Visible-light-induced, UiO-67-Ru-catalyzed oxidative cross-coupling for constructing β-acetylamino acrylosulfones

doi:10.1016/j.tetlet.2020.151629

Tetrahedron Letters

Volume 61, Issue 11, 12 March 2020, 151629

https://doi.org/10.1016/j.tetlet.2020.151629 Get rights and content

Highlights:

•
UiO-67-Ru-catalyzed oxidative cross-coupling.
•
Visible-light-induced the synthesis of sulfones.
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Recyclable and reusable heterogeneous photocatalytic system.

Abstract

A novel approach to generate β-acetylamino acrylosulfones using the photocatalyst UiO-67-Ru under visible light has been developed. The entire reaction is applicable to sulfone-containing skeleton and exhibits good substrate scope. UiO-67-Ru-catalyzed protocol provides a sustainable and efficient access to construct a variety of sulfones via the direct functionalization of C–H bonds.

Graphical abstract

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Declaration of Competing Interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgments

We thank the National Natural Science Foundation of China (No. 20972113/B020502) and the Fundamental Research Funds for the Central Universities for financial support.

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Citation Excerpt :
All the related reactions were performed in cross-coupling of enamides and sodiumsulfinates under a visible-light-induced oxidative. UiO-67-Ru can be recycled many times and has no any change in nature and stability [215]. Recently, new CO-releasing framework materials by post-synthetic supporting of photoactive MnBr(bpy)(CO)3 core into the UiO-67-BIPYDC, MnBr(BIPYDC)(CO)3@UiO-67 have been reported [216].
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Visible-light-induced, UiO-67-Ru-catalyzed oxidative cross-coupling for constructing β-acetylamino acrylosulfones

Highlights:

Abstract

Graphical abstract

Section snippets

Declaration of Competing Interest

Acknowledgments

J. Med. Chem.

J. Med. Chem.

Arch. Dermatol. Res.

Org. Biomol. Chem.

RSC Adv.

Org. Chem. Front.

Org. Lett.

Org. Biomol. Chem.

Chem. Soc. Rev.

Chem. Commun.

Chem. Commun.

Org. Biomol. Chem.

Org. Chem. Front.

Green Chem.

Chem. Commun.

Org. Lett.

J. Org. Chem.

J. Chem. Soc.

Org. Biomol. Chem.

Chem. Commun.

Org. Biomol. Chem.

Chem. Commun.

Org. Chem. Front.

Chem. Commun.

Org. Biomol. Chem.

Org. Biomol. Chem.

New J. Chem.

Tetrahedron

Adv. Synth. Catal.

Org. Chem. Front.