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Low consumption design of hollow NiCo-LDH nanoflakes derived from MOFs for high-capacity electrode materials

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Abstract

A low consumption and facile method was employed to prepare hollow nickel–cobalt-layered double hydroxide (NiCo-LDH) nanoflakes grown in situ on nickel foam in deionized water at room temperature. By using MOFs (Metal–organic frameworks) as the precursor and then adjusting the Ni2+ ion exchange reaction time, the surface morphology and electrochemical performance of NiCo-LDH electrode materials can be greatly optimized. NiCo-LDH nanoflakes with a thickness of 150 nm as electrode material have a high specific capacity of 2148 F/g at the current density of 1 A/g and possess cycling stability of 82% capacity retention after 1000 cycles. This study provides a prominent approach for fabricating hollow nanomaterials with three-dimensional structures, and its excellent electrochemical performances make it a promising candidate for low energy consumption and high-performance energy storage devices.

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Acknowledgements

This work was financially supported by the National Science Foundation of China (Grant Nos. 51505478 and 51705517) and the Fundamental Research Funds for the Central Universities (Grant No. 2013QNA05).

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Authors and Affiliations

  1. School of Materials and Physics, China University of Mining and Technology, 221116, Xuzhou, People’s Republic of China

    Mingming Zhou, Fengkai Xu, Sheng Zhang, Yiming Yang, Kai Chen & Jianwei Qi

  2. Jinan Rail Transit Group Co. LTD, 250000, Jinan, People’s Republic of China

    Bendong Liu

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  1. Mingming Zhou
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  2. Fengkai Xu
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  3. Sheng Zhang
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  4. Bendong Liu
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Correspondence to Jianwei Qi.

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Zhou, M., Xu, F., Zhang, S. et al. Low consumption design of hollow NiCo-LDH nanoflakes derived from MOFs for high-capacity electrode materials. J Mater Sci: Mater Electron 31, 3281–3288 (2020). https://doi.org/10.1007/s10854-020-02876-z

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  • DOI: https://doi.org/10.1007/s10854-020-02876-z

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