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Hydrogen Release from Decalin by Catalytic Dehydrogenation over Supported Platinum Catalysts

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Abstract

Pt catalysts supported on the commonly used supports Al2O3, SiO2 and on mesostructured silicates SBA-15 and MCM-48 were examined in the dehydrogenation of decalin, that is the promising liquid organic hydrogen carrier (LOHC). Synthesized catalysts were studied by low-temperature nitrogen adsorption, temperature programmed reduction, high-resolution transmission electron microscopy. The catalysts are characterized by various dispersion of platinum. The activity of catalysts in decalin dehydrogenation decreases in the following order Pt/MCM-48 > Pt/SBA-15 > Pt/SiO2 > Pt/Al2O3. Pt/MCM-48 catalyst allows to release hydrogen in the decalin amount of 5.7 wt% and can be considered the promising LOHC hydrogen storage technology.

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Acknowledgements

The HR TEM study was performed on the equipment of CKP “VTAN” in ATRC Department of NSU. The research was supported by the Russian Federation Government, Resolution No. 220, Grant 14.Z50.31.0038.

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  1. Samara State Technical University, Samara, Russian Federation

    E. A. Martynenko, Al. A. Pimerzin, A. A. Savinov, S. P. Verevkin & A. A. Pimerzin

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  1. E. A. Martynenko
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  2. Al. A. Pimerzin
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  3. A. A. Savinov
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  4. S. P. Verevkin
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Correspondence to Al. A. Pimerzin.

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Martynenko, E.A., Pimerzin, A.A., Savinov, A.A. et al. Hydrogen Release from Decalin by Catalytic Dehydrogenation over Supported Platinum Catalysts. Top Catal 63, 178–186 (2020). https://doi.org/10.1007/s11244-020-01228-9

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  • DOI: https://doi.org/10.1007/s11244-020-01228-9

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