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Synthesis of Co-doped micro-mesoporous SAPO-11 zeolite for glycerol hydrogenolysis

  • Catalysis, Reaction Engineering
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Abstract

Co-doped micro-mesoporous SAPO-11 zeolite (Co-MSAPO-11) was synthesized and used for hydrogenolysis of glycerol. After simultaneous introduction of Co and mesopores, the pore structure and acidic properties of microporous SAPO-11 zeolite are reintegrated. The larger mesopores of Co-MSAPO-11 facilitate the diffusion of molecules and provide more space for the highly dispersed Co species. The appropriate acidity of Co-MSAPO-11 with more Lewis acid sites appears to be more helpful for the activation of reactants to intermediates, potentially increasing the probability of high selectivity to 1,2-propanediol. Therefore, Co-MSAPO-11 shows unique catalytic performance with a glycerol conversion of 94.0% and selectivity to 1,2-PDO of 90.5% under mild conditions. The possible representative model of Co-MSAPO-11 is proposed for the first time.

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Acknowledgement

This work was supported by the National Natural Science Foundation of China under Grant Nos. 21878048 and 21676055.

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Authors and Affiliations

  1. Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Southeast University, Jiangning District, Nanjing, 211189, China

    Xue Li & Dongfang Wu

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  1. Xue Li
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  2. Dongfang Wu
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Correspondence to Dongfang Wu.

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Li, X., Wu, D. Synthesis of Co-doped micro-mesoporous SAPO-11 zeolite for glycerol hydrogenolysis. Korean J. Chem. Eng. 37, 216–223 (2020). https://doi.org/10.1007/s11814-019-0445-1

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  • DOI: https://doi.org/10.1007/s11814-019-0445-1

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