Abstract
Mixed bed resin was prepared using T-46 (H+) and A-33 (OH−) through mixing their ratio 1: 1.6 and characterized by Fourier transform infrared scanning electron microscopy and energy dispersive X-Ray spectroscopy. The mixed bed resin was evaluated for the removal of cesium and strontium from contaminated water. The aim of our study was to find the suitable condition for removal of Cs and Sr ions from water under different conditions viz. initial concentration of Cs and Sr ions, contact time, dose of resin and pH. Cs and Sr ions, adsorption data are fitted well with Freundlich and Langmuir isotherm models. The adsorption capacity was 7.53 and 9.58 mg/g for Cs and Sr ions, respectively as obtained at initial concentration 10 mg/L by Langmuir isotherm. Adsorption kinetics was followed by pseudo-second order reaction. The rate constants of pseudo-second order reaction were calculated and quite high correlation coefficients R2 98–99.5 were obtained. The resin also used for removal of Cs and Sr ions from tap water (TDS—200 mg/L) and saline water (TDS—2000 mg/L), and showed 90% (Cs) and 95% (Sr) removal at 10 mg/L of each ion concentration.
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References
Patterson, J.W., Industrial wastewater treatment technology, 2nd ed., London: Butterworth-Heinemann, 1985.
Roberts, J., Metal Toxicity in Children in: Training Manual on Pediatric Environmental Health. Putting it into Practice, (Children’s environmental health network), 1999.
Kemp, R.V., Bennett, D.G., and White, M.J., Recent trends and developments in dialogue on radioactive waste management: Experience from the UK, Environ. Int., 2006, vol. 32, pp. 1021–1032.
Andrade, C., Martinez, I., Castellote, M., and Zuloaga, P., Some principles of service life calculation of reinforcements and in situ corrosion monitoring by sensors in the radioactive waste containers of El Cabril disposal (Spain), J. Nucl. Mater., 2006, vol. 358, pp. 82–95.
Plecas, I. and Dimovic, S., Curing time effect on compressive strength and incremental leaching rates of 137Cs and 60Co in cement immobilized sludge, Progress Nucl. Energy, 2006, vol. 8, pp. 629–633.
Melville, G., Liu, S.F., and Allen, B.J., A theoretical model for the production of Ac-225 for cancer therapy by photon-induced transmutation of Ra-226, Appl. Rad. Isot., 2006, vol. 64, pp. 979–988.
Abdel Raouf, M.W., Typha domingensis leaf powder for decontamination of aluminium, iron, zinc and lead: Bisorption kinetics and equilibrium modeling, J. Chem. Technol. Biotechnol., 2003, vol. 79, pp. 22–29.
Wang, X., Xu, D., Chen, L., Tan, X., Zhou, X., Ren, A., and Chen, C., Sorption and complexation of Eu(III) on alumina: effects of pH, ionic strength, humic acid and chelating resin on kinetic dissociation study, Appl. Rad. Isot., 2006, vol. 64, pp. 414–421.
Nilchi, M., Ghanadi, N., and Khanchi A., Characteristics of novel types of substituted cerium phosphates, J. Rad. Nucl. Chem., 2000, vol. 245, pp. 589–594.
Ibrahim, G.M., EI-Gammal, B., and EI-Naggar, I.M., Selectivity modification of some alkali metal ions on silicon antimonite as cation exchanger, Curr. Topics Colloid. Interface. Sci., 2003, vol. 6, pp. 159–165.
Borai, E.H., Harjula, R., Malien, L., and Paajanen, A., Efficient removal of cesium from low-level radioactive liquid waste using natural and impregnated zeolite minerals, J. Hazard. Mater., 2009, vol. 172, pp. 416–420.
Klika, Z., Kraus, L., and Vopalka, D., Cesium Uptake from aqueous solutions by bentonite: a comparison of multi-component sorption with ion-exchange models, Langmuir, 2007, vol. 23, pp. 1227–1233.
EI-Naggar, I.M., Ibrahim, G.M., EI-Kady, E.A., and Hegazy, E.A., Sorption mechanism of Cs+, Co2+ and Eu3+ ions onto EGIB sorbent, Desalination, 2009, vol. 237, pp. 147–154.
Misra, R.K., Jain, S.K., and Khatri, P.K., Iminodiacetic acid functionalized cation exchange resin for adsorptive removal of Cr(VI), Cd(II), Ni(II) and Pb(II) from their aqueous solutions, J. Hazard. Mater., 2011, vol. 185, pp. 1508–1512.
Kumar, R., Jain, S.K., and Misra, R.K., Aqueous heavy metals removal by absorption on β-diketone-functionalized Styrene-DVB co polymeric resin, Int. J. Environ. Sci. Technol., 2011, vol. 9, pp. 79- 84.
Kumar, R. and Jain, S.K., Synthesis, characterization and application of a new chelating resin containing 2-(4-methyl benzylidene) hydrazone, Adsor. Sci. Technol., 2011, vol. 29, pp. 917–926.
Kumar R., and Jain S.K., Adsorption and kinetic studies of cesium ions from aqueous solution by functionalized silica, Desal. and Water Treat., 2013, vol. 51, pp. 2014–2020.
Abraham, T.N., Kumar, R., Misra, R.K., and Jain, S.K., Poly (vinyl alcohol) based MWNT hydrogel for lead ion removal from contaminated water, J. Appl. Polym. Sci., 2012, vol. 125, pp. E670–E674.
Langmuir, I., The constitution and fundamental properties of solids and liquids, J. Amer. Chem. Soc., 1916, vol. 38, pp. 2221–2295.
Freundlich, H.M.F., Über die adsorption in läsungen, Zeitschrift für Physikalische Chemie, 1906, vol. 57, pp. 385–470.
Gupta, S. and Babu, B.V., Utilization of waste product (tamarind seeds) for the removal of Cr (VI) from aqueous solution: Equlibrium, kinetics and regeneration studies, J. Environ. Manage, 2009, vol. 90, pp. 3013–3022.
Ho, Y.S. and Mckay, G., The kinetic of sorption of divalent metal ions onto sphagnum moss peat, Water Res., 2000, vol. 34, pp. 735–742.
Ho, Y.S. and McKay, G., Pseudo-second order model for sorption processes, Process. Biochem., 1999, vol. 34, pp. 451–465.
Allen, J.A. and Brown, D.A., Isotherm analyses for single component and multi component metal sorption onto lignite, J. Chem. Technol. Biotechnol., 1995, vol. 62, pp. 17–24.
Acknowledgments
Authors are thankful to Dr S.R. Vadera, OS and Director, Defence Laboratory, Jodhpur for guidance and encouragements. Authors would like to thank Sh. Deepesh Patidar, Sc-F, for his technical suggestions for preparation of manuscript. We wish to thank Sh. Ravindra Kumar, Sc-G, for his suggestions and help throughout the writing of manuscript. The authors thank Dr. Anuj Shukla, Sc-E for SEM and EDS spectra analysis.
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Kumar, R., Malodia, P., Kachwaha, M. et al. Adsorptive and Kinetic Studies of Resin for Removal of Cs+ and Sr2+ from Aqueous Solution. J. Water Chem. Technol. 41, 292–298 (2019). https://doi.org/10.3103/S1063455X19050047
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DOI: https://doi.org/10.3103/S1063455X19050047