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Facile synthesis of Sb-Sb2O5@P@C composite and study for the supercapacitor application

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Abstract

A Sb-Sb2O5@P@C composite was synthesized using a two-step high-energy mechanical milling (HEMM) method using metal antimony, red phosphorus, and carbon as raw materials. XPS, XRD, and Raman spectroscopy clearly showed that the Sb was partially oxidized to become Sb2O5 during the milling process and that some of the red phosphorus was converted to black phosphorus. A specific capacitance of 109.7 F g−1 was achieved at a current density of 0.5 mA cm-2 in the obtained Sb-Sb2O5@P@C composite, and the packaged supercapacitor prepared with the Sb-Sb2O5@P@C composite was found to maintain a capacitance retention of 77.3% after 5000 cycles at a current density of 2 A g−1. This study therefore provides a possible direction for the selection of electrode materials the perform well for application in supercapacitors.

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Acknowledgements

This research was funded by Beijing Natural Science Foundation (Grant No. 2184134), Tianjin Natural Science Foundation (Grant No. 18JCZDJC99800), National Natural Science Foundation of China (Grant No. 51502203), Tianjin Young Overseas High-level Talent Plans (Grant No. 01001502), Tianjin Science and Technology Foundation (Grant No. 17ZXZNGX00090) and Tianjin Development Program for Innovation and Entrepreneurship.

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Author notes

  1. Zongsheng Cao and Zhengchun Yang have contributed equally to this work.

Authors and Affiliations

  1. School of Electrical and Electronic Engineering, Advanced Materials and Printed Electronics Center, Tianjin Key Laboratory of Film Electronic & Communication Devices, Tianjin University of Technology, Tianjin, 300384, People’s Republic of China

    Zongsheng Cao, Zhengchun Yang, Cong Zhang, Liqiang Xie, Xinhao Zhao, Peng Pan, Yujie Yuan, Jie He, Jun Wei, Kailiang Zhang & Jinshi Zhao

  2. Materials Center, Beijing Institute of Collaborative Innovation, Beijing, 100081, People’s Republic of China

    Wen Qi

  3. School of Electrical and Information Engineering, Tianjin University, Tianjin, 300072, People’s Republic of China

    Honghao Zhang & Ping Zhang

  4. Singapore Institute of Manufacturing Technology, Agency for Science, Technology and Research (A*STAR), 71 Nanyang Drive, Singapore, 638075, Singapore

    Jun Wei

  5. Center for Analysis and Test, Tianjin University, Tianjin, 300072, People’s Republic of China

    Tao Xue

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  1. Zongsheng Cao
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Correspondence to Wen Qi or Jie He.

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Additional file 1: Table S1.

Predictive value of variables on one-year global cognitive scores.

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Cao, Z., Yang, Z., Zhang, C. et al. Facile synthesis of Sb-Sb2O5@P@C composite and study for the supercapacitor application. J Mater Sci: Mater Electron 31, 2406–2415 (2020). https://doi.org/10.1007/s10854-019-02776-x

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