Abstract
Intermetallic phases in the Fe-Nb system have been obtained as products of the devitrification of a homogeneous amorphous Fe70Nb30 alloy prepared by mechanical alloying. Besides Fe2Nb Laves and Fe7Nb6 intermetallic phases, α-Fe phase has been detected by X-ray diffraction (XRD). Hyperfine parameters for both Fe2Nb and Fe7Nb6 intermetallics have been obtained from Mössbauer spectroscopy in correlation with phase identification from XRD results. Thermomagnetic measurements show changes in the Curie temperatures of the amorphous and Fe2Nb phases during the crystallization, due to compositional variations related to the developing of the α-Fe phase. Kinetics of the crystallization process has been analyzed using the classical Johnson-Mehl-Avrami-Kolmogorov kinetic theory in both isothermal and non-isothermal regimes.
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References
N. Fujita, K. Ohmura, A. Yamamoto: Mater. Sci. Eng. A. 2003, vol. 351, pp. 272-281.
G.M. Sim, J.C. Ahn, S.C. Hong, K.J. Lee, K. S. Lee: Mater. Sci. Eng. A. 2005, vol. 396, pp. 159-165.
A. Malfliet, W. Van den Broek, F. Chassagne, J.D. Mithieux, B. Blanpain, P. Wollants: J. Alloy Comp. 2011, vol. 509, pp. 9583-9588.
Y. Kang, W.M. Mao, Y.J. Chen, J. Jing, M. Cheng: Mater. Sci. Eng. A. 2016, vol. 677, pp. 453-464.
M.E. McHenry, M.A. Willard, D.E. Laughlin: Prog. Mater. Sci. 1999, vol. 44, pp. 291-433.
L.E. Zamora, G.A.P. Alcazar, J.A. Tabares, J.D. Betancur, F.R. Sives, J. Jaen, J.M. Greneche, J.F. Marco, J.M. Gonzalez: J. Phys. D: Appl. Phys. 2008, vol. 41, p. 155010.
G. Herzer: Scr. Metall. Mater. 1995, vol. 33, pp. 1741-1756.
S. Voss, M. Palm, F. Stein, D. Raabe: J. Phase Equilib. Diffus. 2011, vol. 32, pp. 97-104.
K.W. Li, X.B. Wang, S.M. Li, W.X. Wang, S.P. Chen, D.Q. Gong, J.L. Cui: High. Temp. Mater. Processes, 2015, vol. 34, pp. 479-485.
C.G. Schon, J.A.S. Tenorio: Intermetallics 1996, vol. 4, pp. 211-216.
H.J. Goldschmidt: Research (London) 1957, vol. 10, pp. 289-291.
A. Takeuchi, A. Inoue: Mater. Trans. JIM 2000, vol. 41, pp. 1372-1378.
E.P. Abrahamson, S.L. Lopata: Trans. Metall. Soc. AIME 1966, vol. 236, pp. 76-87.
J.J. Ipus, J.S. Blázquez, V. Franco, A. Conde, L.F. Kiss: Intermetallics 2010, vol. 18, pp. 565-568.
J.S. Blázquez, J.J. Ipus, S. Lozano-Perez, A. Conde: JOM 2013, vol. 65, pp. 870-882.
A.F. Manchón-Gordón, J.J. Ipus, J.S.; Blázquez, C.F. Conde, A. Conde: J. Non-Cryst. Solids 2018, vol. 494, pp. 78–85.
J. Balogh, L. Bujdoso, D. Kaptas, T. Kemeny, I. Vincze, S. Szabo, D.L. Beke: Phys. Rev. B 2000, vol. 61, pp. 4109-4116.
J.S. Blázquez, J.J. Ipus, V. Franco, C.F. Conde, A. Conde: J. Alloy Comp. 2014, vol. 610, pp. 92-99.
W.A. Johnson, R.F. Mehl: Tech. Publ. 1939, 135, 416–442.
M. Avrami: J. Chem. Phys. 1941, vol. 9, pp. 177-184.
A.N. Kolmogorov, Bull. Russ. Acad. Sci. 1937, vol. 1, pp. 355–359.
P. Bruna, D. Crespo, R. Gonzalez-Cinca, E. Pineda: J. Appl. Phys. 2006, vol. 100, p. 054907.
J.S. Blázquez, M. Millán, C.F. Conde, A. Conde: J. Alloy Comp. 2010, vol. 505, pp. 91-95.
T. Ozawa, Polymer 1971, vol. 12, pp. 150-158.
K. Nakamura, T. Watanabe, K. Katayama: J. Appl. Polym. Sci. 1972, vol. 16, pp. 1077-1091.
K. Nakamura, T. Watanabe, T. Amano: J. Appl. Polym. Sci. 1974, vol. 18, pp. 615-623.
M.J. Starink, A.M. Zahra: Thermochim. Acta 1997, vol. 298, pp. 179-189.
J.S. Blázquez, C.F. Conde, A. Conde: Acta Mater. 2005, vol. 53, pp. 2305-2311.
J. Torrens-Serra, P. Bruna, S. Roth, J. Rodriguez-Viejo, M.T. Clavaguera-Mora: J. Alloy Comp. 2010, vol. 496, pp. 202-207.
R.A. Brand, J. Lauer, D.M. Herlach: J. Phys. D: Appl. Phys. 1983, vol. 13, pp. 675-683.
H.E. Kissinger: Anal. Chem. 1957, vol. 29, pp. 1702-1706.
M.S. El-Eskandarany, A.A. Bahgat, N.S. Gomaa, N.A. Eissa: J. Alloy Comp. 1999, vol. 290, pp. 181-190.
E. Jartych, D. Oleszak, J.K. Zurawicz: Hyperfine Interact. 2001, vol. 136, pp.25-33.
G.Y. Velez, G.A.P. Alcazar, L.E. Zamora: J. Magn. Magn. Mater. 2014, vol. 354, pp. 333-335.
M.T. Raposo, J.D. Ardisson, A.I.C. Persiano, R.A. Mansur: Hyperfine Interact. 1994, vol. 83, pp. 235-238.
G.Y. Velez, G.A.P. Alcazar, L.E. Zamora, J.A. Tabares: J. Supercond. Novel Magn. 2014, vol. 27, pp. 1279-1283.
A. Blachowski, K. Ruebenbauer, J. Zukrowski: Phys. Status Solidi B 2005, vol. 242, pp. 3201-3208.
M.J.M. Pires, W.A.A. Macedo, L.P. Cavalcanti, A.M.G. Carvalho, J. Phys. Chem. Solids 2015, vol. 86, pp. 36-41.
J.S. Blázquez, J.M. Borrego, C.F. Conde, A. Conde, S. Lozano-Perez: J. Alloy Comp. 2012, vol. 544, pp. 73-81.
Acknowledgments
This work was supported by AEI/FEDER-UE (Project MAT 2016-77265-R) and the PAI of the Regional Government of Andalucía. Support of the project APVV-15-0621 is also acknowledged. A.F. Manchón-Gordón acknowledges his contract to the VPPI-US of the University of Sevilla.
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Manuscript submitted September 16, 2019.
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Manchón-Gordón, A.F., Svec, P., Ipus, J.J. et al. Devitrification of Mechanically Alloyed Fe-Nb System: Mössbauer Study of the Intermetallic Phases. Metall Mater Trans A 51, 1395–1401 (2020). https://doi.org/10.1007/s11661-019-05610-5
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DOI: https://doi.org/10.1007/s11661-019-05610-5