Abstract
Aqueous solutions or gels of polyampholytes attract interest for more than half a century due to their several attractive properties. We present here thermally healable hydrophobically modified physical polyampholyte (PA) hydrogels based on oppositely charged 2-acrylamido-2-methylpropane-1-sulfonic acid sodium salt (AMPS) and (3-acrylamidopropyl) trimethylammonium chloride (APTAC) monomers. PA hydrogels were prepared via micellar polymerization technique in the presence of the hydrophobic monomer n-octadecyl acrylate (C18A) in aqueous sodium dodecyl sulfate (SDS) solutions. Charge-balanced PA hydrogels containing 60–90% water exhibit a high tensile strength and stretchability of up to 202 kPa and 1239%, respectively. Above 7 mol% C18A, swollen hydrogels containing around 90% water exhibit much better mechanical properties as compared with the corresponding as-prepared ones because of the stronger hydrophobic interactions in the absence of SDS micelles. Cut-and-heal tests conducted at 50 °C reveal a complete healing efficiency with respect to Young’s modulus for all as-prepared PA hydrogels within 1–4 h.
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Acknowledgments
E.S. thanks Science Fellowships and Grant Programmes (BIDEB) of the Scientific and Technological Research Council of Turkey (TUBITAK) for a Ph.D. scholarship. O. O. thanks Turkish Academy of Sciences (TUBA) for the partial support.
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The work was supported by Ministry of Education and Science of the Republic of Kazakhstan (IRN AP05131003, 2018–2020).
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• Physical polyampholyte hydrogels are prepared via micellar polymerization technique.
• Incorporation of hydrophobes within the gel network provides their water stability.
• The hydrogels containing 60–90% water exhibit a high stretchability of up to 1239%.
• They exhibit a complete healing efficiency at 50 °C within 1–4 h.
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Toleutay, G., Su, E., Kudaibergenov, S. et al. Highly stretchable and thermally healable polyampholyte hydrogels via hydrophobic modification. Colloid Polym Sci 298, 273–284 (2020). https://doi.org/10.1007/s00396-020-04605-8
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DOI: https://doi.org/10.1007/s00396-020-04605-8