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Improvement in phase-change hybrid nanocomposites material based on polyethylene glycol/epoxy/graphene for thermal protection systems

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Abstract

Polyethylene glycol (PEG) is established as an organic solid–liquid phase-change material (PCM) offering a wide range of enthalpies and phase transition temperatures as a function of its molecular weight. PCMs are known for their high-energy absorbance; however, they also have two main drawbacks of leakage and enthalpy reduction during melting. In this work, polyethylene glycol as a phase-change material and graphene oxide (GO), expanded graphene (EG), and epoxy resin (EP) as shape stabilizing materials were used and designed based on experimental design—Taguchi method to find the composition with the least molten PEG leakage and the highest enthalpy of melting. Based on improvements made on main drawbacks, two samples were introduced, while their only difference was epoxy content. The results showed that the epoxy resin and graphene oxide caused a significant reduction in molten PEG leakage by hydrogen bonding and trapping of PEG between GO plates and the barrier effect. Also, the expanded graphene by heterogeneous nucleation of molten PEG in a cooling cycle caused a dramatic increment in crystallinity and enthalpy of melting. Among the achievements of this research is the attainment of hybrid nanocomposites samples without leakage (less than 5 wt%) and samples with enthalpy of melting more than that of pure polyethylene glycol (8%).

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References

  1. Sundararajan S, Kumar A, Chakraborty AC, Samui AB, Kulkarni PS (2018) Poly(ethylene glycol) (PEG)-modified epoxy phase change polymer with dual properties of thermal storage and vibration damping. Sustain Energy Fuels 2:688–697

    Article  CAS  Google Scholar 

  2. Dakhli D, Chaffar K, Lafhaj Z (2019) The effect of phase change materials on the physical, thermal and mechanical properties of cement. Science 1:27–39

    Article  Google Scholar 

  3. Yang J, Tang LS, Bai L, Bao RY, Liu ZY, Xie BH, Yang MB, Yang W (2019) High-performance composite phase change materials for energy conversion based on macroscopically three-dimensional structural materials. Mater Horiz 6:250–273

    Article  CAS  Google Scholar 

  4. Fleischer A (2015) Thermal energy storage using phase change materials fundamentals and applications. Springer, New York, pp 37–45

    Book  Google Scholar 

  5. Wang W, Yang X, Fang Y, Ding J (2009) Preparation and performance of form-stable polyethylene glycol/silicon dioxide composites as solid–liquid phase change materials. Appl Energy 86:170–174

    Article  CAS  Google Scholar 

  6. Shchukina EM, Graham M, Zheng Z, Shchukin DG (2018) Nanoencapsulation of phase change materials for advanced thermal energy storage systems. Chem Soc Rev 11:4156–4175

    Article  Google Scholar 

  7. Arce ME, Feijoo MAA, Garcia AS, Luhrs CC (2018) Novel formulations of phase change materials-epoxy composites for thermal energy storage. Materials 11:195–213

    Article  CAS  Google Scholar 

  8. Qian T, Li J, Min X, Deng Y, Guan W, Ma H (2015) Polyethylene glycol/mesoporous calcium silicate shape-stabilized composite phase change material: preparation, characterization, and adjustable thermal property. Energy 82:333–340

    Article  CAS  Google Scholar 

  9. Giro-Paloma J, Martínez M, Cabeza LF, Fernández AI (2016) Types, methods, techniques, and applications for microencapsulated phase change materials (MPCM): a review. Renew Sustain Energy Rev 53:1059–1075

    Article  CAS  Google Scholar 

  10. Qi G, Liang C, Bao R, Liu Z, Yang W, Xie B (2014) Polyethylene glycol based shape-stabilized phase change material for thermal energy storage with ultra-low content of graphene oxide. Sol Energy Mater Sol Cells 123:171–177

    Article  CAS  Google Scholar 

  11. Sundararajan S, Samui AB, Kulkarni PS (2017) Versatility of polyethylene glycol (PEG) in designing solid-solid phase change materials (PCMs) for thermal management and their application to innovative technologies. J Mater Chem A 5:18379–18396

    Article  CAS  Google Scholar 

  12. Samani F, Bahramian AR, Sharif AR (2018) Shape-stable phenolic/polyethylene glycol phase change material: kinetics study and improvements in thermal properties of nanocomposites. Iran Polym J 27:495–505

    Article  CAS  Google Scholar 

  13. Latibari ST, Mehrali MM, Mahlia TM, Cornelis SH (2013) Synthesis, characterization and thermal properties of nanoencapsulated phase change materials via sol-gel method. Energy 61:664–672

    Article  CAS  Google Scholar 

  14. Min X, Fang M, Huang Z, Liu YG, Huang Y, Wen R (2015) Enhanced thermal properties of novel shape-stabilized PEG composite phase change materials with radial mesoporous silica sphere for thermal energy storage. Sci Rep 5:12964–12975

    Article  CAS  Google Scholar 

  15. Yang J, Tang LS, Bao RY, Bai L, Liu ZY, Xie BH, Yang MB, Yang W (2018) Hybrid network structure of boron nitride and graphene oxide in shape stabilized composite phase change materials with enhanced thermal conductivity and light-to-electric energy conversion capability. Sol Energy Mater Sol Cells 174:56–64

    Article  CAS  Google Scholar 

  16. Giro-Paloma J, Al-Shannaq R, Fernández AI, Farid MM (2016) Preparation and characterization of microencapsulated phase change materials for use in building applications. Materials 9:11–25

    Article  CAS  Google Scholar 

  17. Li J, Li Y, Jia L, Cheng Z (2017) Synthesis, characterization and thermal properties of microencapsulated phase change materials via microfluidic device. In: Proceedings of the Asian conference on thermal sciences, 1st ACTS2017, March 26–30, 2017, Jeju Island

  18. Giro-Paloma J, Alkan C, Chimenos JM, Fernández AI (2017) Comparison of microencapsulated phase change materials prepared at laboratory containing the same core and different shell material. Appl Sci 7:723–732

    Article  CAS  Google Scholar 

  19. Zhang N, Yuan Y, Cao X, Du Y, Zhang Z, Gui Y (2018) Latent heat thermal energy storage systems with solid-liquid phase change materials: a review. Adv Eng Mater 20:1700753

    Article  CAS  Google Scholar 

  20. Rezaei B, Askari M, Shoushtari AM, Malek RAM (2014) The effect of diameter on the thermal properties of the modeled shape-stabilized phase change nanofibers (PCNs). J Therm Anal Calorim 118:1619–1629

    Article  CAS  Google Scholar 

  21. Huang X, Alva G, Liu L, Fang G (2017) Microstructure and thermal properties of cetyl alcohol/high density polyethylene composite phase change materials with carbon fiber as shape-stabilized thermal storage materials. Appl Energy 200:19–27

    Article  CAS  Google Scholar 

  22. Chavan S, Gumtapure V, Perumal A (2020) Numerical and experimental analysis on thermal energy storage of polyethylene/functionalized graphene composite phase change materials. J Energy Storage 27:1–11

    Article  Google Scholar 

  23. Tang B, Wang L, Xu Y, Xiu J, Zhang S (2016) Hexadecanol/phase change polyurethane composite as form-stable phase change material for thermal energy storage. Sol Energy Mater Sol Cells 144:1–6

    Article  CAS  Google Scholar 

  24. Hu Q, Chen Y, Hong JS, Zou G, Chen L (2019) A smart epoxy composite based on phase change microcapsules: preparation, microstructure, thermal and dynamic mechanical performances. Molecules 24:916–920

    Article  CAS  Google Scholar 

  25. Su JF, Wang XY, Huang Z, Zhao YH (2011) Thermal conductivity of microPCMs-filled epoxy matrix composites. Colloid Polym Sci 289:1535–1542

    Article  CAS  Google Scholar 

  26. Tumirah K, Hussein MZ, Zulkarnain Z, Rafeadah R (2014) Nano-encapsulation organic phase change material based on copolymer nenocomposites fir thermal energy storage. Energy 66:881–890

    Article  CAS  Google Scholar 

  27. Qi G, Yang J, Bao R, Liu Z, Yang W, Xie B (2015) Enhanced comprehensive performance of polyethylene glycon based phase change material with hybrid graphene nanomaterials for thermal energy storage. Carbon 88:196–205

    Article  CAS  Google Scholar 

  28. Yang J, Qi GQ, Liu Y, Bao RY, Liu ZY, Yang W, Xie BH, Yang MB (2016) Hybrid graphene aerogels/phase change material composites: thermal conductivity, shape stabilization, and light-to-thermal energy. Carbon 100:693–702

    Article  CAS  Google Scholar 

  29. Wang Z, Zhang X, Jia S, Zhu Y, Chan L, Fu L (2017) Influences of dynamic impregnating on morphologies and thermal properties of polyethylene glycol-based composite as shape stabilized PCMs. J Therm Anal Calorim 128:1039–1048

    Article  CAS  Google Scholar 

  30. Wang C, Feng L, Li W, Zheng J, Tian W, Li X (2012) Shape-stabilized phase change materials based on polyethylene glycol/porous carbon composite: the influence of the pore structure of the carbon materials. Sol Energy Mater Sol Cells 105:21–26

    Article  CAS  Google Scholar 

  31. Tang B, Wang Y, Qiu M, Zhang S (2014) A full-band sunlight-driven carbon nanotube/PEG/SiO2 composites for solar energy storage. Sol Energy Mater Sol Cells 123:7–12

    Article  CAS  Google Scholar 

  32. Seraji MM, Seifi A, Bahramian AR (2015) Morphology and properties of silica/novolac hybrid xerogels synthesized using sol–gel polymerization at solvent vapor-saturated atmosphere. Mater Design 69:190–196

    Article  CAS  Google Scholar 

  33. Deng Y, Li J, Nian H, Li Y, Yin X (2017) Design and preparation of shape-stabilized composite phase change material with high thermal reliability via encapsulating polyethylene glycol into flower-like TiO2 nanostructure for thermal energy storage. Appl Therm Eng 114:328–336

    Article  CAS  Google Scholar 

  34. Xiong W, Chen Y, Hao M, Zhang L, Mei T, Wang J, Li J, Wang X (2015) Facile synthesis of PEG based shape-stabilized phase change materials and their photo-thermal energy conversion. Appl Therm Eng 91:630–637

    Article  CAS  Google Scholar 

  35. Fallahi A, Guldentops G, Tao M, Granados-Focil S (2017) Review on solid-solid phase change materials for thermal energy storage: molecular structure and thermal properties. Appl Therm Eng 127:1427–1441

    Article  Google Scholar 

  36. Yuan Y, Yuan Y, Zhang N, Du Y, Cao X (2014) Preparation and thermal characterization of capric–myristic–palmitic acid/expanded graphite composite as phase change material for energy storage. Mater Lett 125:154–157

    Article  CAS  Google Scholar 

  37. Kong Y, Hay JN (2003) The enthalpy of fusion and degree of crystallinity of polymers as measured by DSC. Eur Polym J 39:1721–1727

    Article  CAS  Google Scholar 

  38. Hajizadeh A, Bahramian AR, Seifi A, Naseri I (2016) Effect of initial sol concentration on the microstructure and morphology of carbon aerogels. J Sol Gel Sci Technol 73:220–226

    Article  CAS  Google Scholar 

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Acknowledgements

The authors would also like to thank the Research Department of Tarbiat Modares University (provided Grant No. IG-39710 for the research group of Phase-Change Materials) for the financial supports during this research.

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Authors and Affiliations

  1. Polymer Engineering Department, Faculty of Chemical Engineering, Tarbiat Modares University, P.O. Box 14115-143, Tehran, Islamic Republic of Iran

    Samire Sabagh, Ahmad Reza Bahramian & Majid Haghir Madadi

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  1. Samire Sabagh
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  2. Ahmad Reza Bahramian
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  3. Majid Haghir Madadi
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Correspondence to Ahmad Reza Bahramian.

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Sabagh, S., Bahramian, A.R. & Madadi, M.H. Improvement in phase-change hybrid nanocomposites material based on polyethylene glycol/epoxy/graphene for thermal protection systems. Iran Polym J 29, 161–169 (2020). https://doi.org/10.1007/s13726-020-00783-y

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  • DOI: https://doi.org/10.1007/s13726-020-00783-y

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