Regular ArticleTorsional Splitting in the ν5 Fundamental Infrared Band of CH3CD3 and 13CH3CD3
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Supplementary Files
The file CCprnt is an ASCII file. It contains the Supplement (observed wavenumbers and their assignments) to the article “Torsional Splitting in the ?5 Fundamental Infrared Band of CH3CD3 and 13CH3CD3”, by F. Lattanzi, C. di Lauro, C. Claveau, A. Valentin, and G.D. Nivellini, Journal of Molecular Spectroscopy.
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Cited by (2)
Internal rotation in symmetric tops
2007, Advances in Atomic, Molecular and Optical PhysicsThe ν<inf>5</inf> band of CH<inf>3</inf>CD<inf>3</inf>: High-resolution spectrum and global three-band analysis
2003, Chemical Physics LettersCitation Excerpt :The measured frequencies were successfully modeled by a vibration–torsion–rotation Hamiltonian employing 35 parameters, three of which characterize this coupling. An analysis of the ν5 (C–C stretch) fundamental of CH3CD3, which is the subject of the present study, has been reported recently by Lattanzi et al. [8]. In their study, the observed transitions were fit to a simplified model in which effective rotational parameters were assigned independently to the five torsional families of ν5.