Abstract
The composition of gels and xerogels, as well as their transformation during heating and dehydration, determine the thermochemistry of solution combustion synthesis reactions. An improved descriptive thermodynamic model of combustion processes was formulated on the basis of the investigated formation of complex compounds of metal ions with organic fuel (glycine, citric acid, urea, and PVA) in nitrate solutions. The intensity of SCS reactions was found to depend on the strength of Ni2+–ligand complexes. The effect of heat loss during combustion on the ΔTmax value was analyzed for the model system Ni(NO3)2·nH2O–Fuel–H2O. It was found the heat loss occurs due to the presence of various amounts of structurally-bound water in gels and xerogels before the combustion.
Highlights
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Nitrate/fuel ratios affect the formation of a hypergolic mixture of gases.
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The intensity of SCS reactions depends on the strength of Ni2+–ligand complexes.
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Water in the xerogel has a great impact on the maximal thermal effect.
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References
Varma A, Mukasyan AS, Rogachev AS, Manukyan KV (2016) Solution combustion synthesis of nanoscale materials. Chem Rev 116:14493–14586
Rogachev AS, Mukasyan AS (2014) Combustion for material synthesis, 1st ed. CRC Press, New York
Kopp Alves A, Bergmann CP, Berutti FA (2013) Novel synthesis and characterization of nanostructured materials. Springer Berlin Heidelberg, Heidelberg
Patil KC, Hegde MS, Rattan T, Aruna ST (2008) Chemistry of nanocrystalline oxide materials. World Scientific Publishing Co, Singapore
Deganello F, Tyagi AK (2018) Solution combustion synthesis, energy and environment: Best parameters for better materials. Prog Cryst Growth Charact Mater 64:23–61
Khort AA, Podbolotov KB (2016) Preparation of BaTiO3 nanopowders by the solution combustion method. Ceram Int 42:15343–15348
Khort AA, Podbolotov KB (2014) Effect of reductant type on phase composition and ferroelectric behavior of combustion-synthesized BaTiO3 and Bi4Ti3O12. Int J Self-Propagating High-Temp Synth 23:106–111
Vilejshikova EV, Khort AA, Podbolotov KB et al. (2017) Luminescence of Eu:Y3Al5O12, Eu:Lu3Al5O12, and Eu:GdAlO3 nanocrystals synthesized by solution combustion. J Appl Spectrosc 84:866–874
Wrzesinska A, Khort A, Bobowska I et al. (2019) Influence of the La3+, Eu3+, and Er3+ doping on structural, optical, and electrical properties of BiFeO3 nanoparticles synthesized by microwave-assisted solution combustion method. J Nanomater 2019:1–11
Khaliullin SM, Zhuravlev VD, Russkikh OV et al. (2015) Solution-combustion synthesis and eletroconductivity of CaZrO3. Int J Self-Propagating High-Temp Synth 24:83–88
Zhuravlev VD, Bamburov VG, Beketov AR et al. (2013) Solution combustion synthesis of α-Al2O3 using urea. Ceram Int 39:1379–1384
Khaliullin SM, Zhuravlev VD, Bamburov VG (2016) Solution-combustion synthesis of oxide nanoparticles from nitrate solutions containing glycine and urea: Thermodynamic aspects. Int J Self-Propagating High-Temp Synth 25:139–148
Khaliullin SM, Zhuravlev VD, Bamburov VG (2017) Solution-combustion synthesis of MZrO3 zirconates (M = Ca, Sr, Ba) in open reactor: thermodynamic analysis and experiment. Int J Self-Propagating High-Temp Synth 26:93–101
Khaliullin SM, Nefedova KV, Zhuravlev VD (2019) Nanocomposites mAl2O3–nYSZ by impregnation combustion synthesis with urea as a fuel. Int J Self-Propagating High-Temp Synth 28:1–9
Mukasyan AS, Dinka P (2007) Novel approaches to solution-combustion synthesis of nanomaterials. Int J Self-Propagating High-Temp Synth 16:23–35
Mukasyan AS, Costello C, Sherlock KP et al. (2001) Perovskite membranes by aqueous combustion synthesis: synthesis and properties. Sep Purif Technol 25:117–126
Chirnside R (1959) The chemical behavior of zirconium. D. van Nostrand Company Inc., London
Nikolic R, Zec S, Maksimovic V, Mentus S (2006) Physico-chemical characterization of thermal decomposition course in zinc nitrate-copper nitrate hexahydrates. J Therm Anal Calorim 86:423–428
Kumar A, Wolf EE, Mukasyan AS (2011) Solution combustion synthesis of metal nanopowders: Nickel-Reaction pathways. AIChE J 57:2207–2214
Małecka B, Łącz A, Drożdż E, Małecki A (2015) Thermal decomposition of d-metal nitrates supported on alumina. J Therm Anal Calorim 119:1053–1061
Pacewska B, Keshr M (2002) Thermal transformations of aluminium nitrate hydrate. Thermochim Acta 385:73–80
Melnikov P, Nascimento VA, Arkhangelsky IV et al. (2014) Thermal decomposition mechanism of iron(III) nitrate and characterization of intermediate products by the technique of computerized modeling. J Therm Anal Calorim 115:145–151
Martell AE, Hancock RD (1996) Metal complexes in aqueous solutions. Springer US, Boston
Silbey RJ, Alberty RA, Bawendi MG (2004) Physical chemistry, 4th ed. Wiley, Hoboken, NJ
Ashmead SD (2001) The chemistry of ferrous bis-glycinate chelate. Arch Latinoam Nutr 51:7–12
Li J, Wang Z, Yang X et al. (2007) Evaluate the pyrolysis pathway of glycine and glycylglycine by TG-FTIR. J Anal Appl Pyrolysis 80:247–253
Khort A, Podbolotov K, Serrano-García R, Gun’Ko Y (2018) One-step solution combustion synthesis of cobalt nanopowder in air atmosphere: the fuel effect. Inorg Chem 57:1464–1473
Khort A, Podbolotov K, Serrano-García R, Gun’ko YK (2017) One-step solution combustion synthesis of pure Ni nanopowders with enhanced coercivity: the fuel effect. J Solid State Chem 253:270–276
Apelblat A (2014) Citric acid. Springer Cham Heidelberg, London
Matzapetakis M, Karligiano N, Bino A et al. (2000) Manganese citrate chemistry: Syntheses, spectroscopic studies, and structural characterizations of novel mononuclear, water-soluble manganese citrate complexes. Inorg Chem 39:4044–4051
Hedwig GR, Liddle JR, Reeves RD (1980) Complex formation of nickel(II) ions with citric acid in aqueous solution: a potentiometric and spectroscopic study. Aust J Chem 33:1685
Bickley RI, Edwards HGM, Gustar R, Rose SJ (1991) A vibrational spectroscopic study of nickel(II) citrate Ni3(C6H5O7)2 and its aqueous solutions. J Mol Struct 246:217–228
Megahed AS, Ibrahim OB, Adam AMA, Al-Majthoub MM (2014) Structure and properties of some metal-urea complexes obtained at low temperature: Cr(III), Mn(II), Fe(III), Co(II) and Ni(II) ions. Res J Pharm Biol Chem Sci 5:960–969
Schaber PM, Colson J, Higgins S et al. (2004) Thermal decomposition (pyrolysis) of urea in an open reaction vessel. Thermochim Acta 424:131–142
Rafat F (2014) Effect of different heating rate on the thermal decomposition of urea in an open reaction vessel. Arch Appl Sci Res 6:75–78
Ibrahim OB (2012) Complexes of urea with Mn (II), Fe (III), Co (II), and Cu (II) metal ions. Adv Appl Sci Res 3:3522–3539
Ibrahim OB, Refat MS, Salman M (2012) New complexes of urea with Hg(II) and Ni(II) metal ions. Eur Chem Bull 1:188–195
Swift G (1994) Water-soluble polymers. Polym Degrad Stab 45:215–231
Carrado KA, Thiyagarajan P, Elder DL (1996) Polyvinyl alcohol-clay complexes formed by direct synthesis. Clays Clay Min 44:506–514
Cordeiro CF (2005) Vinyl acetate polymers. Van Nostrand’s Encyclopedia of Chemistry. https://doi.org/10.1002/0471740039.vec2622
Tamura S, Oono R (2015) The cluster size and change of water molecules in poly(vinyl alcohol) film by heating. J Fiber Sci Technol 71:284–290
Kimura K, Inaki Y, Takemoto K (1974) Vinyl polymerization by metal complexes, 12. Initiation by poly(vinyl alcohol)-copper(II) chelates. Die Makromol Chem 175:95–103
Abo El-Khair BM, Mokhtar SM, Dakroury AZ, Osman MBS (1994) Measurement of thermophysical properties of polyvinyl alcohol complexed with some metal ions. J Macromol Sci Part B 33:387–395
Ostroushko AA, Russkikh OV (2017) Oxide material synthesis by combustion of organic-inorganic compositions. Nanosyst Phys, Chem Math 8:476–502
Barenblatt G (1985) The mathematical theory of combustion and explosions. Springer, US
Elmasry MAA, Gaber A, Khater EMH (1998) Thermal decomposition of Ni(II) and Fe(III) nitrates and their mixture. J Therm Anal Calorim 52:489–495
Mikuli E, Migdal-Mikuli A, Chyy R et al. (2001) Melting and thermal decomposition of [Ni(H2O)6](NO3)2. Thermochim Acta 370:65–71
Gamsjäger H, Mompean FJ et al. (2005) Chemical thermodynamics of nickel. Issy-les-Moulineaux, France
Speight JG (2005) Lange’s handbook of chemistry, 16th ed. McGraw-Hill Education, New York
Da Silva G, Kim CH, Bozzelli JW (2006) Thermodynamic properties (enthalpy, bond energy, entropy, and heat capacity) and internal rotor potentials of vinyl alcohol, methyl vinyl ether, and their corresponding radicals. J Phys Chem A 110:7925–7934
Acknowledgements
The work was carried out in accordance with the state assignment for the Institute of Solid State Chemistry of the Ural Branch of Russian Academy of Sciences (theme No АААА-А19-119031890026-6) and the Ministry of Science and Higher Education of the Russian Federation in the framework of Increase Competitiveness Program of NUST «MISiS» (№ К2-2019-007), implemented by a governmental decree dated 16th of March 2013, N 211.
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Khaliullin, S.M., Zhuravlev, V.D., Bamburov, V.G. et al. Effect of the residual water content in gels on solution combustion synthesis temperature. J Sol-Gel Sci Technol 93, 251–261 (2020). https://doi.org/10.1007/s10971-019-05189-8
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DOI: https://doi.org/10.1007/s10971-019-05189-8