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Annual Review of Fluid Mechanics

Volume 52, 2020

Chemo-Hydrodynamic Patterns and Instabilities

Abstract

By modifying a physical property of a solution like its density or viscosity, chemical reactions can modify and even trigger convective flows. These flows in turn affect the spatiotemporal distribution of the chemical species. A nontrivial coupling between reactions and flows then occurs. We present simple model systems of this chemo-hydrodynamic coupling. In particular, we illustrate the possibility of chemical reactions controlling or triggering viscous fingering, Rayleigh–Taylor, double-diffusive, and convective dissolution instabilities. We discuss laboratory experiments performed to study these phenomena and compare the experimental results to theoretical predictions. In each case we contrast the chemo-hydrodynamic patterns and instabilities with those that develop in nonreactive systems and unify the different dynamics in terms of the common features of the related spatial mobility profiles.

Keyword(s): buoyancy-driven instabilities, chemical fronts, chemo-hydrodynamics, double diffusion, Rayleigh–Taylor, reactive flows, viscous fingering
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2020-01-05
2024-04-23
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Chemo-Hydrodynamic Patterns and Instabilities
Annual Review of Fluid Mechanics 52, 531 (2020); https://doi.org/10.1146/annurev-fluid-010719-060349
/content/journals/10.1146/annurev-fluid-010719-060349
/content/journals/10.1146/annurev-fluid-010719-060349
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  • Article Type: Review Article

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