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Influence of carbon-partitioning treatment on the microstructure, mechanical properties and wear resistance of in situ VCp-reinforced Fe-matrix composite

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Abstract

The wear resistance of iron (Fe)-matrix materials could be improved through the in situ formation of vanadium carbide particles (VCp) with high hardness. However, brittleness and low impact toughness limit their application in several industries due to addition of higher carbon content. Carbon-partitioning treatment plays an important role in tuning the microstructure and mechanical properties of in situ VCp-reinforced Fe-matrix composite. In this study, the influences of carbon-partitioning temperatures and times on the microstructure, mechanical properties, and wear resistance of in situ VCp-reinforced Fe-matrix composite were investigated. The experimental results indicated that a certain amount of retained austenite could be stabilized at room temperature through the carbon-partitioning treatment. Microhardness of in situ VCp-reinforced Fematrix composite under carbon-partitioning treatment could be decreased, but impact toughness was improved accordingly when wear resistance was enhanced. In addition, the enhancement of wear resistance could be attributed to transformation-induced plasticity (TRIP) effect, and phase transformation was caused from γ-Fe (face-centered cubic structure, fcc) to α-Fe (body-centered cubic structure, bcc) under a certain load.

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References

  1. R.R. Moskalyk and M.A. Alfantazi, Processing of vanadium: a review, Miner. Eng., 16(2003), No. 9, p. 793.

    Article  CAS  Google Scholar 

  2. M. Radulovic, M. Fiset, K. Peev, and M. Tomovic, The influence of vanadium on fracture toughness and abrasion resistance in high chromium white cast irons, J. Mater. Sci., 29(1994), No. 19, p. 5085.

    Article  CAS  Google Scholar 

  3. L.S. Zhong, M. Hojamberdiev, F.X. Ye, W. Hong, and Y.H. Xu, Fabrication and microstructure of in situ vana-dium carbide ceramic particulates-reinforced iron matrix composites, Ceram. Int., 39(2013), No. 1, p. 731.

    Article  CAS  Google Scholar 

  4. L. He, Y. Liu, B.H. Li, H. Cao, and J. Li, Reaction synthesis of in situ vanadium carbide particulates-reinforced iron matrix composites by spark plasma sintering, J. Mater. Sci., 45(2010), No. 9, p. 2538.

    Article  CAS  Google Scholar 

  5. L.S. Zhong, F.X. Ye, Y.H. Xu, and J.S. Li, Microstructure and abrasive wear characteristics of in situ vanadium carbide particulate-reinforced iron matrix composites, Mater. Des., 54(2014), p. 564.

    Article  CAS  Google Scholar 

  6. Y.S. Wang, Y.C. Ding, J. Wang, F.J. Cheng, and J.G. Shi, In situ production of vanadium carbide particulates rein-forced iron matrix surface composite by cast-sintering, Mater. Des., 28(2007), No. 7, p. 2202.

    Article  CAS  Google Scholar 

  7. M. Kawalec and E. Olejnik, Abrasive wear resistance of cast iron with precipitates of spheroidal VC carbides, Arch. Foundry Eng., 12(2012), No. 2, p. 221.

    Article  CAS  Google Scholar 

  8. W.M. Zhao, ZX. Liu, Z.L. Ju, B. Liao, and X.G. Chen, Effects of vanadium and rare-earth on carbides and properties of high chromium cast iron, Mater. Sci. Forum, 575–578(2008), p. 1414.

    Article  Google Scholar 

  9. F.X. Ye, M. Hojamberdiev, Y.H. Xu, L.S. Zhong, H.H. Yan, and Z. Chen, (Fe,Cr)7C3-Fe surface gradient composite: Microstructure, microhardness, and wear resistance, Mater. Chem. Phys., 147(2014), No. 3, p. 823.

    Article  CAS  Google Scholar 

  10. S.Z. Wei, J.H. Zhu, and L.J. Xu, Research on wear resistance of high speed steel with high vanadium content, Mater. Sci. Eng. A, 404(2005), No. 1–2, p. 138.

    Article  Google Scholar 

  11. S.Z. Wei, J.H. Zhu, and L.J. Xu, Effects of vanadium and carbon on microstructures and abrasive wear resistance of high speed steel, Tribol. Int., 39(2006), No. 7, p. 641.

    Article  CAS  Google Scholar 

  12. S.Z. Wei, J.H. Zhu, L.J. Xu, and R. Long, Effects of carbon on microstructures and properties of high vanadium high-speed steel, Mater. Des., 27(2006), No. 1, p. 58.

    Article  CAS  Google Scholar 

  13. JX. Liu, ZW. Shi, P.J. Ying, S.Z. Guo, W.L. Ji, and R. Long, Effect of carbon on frictional wear behaviours of high vanadium high speed steel under dry sliding condition, Mater. Sci. Forum, 654–656(2010), p. 370.

    Google Scholar 

  14. L.J. Xu, J.D. Xing, S.Z. Wei, Y.Z. Zhang, and R. Long, Study on relative wear resistance and wear stability of highspeed steel with high vanadium content, Wear, 262(2007), No. 3–4, p. 253.

    Article  CAS  Google Scholar 

  15. M. Kriiger, High temperature compression strength and oxidation of a V-9Si-13B alloy, Scripta Mater, 121(2016), p. 75.

    Article  Google Scholar 

  16. P.H. Chen, Z.L. Liu, R.Q. Li, and X.Q. Li, The effect of manganese additions on the high temperature oxidation behaviour of the high-vanadium cast iron, J. Alloys Compd., 767(2018), p. 181.

    Article  CAS  Google Scholar 

  17. P.H. Chen, R.Q. Li, R.P. Jiang, S.S. Zeng, Y. Zhang, and X.Q. Li, High-temperature oxidation resistance of VCps-re-inforced Fe-matrix composites using an in-situ reaction, AIPAdv., 9(2019), No. 1, p. 015319.

    Google Scholar 

  18. V.F. Zackay, M.D. Bhandarkar, and E.R. Parker, The role of deformation-induced phase transformations in the plasticity of some iron-base alloys, [In] J.J. Burke and V. Weiss, eds., Advances in Deformation Processing, Boston, MA, 1978, p. 351.

    Chapter  Google Scholar 

  19. L. Skalova, R. Divisova, and D. Jandova, Thermo-mechanical processing of low-alloy TRIP-steel, J. Mater. Process. Technol., 175(2006), No. 1–3, p. 387.

    Article  CAS  Google Scholar 

  20. J. Speer, D.K. Matlock, B.C. de Cooman, and J.G. Schroth, Carbon partitioning into austenite after martensite trans-formation, Acta Mater, 51(2003), No. 9, p. 2611.

    Article  CAS  Google Scholar 

  21. J.G. Speer, E. De Moor, K.O. Findley, D.K. Matlock, B.C. de Cooman, and D.V. Edmonds, Analysis of microstruc-ture evolution in quenching and partitioning automotive sheet steel, Metall. Mater. Trans. A, 42(2011), No. 12, p. 3591.

    Article  CAS  Google Scholar 

  22. V.F. Zackay and T.H. Hazlett, Some plastic properties of nickel alloys, Acta Metall, 1(1953), No. 6, p. 624.

    Article  CAS  Google Scholar 

  23. P.J. Gibbs, E. de Moor, M.J. Merwin, B. Clausen, J.G. Speer, and D.K. Matlock, Austenite stability effects on tensile behavior of manganese-enriched-austenite transformation-induced plasticity steel, Metall. Mater. Trans. A, 42(2011), No. 12, p. 3691.

    CAS  Google Scholar 

  24. M. Mansourinejad and M. Ketabchi, Influence of strain state on the kinetics of martensitic transformation induced plasticity (TR.P. in AISI 304 stainless steel, Steel Res. Int., 89(2018), No. 3, p. 1700359.

    Article  Google Scholar 

  25. A.J. Clarke, J.G. Speer, M.K. Mller, RE. Hackenberg, D.V. Edmonds, D.K. Matlock, F.C. Rizzo, K.D. Clarke, and E. De Moor, Carbon partitioning to austenite from martensite or bainite during the quench and partition (Q&P) process: A critical assessment, Acta Mater, 56(2008), No. 1, p. 16.

    Article  CAS  Google Scholar 

  26. J.G. Speer, D.V. Edmonds, F.C. Rizzo, and D.K. Matlock, Partitioning of carbon from supersaturated plates of ferrite, with application to steel processing and fundamentals of the bainite transformation, Curr. Opin. Solid State Mater. Sci., 8(2004), No. 3–4, p. 219.

    Article  CAS  Google Scholar 

  27. Z.C. Li, H. Ding, R.D.K. Misra, Z.H. Cai, and H.X. Li, M-crostructural evolution and deformation behavior in the Fe-(6, 8.5)Mn-3Al-0.2C.TRI. steels, Mater. Sci. Eng. A, 672(2016), p. 161.

    Article  CAS  Google Scholar 

  28. P.H. Chen, Y.B. Li, R.Q. Li, R.P. Jiang, S.S. Zeng, and X.Q. Li, Mcrostructure, mechanical properties, and wear resistance of VCp-reinforced Fe-matrix composites treated by Q&P process, Int. J. Miner. Metall. Mater, 25(2018), No. 9, p. 1060.

    Article  CAS  Google Scholar 

  29. E. De Moor, S. Lacroix, A.J. Clarke, J. Penning, and J.G. Speer, Effect of retained austenite stabilized via quench and partitioning on the strain hardening of martensitic steels, Metall. Mater. Trans. A, 39(2008), p. 2586.

    Article  Google Scholar 

  30. X.C. Xiong, B. Chen, MX. Huang, J.F. Wang, and L. Wang, The effect of morphology on the stability of retained austenite in a quenched and partitioned steel, Scripta Mater, 68(2013), No. 5, p. 321.

    Article  CAS  Google Scholar 

  31. L.J. Xu, S.Z. Wei, J.D. Xing, and R. Long, Effects of carbon content and sliding ratio on wear behavior of high-vanadium high-speed steel (HVH.S. under high-stress rolling-sliding contact, Tribol. Int., 70(2014), p. 34.

    Article  CAS  Google Scholar 

  32. VG. Efremenko, K. Shimizu, A.P. Cheiliakh, TV. Kozar-evskaya, K. Kusumoto, and K. Yamamoto, Effect of vanadium and chromium on the micro structural features of V-Cr-Mn-Ni spheroidal carbide cast irons, Int. J. Miner. Metall. Mater, 21(2014), No. 11, p. 1096.

    Article  CAS  Google Scholar 

  33. L.J. Xu, J.D. Xing, S.Z. Wei, Y.Z. Zhang, and R. Long, Investigation on wear behaviors of high-vanadium high-speed steel compared with high-chromium cast iron under rolling contact condition, Mater. Sci. Eng. A, 434(2006), No. 1–2, p. 63.

    Article  Google Scholar 

  34. L.J. Xu, S.Z. Wei, F.N. Xiao, H. Zhou, G.S. Zhang, and JW. Li, Effects of carbides on abrasive wear properties and failure behaviours of high speed steels with different alloy element content, Wear, 376–377(2017), p. 968.

    Article  Google Scholar 

  35. VG. Efremenko, K. Shimizu, A.P. Cheiliakh, TV. Pastuk-hova, YG. Chabak, and K. Kusumoto, Abrasive resistance of metastable V-Cr-Mn-Ni spheroidal carbide cast irons using the factorial design method, Int. J. Miner. Metall. Mater, 23(2016), No. 6, p. 645.

    Article  CAS  Google Scholar 

  36. VG. Efremenko, K. Shimizu, TV. Pastukhova, YG. Chabak, K. Kusumoto, and A.V. Efremenko, Effect of bulk heat treatment and plasma surface hardening on the micro-structure and erosion wear resistance of complex-alloyed cast irons with spheroidal vanadium carbides, J. Frict. Wear, 38(2017), No. 1, p. 58.

    Article  Google Scholar 

  37. V. Efremenko, K. Shimizu, T. Pastukhova, Y. Chabak, M. Brykov, K. Kusumoto, and A. Efremenko, Three-body ab-rasive wear behaviour of metastable spheroidal carbide cast irons with different chromium contents, Int. J. Mater. Res., 109(2018), No. 2, p. 147.

    Article  CAS  Google Scholar 

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Acknowledgements

This work was financially supported by the China Postdoctoral Foundation (No. 2019M650339), Guangdong Basic and Applied Basic Research Foundation (No. 2019A1515011858), Hunan Provincial Natural Science Foundation, China (No. 2019JJ50807), the State Key Laboratory of High Performance Complex Manufacturing, China (No. ZZYJKT2017-01), the DGUT Innovation Center of Robotics and Intelligent Equipment of China (No. KCYCXPT2017006), and the Key Laboratory of Robotics and Intelligent Equipment of Guangdong Regular Institutions of Higher Education, China (No. 2017KSYS009).

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Correspondence to Rui-qing Li or Song-sheng Zeng.

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Chen, Ph., Zhang, Y., Li, Rq. et al. Influence of carbon-partitioning treatment on the microstructure, mechanical properties and wear resistance of in situ VCp-reinforced Fe-matrix composite. Int J Miner Metall Mater 27, 100–111 (2020). https://doi.org/10.1007/s12613-019-1909-3

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  • DOI: https://doi.org/10.1007/s12613-019-1909-3

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