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Hydrophilic Finishing of PET Fabrics by Applying Chitosan and the Periodate Oxidized β-cyclodextrin for Wash Resistance Improvement

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Abstract

β-cyclodextrin (β-CD) was oxidized by sodium periodate to yield a mixture of dialdehyde oligosaccharides. The periodate-oxidized β-CD (O-β-CD) together with chitosan (CTS) was firstly used to finish poly(ethylene terephthalate) (PET) fabrics by immersion-padding method, in which O-β-CD acted as a hydrophilic finishing agent plus a cross-linker. The processes including the periodate oxidization of β-CD and the CTS/O-β-CD hydrophilic finishing of PET fabrics were eco-friendly. The results from the hydroxylamine hydrochloride titration showed that the aldehyde content in O-β-CD was 3.0 mmol/g. With increasing the CTS/O-β-CD mass ratio, the finished fabric had better hydrophilic properties. When the CTS/O-β-CD mass ratio was 1:1, the moisture regain and water drops wetting time of the finished fabric reached 1.85 % and 5.06 s, respectively. They became 1.50 % and 5.70 s, respectively after 25 times of laundering cycle. The occurrence of cross-linking between O-β-CD and CTS was confirmed by the gel test and FT-IR characterization. The cross-linking network deposited on the fiber surface brought on excellent wash resistance of the CTS/O-β-CD finished PET fabrics.

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Acknowledgements

The authors are grateful to the National Natural Science Foundation of China (Grant Nos. 31570578 and 31270632), the Fundamental Research Funds for the Central Universities (Grant No. JUSRP51622A), and State Key Laboratory of Pulp and Paper Engineering (No.201772 and 201809).

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Authors and Affiliations

  1. College of Textiles & Clothing, Key Laboratory of Eco-Textile, Ministry of Education, Jiangnan University, Wuxi, 214122, Jiangsu, China

    Chaoqian Lou, Yuanyuan Yin, Xiuzhi Tian, Haibo Deng, Yingxia Wang & Xue Jiang

  2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640, Guangdong, China

    Xiuzhi Tian & Xue Jiang

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  1. Chaoqian Lou
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  2. Yuanyuan Yin
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  3. Xiuzhi Tian
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  4. Haibo Deng
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  5. Yingxia Wang
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  6. Xue Jiang
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Correspondence to Xiuzhi Tian or Xue Jiang.

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Lou, C., Yin, Y., Tian, X. et al. Hydrophilic Finishing of PET Fabrics by Applying Chitosan and the Periodate Oxidized β-cyclodextrin for Wash Resistance Improvement. Fibers Polym 21, 73–81 (2020). https://doi.org/10.1007/s12221-020-9269-1

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