Abstract
Self-assembly of CuX2 with C3-symmetric tridentate ligand, 1,3,5-tris(nicotinoyloxy-methyl)benzene (L), affords thermodynamically stable C2-symmetric metallacyclodimers, [Cu2X2L2(H2O)2]X2(H2O)2 (X− = NO3−, BF4−, and ClO4−) in high yields. These cyclodimeric species show the significant anion effects on the catechol oxidation catalysis in chloroform in the order [Cu2(NO3)2L2(H2O)2](NO3)2(H2O)2 > [Cu2(BF4)2L2(H2O)2](BF4)2(H2O)2 > [Cu2(ClO4)2L2(H2O)2](ClO4)2(H2O)2.
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Acknowledgements
This work was supported by National Research Foundation of Korea (NRF) Grants funded by the Korean Government [MEST] (2019K1A3A1A25000268) (OSJ) and (2017R1D1A3B03035719) (YAL).
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11243_2019_358_MOESM1_ESM.doc
IR spectra, 1H NMR spectra and TGA curves of [Cu2(NO3)2L2(H2O)2](NO3)2(H2O)2, [Cu2(BF4)2L2(H2O)2](BF4)2(H2O)2, [Cu2(ClO4)2L2(H2O)2](ClO4)2(H2O)2. Crystallographic data for the structure reported here have been deposited with the Cambridge Crystallographic Data Centre (Deposition No. CCDC 1952951, 1952929 and 1952935 for [Cu2(NO3)2L2(H2O)2](NO3)2(H2O)2, [Cu2(BF4)2L2(H2O)2](BF4)2(H2O)2, [Cu2(ClO4)2L2(H2O)2](ClO4)2(H2O)2 respectively. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif (DOC 2126 kb)
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Kim, D., Lee, S., Lee, Y.A. et al. Insight into anion effects on catechol oxidation catalysis: cyclodimeric Cu(II) complexes containing 1,3,5-tris(nicotinoyloxy-methyl)benzene. Transit Met Chem 45, 65–70 (2020). https://doi.org/10.1007/s11243-019-00358-8
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DOI: https://doi.org/10.1007/s11243-019-00358-8