Central Asian Orogenic Belt, Xinjiang, western China. Mineral Deposita 50:65–82

    Google Scholar 

  • Mao YJ, Qin KZ, Barnes SJ, Tang DM, Xue SC, Vaillant ML (2017a) Genesis of the Huangshannan high-Ni tenor magmatic sulfide deposit in the Eastern Tianshan, northwest China: constraints from PGE geochemistry and Os–S isotopes. Ore Geol Rev 90:591–606

    Google Scholar 

  • Mao QG, Yu MJ, Xiao WJ, Windley BF, Li YC, Wei XF, Zhu JJ, Lv XQ (2017b) Skarn-mineralized porphyry adakites in the Harlik arc at Kalatage, E. Tianshan (NW China): slab melting in the Devonian-early Carboniferous in the southern Central Asian Orogenic Belt. J Asian Earth Sci. https://doi.org/10.1016/j.jseaes.2017.03.021

    Google Scholar 

  • Mattinson JM (2005) Zircon U-Pb chemical abrasion (“CA-TIMS”) method: combined annealing and multi-step partial dissolution analysis for improved precision and accuracy of zircon ages. Chem Geol 220:47–66

    Google Scholar 

  • Mavrogenes JA, O'Neill HSC (1999) The relative effects of pressure, temperature and oxygen fugacity on the solubility of sulfide in mafic magmas. Geochim Cosmochim Acta 63:1173–1180

    Google Scholar 

  • Naldrett AJ (1994) Proceedings of the Sudbury ± Noril'sk Symposium. Ontario Geological Survey Epec 5:423

    Google Scholar 

  • Naldrett AJ (1997) Key factors in the genesis of Noril'sk, Sudbury, Jinchuan, Voisey's Bay and other world-class Ni-Cu-PGE deposits: implications for exploration. Aust J Earth Sci 44:283–315

    Google Scholar 

  • Naldrett AJ (1999) World-class Cu-Ni-PGE deposits: key factors in their genesis. Mineral Deposita 34:227–240

    Google Scholar 

  • Naldrett AJ, Innes DC, Sowa J, Gorton MP (1982) Compositional variations within and between five Sudbury ore deposits. Econ Geol 77:1519–1534

    Google Scholar 

  • Ohmoto H, Rye RO (1979) Isotopes of sulfur and carbon. In: Barnes HL (ed) Geochemistry of hydrothermal ore deposits, 2nd edn. John Wiley and Sons, London, pp 509–567

    Google Scholar 

  • Peach CL, Mathez EA, Keays RR (1990) Sulfide melt-silicate melt distribution coefficients for noble metals and other chalcophile elements as deduced from MORB: implications for partial melting. Geochim Cosmochim Acta 54:3379–3389

    Google Scholar 

  • Pearce JA (1982) Trace elements characteristics of lavas from destructive plate boundaries. In: Thorpe RS (ed) Andesites: orogenic andesites and related rocks. Wiley, New York, pp 525–548

    Google Scholar 

  • Pearce JA (1983) The role of sub-continental lithosphere in magma genesis at destructive plate margins. In: Hawkesworth CJ, Norry MJ (eds) Continental basalts and mantle xenoliths. Shiva, Nantwich, pp 230–249

    Google Scholar 

  • Pettigrew N, Hattori K (2006) The Quetico Intrusions of Western Superior Province: Neo-Archean examples of Alaskan/Ural-type mafic-ultramafic intrusions. Precambrian Res 149:21–42

    Google Scholar 

  • Qi L, Hu J, Gregoire DC (2000) Determination of trace elements in granites by inductively coupled plasma mass spectrometry. Talanta 51:507–513

    Google Scholar 

  • Qi L, Zhou MF, Wang CY (2004) Determination of low concentrations of platinum group elements in geological samples by ID-ICP-MS. J Anal At Spectrom 19:1335–1339

    Google Scholar 

  • Qi L, Zhou MF, Wang CY, Sun M (2007) Evaluation of the determination of Re and PGEs abundances of geological samples by ICP-MS coupled with a modified Carius tube digestion at different temperatures. Geochem J 41:407–414

    Google Scholar 

  • Qin KZ, Fang TH, Wang SL, Zhu BQ, Feng YM, Yu HF, Xiu QY (2002) Plate tectonics division, evolution and metallogenic settings in eastern Tianshan mountains, NW-China. Xinjiang Geol 20:302–308 (in Chinese with English abstract)

    Google Scholar 

  • Qin KZ, Zhang LC, Xiao WJ, Xu XW, Yan Z, Mao JW (2003) Overview of major Au, Cu, Ni and Fe deposits and metallogenic evolution of the eastern Tianshan Mountains, Northwestern China. In: Mao JW, Goldfarb R, Seltmann R, Wang DH, Xiao WJ, Hart C (eds) Tectonic evolution and metallogeny of the Chinese Altay and Tianshan, vol 10. IAGOD Guidebook Series, London, pp 227–248

    Google Scholar 

  • Qin KZ, Sun BX, Sakyi PA, Tang DM, Li XH, Sun H, Xiao QH, Liu PP (2011) SIMS zircon U-Pb geochronology and Sr-Nd isotopes of Ni-Cu-bearing mafic-ultramafic intrusions in Eastern Tianshan and Beishan in correlation with flood basalts in Tarim basin (NW China): constraints on a ca. 280 Ma mantle plume. Am J Sci 311:237–260

    Google Scholar 

  • Ren MH, Wang CY, Ni K, Sun YL (2013) Differentiation of magmas in the formation of Permian mafic-ultramafic intrusions in the Dacaotan area, Eastern Tianshan: implications for Ni-Cu-(PGE) sulfide mineralization potentials. Acta Petrol Sin 29:3473–3486 (in Chinese with English abstract)

    Google Scholar 

  • Ripley EM (2009) Magmatic sulfide mineralization in Alaskan-type complexes. In: Li CS, Ripley EM (eds) New development in magmatic Ni-Cu and PGE deposits, vol 7. Geological Publishing House, Beijing, pp 219–228

    Google Scholar 

  • Ripley EM, Li CS (2013) Sulfide saturation in mafic magmas: is external sulfur required for magmatic Ni-Cu-(PGE) ore genesis? Econ Geol 108:45–58

    Google Scholar 

  • Ripley EM, Li C, Shin D (2002) Paragneiss assimilation in the genesis of magmatic Ni-Cu-Co sulfide mineralization at Voisey's Bay, Labrador: δ34S, δ13C, and Se/S evidence. Econ Geol 97:1307–1318

    Google Scholar 

  • Robertson JC, Ripley EM, Barnes SJ (2015) Sulfur liberation from country rocks and incorporation in mafic magmas. Econ Geol 110:1111–1123

    Google Scholar 

  • Roeder PL, Emslie RF (1970) Olivine-liquid equilibrium. Contrib Mineral Petrol 29:275–289

    Google Scholar 

  • Rudnick R, Gao S (2003) The role of lower crustal recycling in continent formation. Geochim Cosmochim Acta 67:403

    Google Scholar 

  • San JZ, Qin KZ, Tang DM, Su BX, Sun H, Xiao QH, Liu PP, Cao MJ (2010) Precise zircon U-Pb ages of Tulargen large Cu-Ni-ore bearing mafic-ultramafic complex and their geological implications. Acta Petrol Sin 26:3027–3035 (in Chinese with English abstract)

    Google Scholar 

  • Seat Z, Beresford SW, Grguric BA, Mary Gee MA, Gressineau NV (2009) Reevaluation of the role of external sulfur addition in the genesis of Ni-Cu-PGE deposits: evidence from the Nebo-Babel Ni-Cu-PGE deposit, West Musgrave, Western Australia. Econ Geol 104:521–538

    Google Scholar 

  • Sengör AMC, Natal'in BA, Burtman VS (1993) Evolution of the Altaid tectonic collage and Paleozoic crustal growth in Asia. Nature 364:299–307

    Google Scholar 

  • Shu LS, Wang B, Zhu WB, Guo ZJ, Charvet J, Zhang Y (2010) Timing of initiation of extension in the Tianshan, based on structural, geochemical and geochronological analyses of bimodal volcanism and olistostrome in the Bogda Shan (NW China). International Journal of Earth Sciences (Geol Rundsch) 100:1647–1663. https://doi.org/10.1007/s00531-010-0575-5

    Article  Google Scholar 

  • Song XY, Li XR (2009) Geochemistry of the Kalatongke Ni–Cu–(PGE) sulfide deposit, NW China: implications for the formation of magmatic sulfide mineralization in a postcollisional environment. Mineral Deposita 44:303–327

    Google Scholar 

  • Song XY, Xie W, Deng YF, Crawford AJ, Zheng WQ, Zhou GF, Deng G, Chen SL, Li J (2011) Slab break-off and the formation of Permian mafic-ultramafic intrusions in southern margin of Central Asian Orogenic Belt, Xinjiang, NW China. Lithos 127:128–143

    Google Scholar 

  • Song XY, Chen LM, Deng YF, Xie W (2013) Syncollisional tholeiitic magmatism induced by asthenosphere upwelling owing to slab detachment at the southern margin of the Central Asian Orogenic Belt. J Geol Soc Lond 170:941–950

    Google Scholar 

  • Song XY, Yi JN, Chen LM, She YW, Liu CZ, Dang XY, Yang QA, Wu SK (2016) The giant Xiarihamu Ni-Co sulfide deposit in the East Kunlun orogenic belt, northern Tibet plateau, China. Econ Geol 111:29–55

    Google Scholar 

  • Su CQ, Jiang CY, Xia MZ, Zhang L, Ji HG, Guo FF, Liu XJ (2008) Zircon SHRIMP U-Pb dating from granites of the metamorphic core complex system in Jueluotage tectonic belt and its geological significance. Acta Petrol Sin 24:2789–2799 (in Chinese with English abstract)

    Google Scholar 

  • Su BX, Qin KZ, Sakyi PA, Li XH, Yang YH, Sun H, Tang DM, Liu PP, Xiao QH, Malaviarachchi SP (2011) U-Pb ages and Hf-O isotopes of zircons from Late Paleozoic mafic-ultramafic units in the southern Central Asian Orogenic Belt: tectonic implications and evidence for an Early-Permian mantle plume. Gondwana Res 20:516–531

    Google Scholar 

  • Su BX, Qin KZ, Su H, Tang DM, Sakyi PA, Chu ZY, Liu PP, Xiao QH (2012) Subduction-induced mantle heterogeneity beneath Eastern Tianshan and Beishan: insights from Nd-Sr-Hf-O isotopic mapping of Late Paleozoic mafic-ultramafic complexes. Lithos 134-135:41–51

    Google Scholar 

  • Su BX, Qin KZ, Tang DM, Sakyi PA, Liu PP, Su H, Xiao QH (2013) Late Paleozoic mafic-ultramafic intrusions in southern Central Asian Orogenic Belt (NW China): insight into magmatic Ni-Cu sulfide mineralization in orogenic setting. Ore Geol Rev 51:57–73

    Google Scholar 

  • Sun SS, McDonough W (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Geol Soc Lond, Spec Publ 42:313–345

    Google Scholar 

  • Sun T, Qian ZZ, Deng YF, Li CS, Song XY, Tang QY (2013) PGE and isotope (Hf-Sr-Nd-Pb) constraints on the origin of the Huangshandong magmatic Ni-Cu sulfide deposit in the Central Asian Orogenic Belt, Northwestern China. Econ Geol 108:1849–1864

    Google Scholar 

  • Tang DM, Qin KZ, Sun H, Su BX, Xiao QH (2012) The role of crustal contamination in the formation of Ni-Cu sulfide deposits in Eastern Tianshan, Xinjiang, Northwest China: evidence from trace element geochemistry, Re-Os, Sr-Nd, zircon Hf-O, and sulfur isotopes. J Asian Earth Sci 49:145–160

    Google Scholar 

  • Tang DM, Qin KZ, Su BX, Sakyi PA, Mao YJ, Xue SC (2014) Petrogenesis and mineralization of the Hulu Ni-Cu sulphide deposit in Xinjiang, NW China: constraints from Sr-Nd isotopic and PGE compositions. Int Geol Rev 56:711–733

    Google Scholar 

  • Thakurta J, Ripley EM, Li CS (2008) Geochemical constraints on the origin of sulfide mineralization in the Duke Island Complex, southeastern Alaska. Geochem Geophys Geosyst 9:Q07003

    Google Scholar 

  • Tornos F, Casquet C, Galindo C, Velasco F, Canales A (2001) A new style of Ni-Cu mineralization related to magmatic breccia pipes in a transpressional magmatic arc, Aguablanca, Spain. Mineral Deposita 36(7):700–706

    Google Scholar 

  • Wang YL, Zhang ZW, You MX, Li X, Li K, Wang BL (2015) Chronological and geochemical characteristics of the Baixintan Ni-Cu deposit in Eastern Tianshan Mountains, Xinjiang, and their implications for Ni-Cu mineralization. Geol China 42:452–467 (in Chinese with English abstract)

    Google Scholar 

  • Wang YH, Zhang FF, Liu JJ, Que CY (2016a) Carboniferous magmatism and mineralization in the area of the Fuxing Cu deposit, Eastern Tianshan, China: evidence from zircon U–Pb ages, petrogeochemistry, and Sr–Nd–Hf–O isotopic compositions. Gondwana Res 34:109–128

    Google Scholar 

  • Wang YL, Zhang ZW, Zhang JW, You MX, Li K, Wang BL (2016b) Mineralogy and Sr-Nd isotope characteristics of Baixintan Ni-Cu deposit in eastern Tianshan mountains, Xinjiang, and mineralization process. Acta Geol Sin 90:2747–2758 (in Chinese with English abstract)

    Google Scholar 

  • Wendlandt R (1982) Sulfide saturation of basalt and andesite melts at high pressures and temperatures. Am Mineral 67:877–885

    Google Scholar 

  • Wiedenbeck M, Alle P, Corfu F, Griffin WL, Meier M, Oberli F, Quadt AV, Roddick JC, Spiegel W (1995) Three natural zircon standards for U-Th-Pb, Lu-Hf, trace element and REE analyses. Geostand Geoanal Res 19:1–23

    Google Scholar 

  • Wilson M (1989) Igneous petrogenesis. Unwin Hyman, London, pp 1–466

    Google Scholar 

  • Windley BF, Alexeiev D, Xiao WJ, Kröner A, Badarch G (2007) Tectonic models for accretion of the Central Asian Orogenic Belt. J Geol Soc Lond 164:31–47

    Google Scholar 

  • Windrim DP, Mcculloch MT (1986) Nd and Sr isotopic systematics of central Australian granulites: chronology of crustal development and constraints on the evolution of lower continental crust. Contrib Mineral Petrol 94:289–303

    Google Scholar 

  • Xiao WJ, Zhang LC, Qin KZ, Sun S, Li JL (2004) Paleozoic accretionary and collisional tectonics of the eastern Tianshan (China): implications for the continental growth of central Asia. Am J Sci 304:370–395

    Google Scholar 

  • Xiao WJ, Han CM, Yuan C, Sun M, Lin SF, Chen HL, Li ZL, Li JL, Sun S (2008) Middle Cambrian to Permian subduction-related accretionary orogenesis of Northern Xinjiang, NW China: implications for the tectonic evolution of central Asia. J Asian Earth Sci 32:102–117

    Google Scholar 

  • Xie W, Song XY, Chen LM, Deng YF, Zheng WQ, Wang YS, Ba DH, Zhang XQ, Luan Y (2014) Geochemistry insights on the genesis of the subduction-related Heishan magmatic Ni-Cu-(PGE) deposit in Gansu, NW China, at the southern margin of the Central Asian Orogenic Belt. Econ Geol 109:1563–1583

    Google Scholar 

  • Xie W, Xu YG, Chen YB, Luo ZY, Hong LB, Ma L, Liu HQ (2016a) High-alumina basalts from the Bogda Mountains suggest an arc setting for Chinese Northern Tianshan during the Late Carboniferous. Lithos 256-257:165–181

    Google Scholar 

  • Xie W, Luo ZY, Xu YG, Chen YB, Hong LB, Ma L, Ma Q (2016b) Petrogenesis and geochemistry of the Late Carboniferous rear-arc (or back-arc) pillow basaltic lava in the Bogda Mountains, Chinese North Tianshan. Lithos 244:30–42

    Google Scholar 

  • Yang YH, Zhang FH, Chu ZY, Xie XW, Wu FY (2010) Combined chemical separation of Lu, Hf, Rb, Sr, Sm and Nd from a single rock digest and precise and accurate isotope determinations of Lu-Hf, Rb-Sr and Sm-Nd isotope systems using multi-collector ICP-MS and TIMS. Int J Mass Spectrom 290:120–126

    Google Scholar 

  • Yang WZ, Ren Y, Tian JT, She JZ, Yang GG (2017) The discovery of Lubei Cu-Ni sulfide deposit in eastern Tianshan, NW China and its significant. Bulletin of Mineraloy, Petrology and Geochemistry 36:112–120 (in Chinese with English abstract)

    Google Scholar 

  • Yuan F, Zhou TF, Fan Y, Tan LG, David C, Sebastien M, Wang QM, Wang WJ (2007) LA-ICPMS U-Pb age of zircon from basalt of Matoutan Group in Shilipo native copper mineralized area, Eastern Tianshan, Xinjiang. Acta Petrol Sin 23:1973–1980 (in Chinese with English abstract)

    Google Scholar 

  • Zhang LC, Xiao WJ, Qin KZ, Zhang Q (2006) The adakite connection of the Tuwu-Yandong copper porphyry belt, eastern Tianshan, NW China: trace element and Sr-Nd-Pb isotope geochemistry. Mineral Deposita 41:188–200

    Google Scholar 

  • Zhang M, Stephenson PJ, O’Reilly SY, McCulloch M, Norman M (2001) Petrogenesis and geodynamic implications of Late Cenozoic basalts in north Queensland, Australia: trace-element and Sr–Nd–Pb isotope evidence. J Petrol 42:685–719

    Google Scholar 

  • Zhang MJ, Li CS, Fu PE, Hu PQ, Ripley EM (2011) The Permian Huangshanxi Cu-Ni deposit in western China: intrusive-extrusive association, ore genesis, and exploration implications. Mineral Deposita 46:153–170

    Google Scholar 

  • Zhang DY, Zhou TF, Yuan F, Fiorentini ML, Said N, Lu YJ, Pirajno F (2013) Geochemical and isotopic constraints on the genesis of the Jueluotage native copper mineralized basalt, Eastern Tianshan, Northwest China. J Asian Earth Sci 73:317–333

    Google Scholar 

  • Zhang DY, Zhou TF, Yuan F, Fan Y, Deng YF, Xu C, Zhang RF (2014) Genesis of Permian granites along the Kangguer Shear Zone, Jueluotage area, Northwest China: geological and geochemical evidence. Lithos 198-199:141–152

    Google Scholar 

  • Zhao Y, Xue CJ, Zhao XB, Yang YQ, Ke JJ (2015) Magmatic Cu-Ni sulfide mineralization of the Huangshannan mafic-untramafic intrusion, Eastern Tianshan, China. J Asian Earth Sci 105:155–172

    Google Scholar 

  • Zhao Y, Xue CJ, Zhao XB, Yang YQ, Ke JJ, Zu B, Zhang GZ (2016) Origin of an anomalously Ni-rich parental magma and genesis of the Huangshannan Ni-Cu sulfide deposit, Central Asian Orogenic Belt, Northwestern China. Ore Geol Rev 77:57–71

    Google Scholar 

  • Zhao BB, Deng YF, Zhou TF, Yuan F, Zhang DY, Deng G, Li WD, Li Y (2018) Petrogenesis of the Baixintan Ni-Cu sulfide-bearing mafic-ultramafic intrusion, east Tianshan: evidence from geochronology, petrogeochemistry and Sr-Nd isotope. Acta Petrol Sin 34(9):2733–2753 (in Chinese with English abstract)

    Google Scholar 

  • Zhou MF, Lesher CM, Yang ZX, Li JW, Sun M (2004) Geochemistry and petrogenesis of 270 Ma Ni-Cu-(PGE) sulfide-bearing mafic intrusions in the Huangshan District, eastern Xinjiang, Northwest China: implications for the tectonic evolution of the Central Asian orogenic belt. Chem Geol 209:233–257

    Google Scholar 

  • Zhou TF, Yuan F, Zhang DY, Fan Y, Liu S, Peng MX, Zhang JD (2010) Geochronology, tectonic setting and mineralization of granitoids in Jueluotage area, eastern Tianshan, Xinjiang. Acta Petrol Sin 26:478–502 (in Chinese with English abstract)

    Google Scholar 

  • Zindler A, Hart S (1986) Chemical geodynamics. Annu Rev Earth Planet Sci 14:493–571

    Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant Nos. U1803113, 41672069, 41630316, 41303031, and 41820104007), the China Academy of Science “Light of West China” Program, and the Fundamental Research Funds for the Central Universities (JZ2018HGTB0246). We are very grateful to Weidong Li, Jiangtao Tian, and Dahai Li for the help during our field work. We also thank Kaiyuan Wang, Jing Hu, and Fang Xiao for their kind help on the analyses of isotopes and trace elements. Critical comments from Professor Chusi Li, another anonymous reviewer, and editorial inputs from guest editor Professor Marco Fiorentini are greatly appreciated.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yu-Feng Deng.

Additional information

Editorial handling: M. Fiorentini

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

ESM 1

(DOC 163 kb)

ESM 2

(DOC 99 kb)

ESM 3

(DOC 39 kb)

ESM 4

(DOC 111 kb)

ESM 5

(DOC 103 kb)

ESM 6

(DOC 195 kb)

ESM 7

(DOC 301 kb)

ESM 8

(DOC 101 kb)

ESM 9

(DOC 106 kb)

ESM 10

(DOC 108 kb)

ESM 11

(DOC 29 kb)

ESM 12

(DOC 27 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Deng, YF., Yuan, F., Hollings, P. et al. Magma generation and sulfide saturation of Permian mafic-ultramafic intrusions from the western part of the Northern Tianshan in NW China: implications for Ni-Cu mineralization. Miner Deposita 55, 515–534 (2020). https://doi.org/10.1007/s00126-019-00890-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00126-019-00890-8

Keywords

Navigation